| 1. |
- Adamo, Nasrat, et al.
(författare)
-
Climate Change: Droughts and Increasing Desertification in the Middle East, with Special Reference to Iraq
- 2022
-
Ingår i: Engineering. - : Scientific Research Publishing. - 1947-3931 .- 1947-394X. ; 14:7, s. 235-273
-
Tidskriftsartikel (refereegranskat)abstract
- Climate change impacts on Earth’s atmosphere have caused drastic changes in the environment of most regions of the world. The Middle East region ranks among the worst affected of these regions. This has taken forms of increasing atmospheric temperatures, intensive heat waves, decreased and erratic precipitation and general decline in water resources; all leading to frequent and longer droughts, desertification and giving rise to intensive and recurrent (SDS). The present conditions have led to increasing emissions of (GHG) in the earth atmosphere. All future projections especially those using (IPCC) models and emission scenarios indicate that the Middle East will undergo appreciable decrease in winter precipitation with increasing temperature until the end of this century both of which are inductive to increased dryness and desertification. Iraq as one of the countries of this region and due to its geographical location, its dependence mostly on surface water resources originating from neighboring countries, long years of neglect and bad land management put it in the most precarious and unstable position among the other countries of the region. Modelling studies have shown that Iraq is suffering now from excessive dryness and droughts, increasing loss of vegetation cover areas, increasing encroachment of sand dunes on agricultural lands, in addition to severe and frequent (SDS). These negative repercussions and their mitigations require solutions not on the local level alone but collective cooperation and work from all the countries of the region.
|
|
| 2. |
- Wang, Ning, et al.
(författare)
-
Boride-derived oxygen-evolution catalysts
- 2021
-
Ingår i: Nature Communications. - : Springer Nature. - 2041-1723. ; 12
-
Tidskriftsartikel (refereegranskat)abstract
- Metal borides/borates have been considered promising as oxygen evolution reaction catalysts; however, to date, there is a dearth of evidence of long-term stability at practical current densities. Here we report a phase composition modulation approach to fabricate effective borides/borates-based catalysts. We find that metal borides in-situ formed metal borates are responsible for their high activity. This knowledge prompts us to synthesize NiFe-Boride, and to use it as a templating precursor to form an active NiFe-Borate catalyst. This boride-derived oxide catalyzes oxygen evolution with an overpotential of 167 mV at 10 mA/cm2 in 1 M KOH electrolyte and requires a record-low overpotential of 460 mV to maintain water splitting performance for over 400 h at current density of 1 A/cm2. We couple the catalyst with CO reduction in an alkaline membrane electrode assembly electrolyser, reporting stable C2H4 electrosynthesis at current density 200 mA/cm2 for over 80 h.
|
|
