| 1. |
- Andersson, Erik, et al.
(author)
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Enabling Green and Blue Infrastructure to Improve Contributions to Human Well-Being and Equity in Urban Systems
- 2019
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In: BioScience. - : Oxford University Press (OUP). - 0006-3568 .- 1525-3244. ; 69:7, s. 566-574
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Journal article (peer-reviewed)abstract
- The circumstances under which different ecosystem service benefits can be realized differ. The benefits tend to be coproduced and to be enabled by multiple interacting social, ecological, and technological factors, which is particularly evident in cities. As many cities are undergoing rapid change, these factors need to be better understood and accounted for, especially for those most in need of benefits. We propose a framework of three systemic filters that affect the flow of ecosystem service benefits: the interactions among green, blue, and built infrastructures; the regulatory power and governance of institutions; and people's individual and shared perceptions and values. We argue that more fully connecting green and blue infrastructure to its urban systems context and highlighting dynamic interactions among the three filters are key to understanding how and why ecosystem services have variable distribution, continuing inequities in who benefits, and the long-term resilience of the flows of benefits.
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| 2. |
- Estrader, Marta, et al.
(author)
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Origin of the large dispersion of magnetic properties in nanostructured oxides : FexO/Fe3O4 nanoparticles as a case study
- 2015
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In: Nanoscale. - : Royal Society of Chemistry (RSC). - 2040-3364 .- 2040-3372. ; 7:7, s. 3002-3015
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Journal article (peer-reviewed)abstract
- The intimate relationship between stoichiometry and physicochemical properties in transition-metal oxides makes them appealing as tunable materials. These features become exacerbated when dealing with nanostructures. However, due to the complexity of nanoscale materials, establishing a distinct relationship between structure-morphology and functionalities is often complicated. In this regard, in the FexO/Fe3O4 system a largely unexplained broad dispersion of magnetic properties has been observed. Here we show, thanks to a comprehensive multi-technique approach, a clear correlation between the magneto-structural properties in large (45 nm) and small (9 nm) FexO/Fe3O4 core/shell nanoparticles that can explain the spread of magnetic behaviors. The results reveal that while the FexO core in the large nanoparticles is antiferromagnetic and has bulk-like stoichiometry and unit-cell parameters, the FexO core in the small particles is highly non-stoichiometric and strained, displaying no significant antiferromagnetism. These results highlight the importance of ample characterization to fully understand the properties of nanostructured metal oxides.
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| 3. |
- Estrader, M., et al.
(author)
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Robust antiferromagnetic coupling in hard-soft bi-magnetic core/shell nanoparticles
- 2013
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In: Nature Communications. - : Springer Science and Business Media LLC. - 2041-1723. ; 4
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Journal article (peer-reviewed)abstract
- The growing miniaturization demand of magnetic devices is fuelling the recent interest in bi-magnetic nanoparticles as ultimate small components. One of the main goals has been to reproduce practical magnetic properties observed so far in layered systems. In this context, although useful effects such as exchange bias or spring magnets have been demonstrated in core/shell nanoparticles, other interesting key properties for devices remain elusive. Here we show a robust antiferromagnetic (AFM) coupling in core/shell nanoparticles which, in turn, leads to the foremost elucidation of positive exchange bias in bi-magnetic hard-soft systems and the remarkable regulation of the resonance field and amplitude. The AFM coupling in iron oxide-manganese oxide based, soft/hard and hard/soft, core/shell nanoparticles is demonstrated by magnetometry, ferromagnetic resonance and X-ray magnetic circular dichroism. Monte Carlo simulations prove the consistency of the AFM coupling. This unique coupling could give rise to more advanced applications of bi-magnetic core/shell nanoparticles.
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| 4. |
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| 6. |
- Łaszkiewicz, Edyta, et al.
(author)
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Greenery in urban morphology : a comparative analysis of differences in urban green space accessibility for various urban structures across European cities
- 2022
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In: Ecology and Society. - 1708-3087. ; 27:3
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Journal article (peer-reviewed)abstract
- The understanding of urban social-ecological systems requires integrated and interdisciplinary methods. This paper explores differences in the accessibility of urban green spaces (UGS) based on urban morphology. In contrast to other comparative analyses that followed simplified quantification of UGS provision and/or omitted the impact of morphological properties of urban space, this study proposes three improvements. First, it uses the share of UGS in the service area of 300 m walking distance around each residential building in a city as a measure of UGS provision. Second, it includes the potential physical accessibility of UGS as warranted by key actors, such as owners or managers, who decide whether UGS are open or not to potential users. Third, it links UGS accessibility and heterogeneous urban structures. We developed a mixed-methods analysis that combines multiple data sources regarding UGS, the spatial distribution of residential buildings, and street networks. We conducted our analysis in five case-study cities (Barcelona, Halle, Lodz, Oslo, and Stockholm). Our findings suggest that the urban structures where the human–environment interaction transformed the space (such as in the core city areas) are characterized by limited UGS in the service area. Urban structures that are less transformed by human activity (especially suburbia) have the highest share of selected UGS in the service area. In addition, even if the share of UGS in the service area is high, many of them might have limited physical accessibility. In the broader sense, this highlights that social-ecological processes are linked to urban form and cannot be separated in an analysis. Therefore, social-ecological systems could be better understood through the lens of urban morphology.
