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Search: WFRF:(Chang Chiawei)

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  • Shao, Yue, et al. (author)
  • Scalable Synthesis of Photoluminescent Single-Chain Nanoparticles by Electrostatic-Mediated Intramolecular Crosslinking
  • 2022
  • In: Angewandte Chemie International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 61:27
  • Journal article (peer-reviewed)abstract
    • We report the large-scale synthesis of photoluminescent single-chain nanoparticles (SCNPs) by electrostatic-mediated intramolecular crosslinking in a concentrated solution of 40 mg mL−1 by continuous addition of the free radical initiator. Poly(vinyl benzyl chloride) was charged by quaternization with vinyl-imidazolium for the intramolecular crosslinking by using 2,2-dimethoxy-2-phenylacetophenone (DMAP) as the radical initiator. Under the electrostatic repulsion thus interchain isolation, the intrachain crosslinking experiences the transition from coil through pearl-necklace to globular state. The SCNPs demonstrate strong photoluminescence in the visible range when the non-emissive units are confined thereby. Composition and microstructure of the SCNPs are tunable. The photoluminescent tadpole-like Janus SCNP can be used to selectively illuminate interfacial membranes while stabilizing the emulsions. 
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  • Result 1-1 of 1
Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Liu, Feng (1)
Wang, Yong-lei, 1983 ... (1)
Shao, Yue (1)
Tang, Zian (1)
Wen, Zhendong (1)
Chang, Chiawei (1)
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Wang, Chunyu (1)
Sun, Dayin (1)
Ye, Yilan (1)
Qiu, Dong (1)
Ke, Yubin (1)
Yang, