| 1. |
- Arrhenius, Karine, et al.
(author)
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An inter-laboratory comparison between 13 international laboratories for eight components relevant for hydrogen fuel quality assessment
- 2024
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In: Measurement. - : Elsevier B.V.. - 0263-2241 .- 1873-412X. ; 230
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Journal article (peer-reviewed)abstract
- The quality of the hydrogen delivered by refuelling stations is critical for end-users and society. The purity of the hydrogen dispensed at hydrogen refuelling points should comply with the technical specifications included in the ISO 14687:2019 and EN 17124:2022 standards. Once laboratories have set up methods, they need to verify their performances, for example through participation in interlaboratory comparisons. Due to the challenge associated with the production of stable reference materials and transport of these which are produced in hydrogen at high pressure (>10 bar), interlaboratory comparisons have been organized in different steps, with increasing extent. This study describes an inter-laboratory comparison exercise for hydrogen fuel involving a large number of participants (13 laboratories), completed in less than a year and included eight key contaminants of hydrogen fuel at level close to the ISO14687 threshold. These compounds were selected based on their high probability of occurrence or because they have been found in hydrogen fuel samples. For the results of the intercomparison, it appeared that fully complying with ISO 21087:2019 is still challenging for many participants and highlighted the importance of organising these types of exercises. Many laboratories performed corrective actions based on their results, which in turn significantly improved their performances. © 2024 The Author(s)
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| 2. |
- Arrhenius, Karine, et al.
(author)
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Detection of contaminants in hydrogen fuel for fuel cell electrical vehicles with sensors—available technology, testing protocols and implementation challenges
- 2022
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In: Processes. - : MDPI. - 2227-9717. ; 10:1
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Journal article (peer-reviewed)abstract
- Europe’s low-carbon energy policy favors a greater use of fuel cells and technologies based on hydrogen used as a fuel. Hydrogen delivered at the hydrogen refueling station must be compliant with requirements stated in different standards. Currently, the quality control process is performed by offline analysis of the hydrogen fuel. It is, however, beneficial to continuously monitor at least some of the contaminants onsite using chemical sensors. For hydrogen quality control with regard to contaminants, high sensitivity, integration parameters, and low cost are the most important requirements. In this study, we have reviewed the existing sensor technologies to detect contaminants in hydrogen, then discussed the implementation of sensors at a hydrogen refueling stations, described the state-of-art in protocols to perform assessment of these sensor technologies, and, finally, identified the gaps and needs in these areas. It was clear that sensors are not yet commercially available for all gaseous contaminants mentioned in ISO14687:2019. The development of standardized testing protocols is required to go hand in hand with the development of chemical sensors for this application following a similar approach to the one undertaken for air sensors. © 2021 by the authors.
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| 3. |
- Arrhenius, Karine, et al.
(author)
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Strategies for the sampling of hydrogen at refuelling stations for purity assessment
- 2021
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In: International journal of hydrogen energy. - : Elsevier Ltd. - 0360-3199 .- 1879-3487. ; 46:70, s. 34839-
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Journal article (peer-reviewed)abstract
- Hydrogen delivered at hydrogen refuelling station must be compliant with requirements stated in different standards which require specialized sampling device and personnel to operate it. Currently, different strategies are implemented in different parts of the world and these strategies have already been used to perform 100s of hydrogen fuel sampling in USA, EU and Japan. However, these strategies have never been compared on a large systematic study. The purpose of this paper is to describe and compare the different strategies for sampling hydrogen at the nozzle and summarize the key aspects of all the existing hydrogen fuel sampling including discussion on material compatibility with the impurities that must be assessed. This review highlights the fact it is currently difficult to evaluate the impact or the difference these strategies would have on the hydrogen fuel quality assessment. Therefore, comparative sampling studies are required to evaluate the equivalence between the different sampling strategies. This is the first step to support the standardization of hydrogen fuel sampling and to identify future research and development area for hydrogen fuel sampling. © 2021 The Authors
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| 4. |
- Bacquart, Thomas, et al.
(author)
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Hydrogen fuel quality from two main production processes : Steam methane reforming and proton exchange membrane water electrolysis
- 2019
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In: Journal of Power Sources. - : Elsevier B.V.. - 0378-7753 .- 1873-2755. ; 444
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Journal article (peer-reviewed)abstract
- The absence of contaminants in the hydrogen delivered at the hydrogen refuelling station is critical to ensure the length life of FCEV. Hydrogen quality has to be ensured according to the two international standards ISO 14687–2:2012 and ISO/DIS 19880-8. Amount fraction of contaminants from the two hydrogen production processes steam methane reforming and PEM water electrolyser is not clearly documented. Twenty five different hydrogen samples were taken and analysed for all contaminants listed in ISO 14687-2. The first results of hydrogen quality from production processes: PEM water electrolysis with TSA and SMR with PSA are presented. The results on more than 16 different plants or occasions demonstrated that in all cases the 13 compounds listed in ISO 14687 were below the threshold of the international standards. Several contaminated hydrogen samples demonstrated the needs for validated and standardised sampling system and procedure. The results validated the probability of contaminants presence proposed in ISO/DIS 19880-8. It will support the implementation of ISO/DIS 19880-8 and the development of hydrogen quality control monitoring plan. It is recommended to extend the study to other production method (i.e. alkaline electrolysis), the HRS supply chain (i.e. compressor) to support the technology growth.
