| 1. |
- Ross, Russell G.
(author)
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Thermal conductivity of the urea-hexadecane inclusion compound
- 1990
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In: Journal of inclusion phenomena and molecular recognition in chemistry. - : Kluwer Academic Publishers. - 0923-0750 .- 2212-1765 .- 1573-1111. ; 8:1-2, s. 227-233
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Journal article (peer-reviewed)abstract
- The thermal conductivity λ and the heat capacity per unit volume ϱcp have been measured for the urea-hexadecane inclusion compound using the transient hot-wire method. Measurements were made under isobaric conditions at a pressure of 0.1 GPa and in the temperature range of 100–300 K. There was evidence for a phase transition at a temperature of about 160 K, in reasonable agreement with previous work. For the high-temperature phase λ was independent of temperature within ±1%. The low-temperature phase showed a weak temperature dependence, with (d lnλ/d lnT)p = −0.13. It was inferred that interaction between acoustic phonons and low-frequency vibrational excitations of the guest molecules made a major contribution to the thermal resistivity. For the quantity ϱcp a weak maximum was observed in the region of the phase transition temperature.
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| 2. |
- Stödeman, Magnus, et al.
(author)
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Thermodynamics of binding of alpha-cyclodextrin to straight-chain alkyl derivatives in aqueous solution
- 2003
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In: Journal of Inclusion Phenomena and Molecular Recognition in Chemistry. - 0923-0750. ; 46:3-4, s. 125-132
-
Journal article (peer-reviewed)abstract
- Apparent standard Gibbs energy, enthalpy, entropy, and heat capacity data of the interactions of alpha-cyclodextrin (alphaCD) to some n-carboxylates H(CH2)(n)COO- (n = 4 - 6), are determined by isothermal titration microcalorimetry at different temperatures in phosphate buffer, pH 9.0, assuming a 1 : 1 model in dilute solution. Modelling of contributions of the thermodynamic properties of the solution indicates that aCD undergoes conformational change upon binding to homologous series of n-carboxylates, n-alcohols, alpha,omega-alkane dicarboxylates and alpha,omega-alkane diols.
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| 3. |
- Vaitkus, Rimantas, et al.
(author)
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Large inclusion constants of beta-cyclodextrin with carborane derivatives
- 2011
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In: Journal of inclusion phenomena and molecular recognition in chemistry. - : Springer Science and Business Media LLC. - 0923-0750 .- 2212-1765. ; 69:3-4, s. 393-395
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Journal article (peer-reviewed)abstract
- Complexation of some o-, m- and p-carborane derivatives with beta-cyclodextrin was investigated using phenolphthalein in pH 10.5 (0.05 mol dm(-3)) borate buffer. Some carborane derivatives indicated large inclusion constants K-ass > 1 x 10(5) dm(3) mol(-1).
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| 4. |
- Ye, Lei, et al.
(author)
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The technique of molecular imprinting : Principle, state of the art, and future aspects
- 2001
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In: Journal of Inclusion Phenomena. - 0923-0750. ; 41:1-4, s. 107-113
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Journal article (peer-reviewed)abstract
- Molecular imprinting has gained increasing research interest during the past few years. In this overview we would like to explain to the readers how a seemingly simple concept can eventually lead to useful applications in several areas. The main focus will be on the present state of the art of molecular imprinting, as several breakthroughs have occurred since most reviews by us and other groups have been written. In the last part of this article we would like to discuss future developments in the area of molecular imprinting.
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