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Aquabis(3,5-dimethy...
Aquabis(3,5-dimethyl-1H-pyrazole-kappa N-2)(malonato-kappa O-2,O ')copper(II) dihydrate
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Xiong, Y (författare)
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Tong, ML (författare)
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An, TC (författare)
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- Karlsson, Hans (författare)
- Lund University,Lunds universitet,Avdelningen för kemiteknik,Institutionen för processteknik och tillämpad biovetenskap,Institutioner vid LTH,Lunds Tekniska Högskola,Division of Chemical Engineering,Department of Process and Life Science Engineering,Departments at LTH,Faculty of Engineering, LTH
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(creator_code:org_t)
- 2001
- 2001
- Engelska.
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Ingår i: Acta Crystallographica. Section C: Crystal Structure Communications. - 0108-2701. ; 57, s. 1385-1387
- Relaterad länk:
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http://dx.doi.org/10...
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https://lup.lub.lu.s...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- In the neutral title complex, [Cu(C3H2O4)(C5H8N2)(2-)(H2O)]. 2H(2)O or [Cu(mal)(dmp)(2)(H2O)]. 2H(2)O (mal is malonate and dmp is 3,5-dimethyl-1H-pyrazole), the Cu-II ion, in a slightly distorted square-pyramidal geometry, is coordinated by two O atoms of the bidentate malonate, the O atom of the water ligand and two N atoms from the two 3,5-dimethylpyrazole ligands. The mean Cu-N bond length is 2.007 (6) Angstrom, longer than the Cu-O-mal bonds [1.950 (5) Angstrom]. The apical position is occupied by a relatively strongly coordinated water molecule [Cu-O-water 2.288 (5) Angstrom]. The crystal structure is characterized by the layer motif of a hydrogen-bonded network.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering (hsv//eng)
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