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| 5. |
- Bacquart, Thomas, et al.
(author)
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METROLOGY FOR HYDROGEN VEHICLE 2 : ACHIEVEMENTS AND PROGRESSES
- 2022
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In: Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference. - : International Association for Hydrogen Energy, IAHE. - 9786250008430 ; , s. 1223-1225
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Conference paper (peer-reviewed)abstract
- Hydrogen fuel cells are an alternative power supply for electric drive trains and could represent 32 % of fuel demand by 2050. To deploy fuel cell electrical vehicles, there is current regulatory barriers (ISO 14687, OIML recommendations) that requires accurate measurements. The European funded project MetroHyVe has provided solutions and improvements in the four measurements challenges (flow metering, quality control, quality assurance and sampling). New challenges arised due to increase of hydrogen economy, therefore a new European project MetroHyVe 2 started in 2020 and its objectives will provide perspectives for the hydrogen economy to solve all regulatory barriers (ISO 14687, ISO 19880-8, ISO 19880-1, ISO 21087, OIML R139-1) and new measurement challenges (flow metering, quality control, sampling and fuel cell stack testing). The presentation will provide a comprehensive overview of the project achievements. The achievements around primary standard for flow metering (light and heavy duty), worldwide inter-laboratory comparison for hydrogen fuel quality, hydrogen sampling intercomparison and fuel cell stack testing recommendations will be highlighted.
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| 6. |
- Beurey, Claire, et al.
(author)
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Review and Survey of Methods for Analysis of Impurities in Hydrogen for Fuel Cell Vehicles According to ISO 14687:2019
- 2021
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In: Frontiers in Energy Research. - : Frontiers Media S.A.. - 2296-598X. ; 8
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Journal article (peer-reviewed)abstract
- Gaseous hydrogen for fuel cell electric vehicles must meet quality standards such as ISO 14687:2019 which contains maximal control thresholds for several impurities which could damage the fuel cells or the infrastructure. A review of analytical techniques for impurities analysis has already been carried out by Murugan et al. in 2014. Similarly, this document intends to review the sampling of hydrogen and the available analytical methods, together with a survey of laboratories performing the analysis of hydrogen about the techniques being used. Most impurities are addressed, however some of them are challenging, especially the halogenated compounds since only some halogenated compounds are covered, not all of them. The analysis of impurities following ISO 14687:2019 remains expensive and complex, enhancing the need for further research in this area. Novel and promising analyzers have been developed which need to be validated according to ISO 21087:2019 requirements. © 2021 Beurey, Gozlan, Carré, Bacquart, Morris, Moore, Arrhenius, Meuzelaar, Persijn, Rojo and Murugan.
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| 7. |
- Haloua, Frederique, et al.
(author)
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Metrology for hydrogen energy applications : a project to address normative requirements
- 2018
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In: Measurement science and technology. - : IOP Publishing. - 0957-0233 .- 1361-6501. ; 29:3
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Journal article (peer-reviewed)abstract
- Hydrogen represents a clean and storable energy solution that could meet worldwide energy demands and reduce greenhouse gases emission. The joint research project (JRP) ‘Metrology for sustainable hydrogen energy applications’ addresses standardisation needs through pre- and co-normative metrology research in the fast emerging sector of hydrogen fuel that meet the requirements of the European Directive 2014/94/EU by supplementing the revision of two ISO standards that are currently too generic to enable a sustainable implementation of hydrogen. The hydrogen purity dispensed at refueling points should comply with the technical specifications of ISO 14687-2 for fuel cell electric vehicles. The rapid progress of fuel cell technology now requires revising this standard towards less constraining limits for the 13 gaseous impurities. In parallel, optimized validated analytical methods are proposed to reduce the number of analyses. The study aims also at developing and validating traceable methods to assess accurately the hydrogen mass absorbed and stored in metal hydride tanks; this is a research axis for the revision of the ISO 16111 standard to develop this safe storage technique for hydrogen. The probability of hydrogen impurity presence affecting fuel cells and analytical techniques for traceable measurements of hydrogen impurities will be assessed and new data of maximum concentrations of impurities based on degradation studies will be proposed. Novel validated methods for measuring the hydrogen mass absorbed in hydrides tanks AB, AB2 and AB5 types referenced to ISO 16111 will be determined, as the methods currently available do not provide accurate results. The outputs here will have a direct impact on the standardisation works for ISO 16111 and ISO 14687-2 revisions in the relevant working groups of ISO/TC 197 ‘Hydrogen technologies’.
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