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Palladium-catalyzed...
Palladium-catalyzed stereoselective domino arylation-acylation: an entry to chiral tetrahydrofluorenone scaffolds
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- Dunås, Petter, 1990 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Paterson, Andrew, 1988 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Kociok-Kohn, Gabriele (författare)
- University of Bath
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- Rahm, Martin, 1982 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Lewis, Simon E. (författare)
- University of Bath
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- Kann, Nina, 1964 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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(creator_code:org_t)
- 2021
- 2021
- Engelska.
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Ingår i: Chemical Communications. - : Royal Society of Chemistry (RSC). - 1364-548X .- 1359-7345. ; 57:53, s. 6518-6521
- Relaterad länk:
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https://research.cha... (primary) (free)
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https://pubs.rsc.org...
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https://research.cha...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- A palladium-catalyzed domino arylation-cyclization of biocatalytically derived cyclic 1,3-dienes is demonstrated. The reaction introduces a high degree of structural complexity in a single step, giving access to tricyclic tetrahydrofluorenones with full regio- and stereoselectivity. The transformation proceeds through a novel acylation-terminated Heck-type sequence, and quantum chemical calculations indicate that C-H activation is involved in the terminating acylation step.
Ämnesord
- NATURVETENSKAP -- Biologi -- Biokemi och molekylärbiologi (hsv//swe)
- NATURAL SCIENCES -- Biological Sciences -- Biochemistry and Molecular Biology (hsv//eng)
- NATURVETENSKAP -- Biologi -- Strukturbiologi (hsv//swe)
- NATURAL SCIENCES -- Biological Sciences -- Structural Biology (hsv//eng)
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
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- ref (ämneskategori)
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