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  • Launois, Pascale, et al. (author)
  • Pressure polymerized C60 single crystals: First x-ray diffraction results
  • 1998
  • In: Molecular Nanostructures. - Singapore : World Scientific. - 9789810232610 ; , s. 348-352
  • Conference paper (peer-reviewed)abstract
    • C60 single crystals compressed at approx. 1 GPa and heated at about 300 C are found to polymerize in one dimension without losing their crystalline order. The resulting structure is orthrhombic, with space group Pmnn and parameters a=9.14 Å, b=9.9 Å and c=14.66 Å. The X-ray single crystal results allow us to derive a polymerization mechanism, which may also, for instance, apply to one dimensional C60 polymers in the doped compounds. The new polymer phase is discussed with respect to the C60 pressure-temperature diagram. The comparison with the A1C60 polymers raises questions about the interchain and the alkali metal - fullerene interactins.
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Type of publication
conference paper (1)
Type of content
peer-reviewed (1)
Author/Editor
Sundqvist, Bertil (1)
Launois, Pascale (1)
Moret, Roger (1)
Persson, Per-Axel (1)
University
Umeå University (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
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