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- Bogdanova, Svetlana, et al.
(author)
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Volgo-Uralia: The First U-Pb, Lu-Hf and Sm-Nd Isotopic Evidence of Preserved Paleoarchean Crust
- 2010
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In: American Journal of Science. - : American Journal of Science (AJS). - 0002-9599. ; 310:10, s. 1345-1383
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Journal article (peer-reviewed)abstract
- The crustal segment Volgo-Uralia is the least known part of the East European Craton. Its crystalline crust is hidden beneath a thick Neoproterozoic to Phanerozoic cover but disclosed by thousands of drill holes. In conjunction with the recent "Tatseis" reflection seismic profile, we conducted the first isotopic study of the Bakaly granitoid block in eastern Volgo-Uralia, which represents a subsurface section of the layered upper-middle crust. The study included whole-rock Sm-Nd and ion-probe zircon U-Th-Pb (SIMS) and Lu-Hf (LA-ICPMS) analyses of granitoids from seven drill cores. The Bakaly block was also targeted because its rocks have never been subjected to granulite facies metamorphism, making it possible to date pristine, pre-metamorphic zircon. Our study showed that the four principal suites of granitoids in the Bakaly block are different in age, each corresponding to a particular stage of Archean crustal evolution between 3.3 and 2.6 Ga. The Tashliar monzonitic suite, belonging to an alkaline series yielded zircon ages of 3.3 and 3.2 Ga, which are the oldest ages yet found in Volgo-Urafia. The epsilon(Hf)(T) values of the dated zircon and the epsilon(Nd)(T) values of their host rocks indicate that a Paleo- to Eoarchean protolith with model T-DM ages up to 3.8 Ga had been involved in the formation of the Tashliar melts. Three Neoarchean rock suites, one comprising quartz dioritic and tonalitic gneisses (the Bak 1), another K-rich granodiorites, granites and migmatites (the Bak 2), and the third monzonitic granitoids (the Aktanysh suite) were formed sequentially between 2.72 and 2.60 Ga. The 2.72 Ga Bak 1 suite is chemically diverse. It includes granitoids of the TTG type related to slab/subduction melts as well as rocks formed by the re-melting of older crust with whole-rock Nd T-DM and Hf T-DM model ages of 3.4 to 3.2 Ga. The 2.69 to 2.65 Ga Bak 2 suite was probably associated with a major collisional event, which defined the stacked structure of the Archean crust in Volgo-Uralia and its seismic layering. Our data suggest that the Bak 2 melts originated partly from juvenile sources with epsilon(Hf)(T) zircon values up to +4.8, as well as mixed crustal and juvenile mantle materials. Some crustal contamination of the melts appears to have occurred as evidenced by incorporated xenocrystic zircon. The chemical compositions of Bak 2 granitoids from the different plutons, their zircon epsilon(Hf) values, and the Hf- and Nd T-DM ages all mirror a heterogeneous, collisional, crustal structure. During post-collisional extension at 2.6 Ga, the intrusion of Aktanysh monzonitic granitoids took place. These rocks also bear evidence of a long crustal pre-history with Nd and Hf T-DM model ages of 3.3 to 3.5 Ga. The Aktanysh rocks are coeval with the Tuymazy gabbro-norite-anorthosite intrusions, which are widely distributed along post-collisional shear zones in the Bakaly block. They could have provided the heat necessary to melt the crust at this stage. Altogether, the isotopic evidence suggests several episodes of crustal growth and recycling possibly reaching back to 3.6 and 3.8 Ga. Metamorphic zircon rims show that the Archean crust in the Bakaly block were subjected to several tectonothermal overprints in the Paleoproterozoic between 2.4 and 1.9 Ga ago.
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| 2. |
- Bogdanova, Svetlana, et al.
(author)
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Danopolonian migmatization of Mesoproterozoic sedimentary rocks in southernmost Sweden: a SIMS zircon study
- 2014
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In: GFF. - : Informa UK Limited. - 2000-0863 .- 1103-5897. ; 136:2, s. 410-428
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Journal article (peer-reviewed)abstract
- To assess the age and origin of the metasedimentary migmatites in southernmost Sweden and their relationships with the Mesoproterozoic granitoid magmatism in the area, we have dated migmatite zircon using the secondary ion mass spectrometry U-Pb method. The studied metasedimentary migmatites, here called the Noteboda migmatites, occur along the southwestern boundary of the 1442 Ma Taghusa granitoid intrusion in southeastern Skane. They contain the mineral assemblage garnet + biotite +/- muscovite + cordierite + sillimanite + quartz + plagioclase + K-feldspar and were formed during a retrograde evolution from c. 750-720 degrees C and 6 kbar (peak conditions) to c. 675 degrees C and 4 kbar. Zircon is characterized by detrital cores surrounded by U-rich rims and overgrowths. Separate rounded metamorphic grains also exist. The age probability-density distribution peaks for detrital zircon are at c. 1700, 1670, 1650, 1610, 1570 and 1530 Ma. These ages suggest Gothian orogenic rocks in the present west as the most probable principal source. Sedimentation occurred after c. 1530 Ma, the age of the youngest detrital zircon, indicating the existence of a previously unknown period of Mesoproterozoic sedimentation in southernmost Sweden. A homogeneous zircon overgrowth yielded a concordant Pb-207/Pb-206 age of 1439 +/- 5 Ma, which dates the migmatization and is close to the age of the Taghusa intrusion. We conclude that the burial of the sediments down to c. 20 km, their metamorphism and progressive migmatization took place concurrently with granitic magmatism, NE-SW compression, folding and shearing of the crust between 1460 and 1440Ma during the Danopolonian orogeny.
