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Organic Polymer Dot...
Organic Polymer Dots Photocatalyze CO2 Reduction in Aqueous Solution
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- Cai, Bin (författare)
- Uppsala universitet,Fysikalisk kemi
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- Axelsson, Martin, 1993- (författare)
- Uppsala universitet,Fysikalisk kemi
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- Zhan, Shaoqi (författare)
- Uppsala universitet,Institutionen för kemi - BMC
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- Pavliuk, Mariia V. (författare)
- Uppsala universitet,Fysikalisk kemi
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- Wang, Sicong (författare)
- Uppsala universitet,Fysikalisk kemi
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- Li, Jingguo (författare)
- Uppsala universitet,Institutionen för kemi - Ångström
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- Tian, Haining, 1983- (författare)
- Uppsala universitet,Fysikalisk kemi
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(creator_code:org_t)
- John Wiley & Sons, 2023
- 2023
- Engelska.
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Ingår i: Angewandte Chemie International Edition. - : John Wiley & Sons. - 1433-7851 .- 1521-3773. ; 62:45
- Relaterad länk:
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https://doi.org/10.1...
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https://uu.diva-port... (primary) (Raw object)
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Developing low-cost and efficient photocatalysts to convert CO2 into valuable fuels is desirable to realize a carbon-neutral society. In this work, we report that polymer dots (Pdots) of poly[(9,9 ' -dioctylfluorenyl-2,7-diyl)-co-(1,4-benzo-thiadiazole)] (PFBT), without adding any extra co-catalyst, can photocatalyze reduction of CO2 into CO in aqueous solution, rendering a CO production rate of 57 mu mol g(-1) h(-1 )with a detectable selectivity of up to 100 %. After 5 cycles of CO2 re-purging experiments, no distinct decline in CO amount and reaction rate was observed, indicating the promising photocatalytic stability of PFBT Pdots in the photocatalytic CO2 reduction reaction. A mechanistic study reveals that photoexcited PFBT Pdots are reduced by sacrificial donor first, then the reduced PFBT Pdots can bind CO(2 )and reduce it into CO via their intrinsic active sites. This work highlights the application of organic Pdots for CO2 reduction in aqueous solution, which therefore provides a strategy to develop highly efficient and environmentally friendly nanoparticulate photocatalysts for CO2 reduction.
Ämnesord
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Nyckelord
- CO Production
- CO2 Photoreduction
- Photocatalyst
- Photochemistry
- Polymer Dots
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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