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| 7. |
- Lopez-Ortega, A., et al.
(author)
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Strongly exchange coupled inverse ferrimagnetic soft/hard, MnxFe3-xO4/FexMn3-xO4, core/shell heterostructured nanoparticles
- 2012
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In: Nanoscale. - : Royal Society of Chemistry (RSC). - 2040-3364 .- 2040-3372. ; 4:16, s. 5138-5147
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Journal article (peer-reviewed)abstract
- Inverted soft/hard, in contrast to conventional hard/soft, bi-magnetic core/shell nanoparticles of MnxFe3-xO4/FexMn3-xO4 with two different core sizes (7.5 and 11.5 nm) and fixed shell thickness (similar to 0.6 nm) have been synthesized. The structural characterization suggests that the particles have an interface with a graded composition. The magnetic characterization confirms the inverted soft/hard structure and evidences a strong exchange coupling between the core and the shell. Moreover, larger soft core sizes exhibit smaller coercivities and loop shifts, but larger blocking temperatures, as expected from spring-magnet or graded anisotropy structures. The results indicate that, similar to thin film systems, the magnetic properties of soft/hard core/shell nanoparticles can be fine tuned to match specific applications.
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| 8. |
- Salazar-Alvarez, G., et al.
(author)
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Cubic versus spherical magnetic nanoparticles : The role of surface anisotropy
- 2008
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In: Journal of the American Chemical Society. - : American Chemical Society (ACS). - 0002-7863 .- 1520-5126. ; 130:40, s. 13234-13239
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Journal article (peer-reviewed)abstract
- The magnetic properties of maghemite (gamma-Fe2O3) cubic and spherical nanoparticles of similar sizes have been experimentally and theoretically studied. The blocking temperature, TB, of the nanoparticles depends on their shape, with the spherical ones exhibiting larger TB. Other low temperature properties such as saturation magnetization, coercivity, loop shift or spin canting are rather similar. The experimental effective anisotropy and the Monte Carlo simulations indicate that the different random surface anisotropy of the two morphologies combined with the low magnetocrystalline anisotropy of gamma-Fe2O3 is the origin of these effects.
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| 9. |
- Venter, Zander S., et al.
(author)
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Interactive spatial planning of urban green infrastructure - Retrofitting green roofs where ecosystem services are most needed in Oslo
- 2021
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In: Ecosystem Services. - : Elsevier BV. - 2212-0416 .- 2212-0416. ; 50
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Journal article (peer-reviewed)abstract
- Spatial multi-criteria decision analysis (MCDA) is increasingly being used to inform urban green infrastructure planning. We explore the use of modern cloud computing technologies (Google Earth Engine) to facilitate public access to spatial MCDA of ecosystem services from green infrastructure. Using the spatial prioritization of green roof retrofitting in Oslo, Norway, as a case study, we present a web application that is a generalizable tool for engaging stakeholders in spatial planning of ecosystem restoration and nature-based solutions. In our application, green roof designers, owners and operators identified the relative importance of a suite of potential ecosystem services (ES) gained from retrofitting of green roofs, conditional on preference profiles expected by users of different building functional types. The ES assessed included temperature regulation, stormwater runoff mitigation, habitat for biodiversity, aesthetic value, and noise reduction. In Oslo we found high spatial correlation in ES deficits, implying that even large differences in stakeholder preferences for individual ES will lead MCDA to identify common interests in the spatial targeting of green roofs. Nevertheless, we found the interactive spatial MCDA web application to have potential for improving planning process efficiency in engaging stakeholders. In more heterogenous urban landscapes, with lower spatial correlation of individual ES, spatial MCDA also has scope to improve the output efficiency of spatial targeting of nature-based solutions such as green roofs. Link to web application: https://nina.earthengine.app/view/green-roof-mcda.
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