Biogeochemical evolution of the carbon dioxide system in the waters of long-lived mesoscale eddies in the Northeast Pacific Ocean

• An anticyclonic eddy, named Haida-2000, formed off the Southern Queen Charlotte Islands early in the year 2000. The eddy subsequently tracked northwest, transporting fresh, warm, and nutrient-rich water into the Northeast Pacific Ocean. Based on total dissolved inorganic carbon (CA total alkalinity (AT), and nutrients from six seasonal cruises between February 2000 and September 2001, we found that the oceanic carbonate system of the Surface waters in the eddy changed significantly. The greatest loss of C-T from the surface waters of Haida-2000 occurred during the first year, between February and June 2000. Based oil a concomitant loss in nitrate (NO3), the large CT loss we observed was likely due to biological production of organic carbon and probably resulted in a large drawdown of atmospheric CO,, as supported by the observed fugacity of carbon dioxide (fCO(2)) in the surface waters. During fall, C-T, fCO(2), and NO3 values increased, probably due to oxidation of organic matter and vertical entrainment Of CT and nutrient-rich water from below with fall mixing. As a result, the surface waters of the eddy were highly oversaturated in CO2 relative to the atmosphere. Another Haida eddy (Haida-2001) had a significantly smaller nitrate drawdown than Haida-2000 during its first spring, but the CT losses were similar in the two eddies. In early summer (mid-June) of the second year, the surface and sub-surface waters in Haida-2000 gained C-T, A(T), and NO3, partly caused by a merging with another 2001 Haida eddy, showing that exchange with surrounding waters took place and was significant at times. The high nitrate/ low chlorophyll (HNLC) surface waters at Ocean Station Papa (OSP), showed less fCO(2) Undersaturation during summer and less total nitrate and CT loss than Haida-2000, indicating that both eddies were larger sinks for carbon lthan HNLC waters. The waters surrounding the eddies generally had concentrations of C-T, A(T), and NO3 that were similar to or slightly higher than the waters of both Haida eddies throughout the study. Also, the sub-surface waters in these eddies showed no significant change in total carbon content, suggesting that at these depths eddies are recycling, not exporting systems. (c) 2005 Elsevier Ltd. All rights reserved.

Ämnesord

NATURVETENSKAP  -- Kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

Nyckelord

SUB-ARCTIC PACIFIC

INTERANNUAL VARIABILITY

INORGANIC CARBON

ORGANIC-CARBON

HAIDA EDDIES

STATION-P

EL-NINO

PHYTOPLANKTON

NUTRIENT

ALASKA

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