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Polymer Core-Polyme...
Polymer Core-Polymer Shell Particle Formation Enabled by Ultralow Interfacial Tension Via Internal Phase Separation: Morphology Prediction Using the Van Oss Formalism
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- Andersson Trojer, Markus, 1981 (författare)
- RISE,IVF,Max Planck Institute of Colloids and Interfaces, Germany
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- Ananievskaia, Anna (författare)
- Gothenburg University,Göteborgs universitet,Institutionen för biologi och miljövetenskap,Department of Biological and Environmental Sciences,University of Gothenburg,University of Gothenburg, Sweden
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- Gabul-Zada, Asvad A (författare)
- Gothenburg University,Göteborgs universitet,Institutionen för biologi och miljövetenskap,Department of Biological and Environmental Sciences
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- Nordstierna, Lars, 1976 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology,Chalmers University of Technology, Sweden
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- Blanck, Hans, 1950 (författare)
- Gothenburg University,Göteborgs universitet,Institutionen för biologi och miljövetenskap,Department of Biological and Environmental Sciences,University of Gothenburg,University of Gothenburg, Sweden
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(creator_code:org_t)
- Elsevier BV, 2018
- 2018
- Engelska.
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Ingår i: Colloid and Interface Science Communications. - : Elsevier BV. - 2215-0382. ; 25, s. 36-40
- Relaterad länk:
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https://pure.mpg.de/...
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https://gup.ub.gu.se...
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https://doi.org/10.1...
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https://research.cha...
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https://urn.kb.se/re...
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Abstract
Ämnesord
Stäng
- The internal phase separation technique is a versatile method for liquid core-polymer shell formation, yet limited to very hydrophobic core materials and actives. The use of polymeric cores instead circumvents this restriction due to the absent mixing entropy for binary polymer mixtures which allows the polymeric core (and the active) to approach the polarity of the shell. Polystyrene core-shell and janus particles were formulated using polymethylmethacrylate, poly(lactic acid), poly(lactic acid-co-glycolic acid), poly(epsilon-caprolactone) or cellulose triacetate as shell-forming polymers. The morphology and the partitioning was experimentally determined by selectively staining the core and the shell with beta-carotene and methylene blue respectively. In addition, the van Oss formalism was introduced to theoretically predict the thermodynamic equilibrium morphology. As elucidated using the theoretical predictions as well as experimental optical tensiometry, it was found that the driving force for core-shell morphology is, in contrast to liquid core-polymer shell particles, a low core-shell interfacial tension.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Nanoteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Nano-technology (hsv//eng)
- MEDICIN OCH HÄLSOVETENSKAP -- Medicinska och farmaceutiska grundvetenskaper -- Andra medicinska och farmaceutiska grundvetenskaper (hsv//swe)
- MEDICAL AND HEALTH SCIENCES -- Basic Medicine -- Other Basic Medicine (hsv//eng)
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Annan kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Other Chemistry Topics (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Materialteknik -- Textil-, gummi- och polymermaterial (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering -- Textile, Rubber and Polymeric Materials (hsv//eng)
Nyckelord
- Microcapsule
- Solvent evaporation
- Core-shell
- Raspberry
- Janus
- Spreading
- microcapsules
- release
- encapsulation
- Chemistry
- Science & Technology - Other Topics
- Materials Science
- Janus
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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