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| 5. |
- Claesson, Stefan, 1950-, et al.
(author)
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The oldest crust in the Ukrainian Shield - Eoarchaean U-Pb ages and Hf-Nd constraints from enderbites and metasediments
- 2014
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In: Continent Formation Through Time. - London : The Geological Society Publishing House.
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Book chapter (peer-reviewed)abstract
- The oldest crust in the Ukrainian Shield occurs in the Podolian and Azov domains which both include Eoarchaeanarchaean components. U-Pb age data for Dniestr-Bug enderbites, Podolian Domain, indicate these are ca. 3.75 Ga old, and Lu-Hf isotope date indicate extraction from chondritic to mildly isotopically depleted sources with εHf up to ca. +2. Nd model ages support their Eoarchaeanarchaean age, while model ages for Dniestr-Bug metasedimentary gneisses indicate that these also include younger crustal material. Most of the Hf-age data for metasedimentary zircon from the Soroki greenstone belt, Azov Domain, reflects Eoarchaeanarchaean primary crustal sources with chondritic to mildly depleted Hf isotope signatures at 3.75 Ga. A minor portion is derived from Mesoarchaeanarchaean crust with a depleted εHf signature of ca. +4 at 3.1 Ga. U-Pb zircon ages from Fedorivka greenstone belt metasediments are consistent with the Soroki age data, but also include a 2.7‒2.9 Ga component. Nd whole rock model ages provide support for a younger crustal component in the latter. Both domains have been subject to Neoarchaeanarchaean, ca. 2.8 Ga, and Palaeoproterozoic, ca. 2.0 Ga metamorphism. The spatial distribution indicates that the Podolian and Azov domains have evolved independently of each other before the amalgamation of the Ukrainian Shield.
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| 6. |
- McMillan, Hilary, et al.
(author)
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Panta Rhei 2013-2015 : global perspectives on hydrology, society and change
- 2016
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In: Hydrological Sciences Journal. - : Taylor & Francis Group. - 0262-6667 .- 2150-3435. ; 61:7, s. 1174-1191
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Journal article (peer-reviewed)abstract
- In 2013, the International Association of Hydrological Sciences (IAHS) launched the hydrological decade 2013-2022 with the theme "Panta Rhei: Change in Hydrology and Society". The decade recognizes the urgency of hydrological research to understand and predict the interactions of society and water, to support sustainable water resource use under changing climatic and environmental conditions. This paper reports on the first Panta Rhei biennium 2013-2015, providing a comprehensive resource that describes the scope and direction of Panta Rhei. We bring together the knowledge of all the Panta Rhei working groups, to summarize the most pressing research questions and how the hydrological community is progressing towards those goals. We draw out interconnections between different strands of research, and reflect on the need to take a global view on hydrology in the current era of human impacts and environmental change. Finally, we look back to the six driving science questions identified at the outset of Panta Rhei, to quantify progress towards those aims.
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| 7. |
- Mohl, Melinda, et al.
(author)
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Titania nanofibers in gypsum composites : an antibacterial and cytotoxicology study
- 2014
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In: Journal of Material Chemistry B. - : Royal Society of Chemistry. - 2050-750X .- 2050-7518. ; 2:10, s. 1307-1316
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Journal article (peer-reviewed)abstract
- Further developments of antibacterial coatings based on photocatalytic nanomaterials could be a promising route towards potential environmentally friendly applications in households, public buildings and health care facilities. Hereby we describe a simple chemical approach to synthesize photocatalytic nanomaterial-embedded coatings using gypsum as a binder. Various types of TiO2 nanofiber-based photocatalytic materials (nitrogen-doped and/or palladium nanoparticle decorated) and their composites with gypsum were characterized by means of scanning (SEM) and transmission (TEM) electron microscopy as well as electron and X-ray diffraction (XRD) and energy-dispersive X-ray spectroscopy (EDX) techniques. These gypsum-based composites can be directly applied as commercially available paints on indoor walls. Herein we report that surfaces coated with photocatalytic composites exhibit excellent antimicrobial properties by killing both methicillin-sensitive Staphylococcus aureus (MSSA) and methicillin-resistant Staphylococcus aureus (MRSA) under blue light. In the case of MSSA cells, the palladium nanoparticle-decorated and nitrogen-doped TiO2 composites demonstrated the highest antimicrobial activity. For the MRSA strain even pure gypsum samples were proven to be efficient in eradicating Gram-positive human pathogens. The cytotoxicity of freestanding TiO2 nanofibers was revealed by analyzing the viability of HeLa cells using MTT and fluorescent cell assays.
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