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Water pores in alky...
Water pores in alkyl ketene dimer (AKD) dispersions studied by NMR diffusometry and optical microscopy
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- Mohlin, Kristina, 1970 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Lorén, Niklas, 1970 (författare)
- RISE,SIK – Institutet för livsmedel och bioteknik
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- Nydén, Magnus, 1970 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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(creator_code:org_t)
- Elsevier BV, 2007
- 2007
- Engelska.
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Ingår i: Colloids and Surfaces A: Physicochemical and Engineering Aspects. - : Elsevier BV. - 1873-4359 .- 0927-7757. ; 297:1-3, s. 114-121
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Abstract
Ämnesord
Stäng
- Water borne alkyl ketene dimer (AKD) dispersions have been investigated by means of optical microscopy and NMR diffusometry (NMR-D). In two different formulations, different amounts of entrapped water in pores with different sizes are obtained, which can be compared to a waterin-oil-in-water (w/o/w) dispersion. It is shown that the amount of entrapped water inside the AKD particles can conveniently be measured with the NMR-D technique. The pore size is however not obtained correctly from the NMR-D experiment. Due to the small size of the water pores, the pore size is underestimated when measured with NMR-D. This effect is investigated in more detail by Brownian dynamic simulations from which a correction factor is obtained that allows a more correct value of the pore size from NMR-D measurements. When the pore size is too small to be observed by optical microscopy, typically below 0.5 mu m, NMR diffusometry combined with Brownian dynamic simulations are shown to be a rapid and reliable tool for quantifying the porosity in these types of systems.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering (hsv//eng)
- LANTBRUKSVETENSKAPER -- Lantbruksvetenskap, skogsbruk och fiske -- Livsmedelsvetenskap (hsv//swe)
- AGRICULTURAL SCIENCES -- Agriculture, Forestry and Fisheries -- Food Science (hsv//eng)
Nyckelord
- Brownian dynamic simulations
- alkyl ketene dimer
- microscopy
- NMR diffusometry
- pores
- dispersion
- optical
Publikations- och innehållstyp
- art (ämneskategori)
- ref (ämneskategori)
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