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Sökning: onr:"swepub:oai:research.chalmers.se:36d599c9-0924-4b62-a526-969efeb9668d" > Fluorinated Ether B...

LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00003184naa a2200397 4500
001oai:research.chalmers.se:36d599c9-0924-4b62-a526-969efeb9668d
003SwePub
008180111s2017 | |||||||||||000 ||eng|
024a https://doi.org/10.1021/acs.chemmater.7b036542 DOI
024a https://research.chalmers.se/publication/2542162 URI
040 a (SwePub)cth
041 a engb eng
042 9 SwePub
072 7a art2 swepub-publicationtype
072 7a ref2 swepub-contenttype
100a Drvarič Talian, Sarau Kemijski Institut,National Institute of Chemistry Slovenia,Univerza V Ljubljani,University of Ljubljana4 aut
2451 0a Fluorinated Ether Based Electrolyte for High-Energy Lithium-Sulfur Batteries: Li+ Solvation Role behind Reduced Polysulfide Solubility
264 c 2017-11-29
264 1b American Chemical Society (ACS),c 2017
338 a electronic2 rdacarrier
520 a By employing new electrolytes, the polysulfide shuttle phenomenon, one of the main problems of lithium-sulfur (Li-S) batteries, can be significantly reduced. Here we present excellent Coulombic efficiencies as well as adequate performance of high-energy Li-S cells by the use of a fluorinated ether (TFEE) based electrolyte at low electrolyte loading. The observed altered discharge profile was investigated both by electrochemical experiments and an especially tailored COSMO-RS computational approach, while the details of the discharge mechanism were elucidated by two operando techniques: XANES and UV-vis spectroscopy. A significant decrease of polysulfide solubility compared to tetraglyme is due to different Li+ solvation mode.
650 7a NATURVETENSKAPx Fysikx Atom- och molekylfysik och optik0 (SwePub)103022 hsv//swe
650 7a NATURAL SCIENCESx Physical Sciencesx Atom and Molecular Physics and Optics0 (SwePub)103022 hsv//eng
700a Jeschke, Steffen,d 1986u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)jeschke
700a Vizintin, Alenu Kemijski Institut,National Institute of Chemistry Slovenia4 aut
700a Pirnat, Klemenu Kemijski Institut,National Institute of Chemistry Slovenia4 aut
700a Iztok, Arcˇonu Institut Jožef Stefan,Jozef Stefan Institute,University of Nova Gorica4 aut
700a Aquilanti, Giulianau Elettra Sincrotrone Trieste Scpa4 aut
700a Johansson, Patrik,d 1969u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)jpatrik
700a Dominko, R.u Kemijski Institut,National Institute of Chemistry Slovenia,Alistore - European Research Institute,Univerza V Ljubljani,University of Ljubljana4 aut
710a Kemijski Institutb Univerza V Ljubljani4 org
773t Chemistry of Materialsd : American Chemical Society (ACS)g 29:23, s. 10037-10044q 29:23<10037-10044x 1520-5002x 0897-4756
856u http://publications.lib.chalmers.se/records/fulltext/254216/local_254216.pdfx primaryx freey FULLTEXT
856u https://pubs.acs.org/doi/pdf/10.1021/acs.chemmater.7b03654
8564 8u https://doi.org/10.1021/acs.chemmater.7b03654
8564 8u https://research.chalmers.se/publication/254216

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