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Bis[4-(dimethylamin...
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Massoud, Al-Shimaà A A,1980Chalmers tekniska högskola,Chalmers University of Technology
(författare)
Bis[4-(dimethylamino)pyridine-κN1]silver(I) nitrate dihydrate
- Artikel/kapitelEngelska2009
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Nummerbeteckningar
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LIBRIS-ID:oai:research.chalmers.se:22810ed8-dc4f-4f50-8af9-ffd2bc75906d
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https://doi.org/10.1107/S0108270109030509DOI
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https://research.chalmers.se/publication/96608URI
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Språk:engelska
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Sammanfattning på:engelska
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Ämneskategori:art swepub-publicationtype
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The title compound, [Ag(C7H10N2)2]NO3·2H2O or [Ag(dmap)2]NO3·2H2O, where dmap is 4-(dimethylamino)pyridine, has a distorted linear coordination geometry around the AgI ion. A novel pattern of water-nitrate hydrogen-bonded anionic strands is formed in the c direction, with the cationic [Ag(dmap)2]+ monomers trapped between them. The AgI ion and the nitrate group atoms, as well as the water molecules (including the H atoms), are on a crystallographic mirror plane (Wyckoff position 4a). The influence of bulky methyl substituents in position 4 of the 4-(dimethylamino)pyridine ligand on packing is discussed. The absolute structure was determined unequivocally.
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Langer, Vratislav,1949Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)langer
(författare)
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Abu-Youssef, Morsy A.M.Alexandria University
(författare)
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Chalmers tekniska högskolaAlexandria University
(creator_code:org_t)
Sammanhörande titlar
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Ingår i:Acta Crystallographica Section C: Crystal Structure CommunicationsC65:9, s. m352-m3540108-27011600-5759
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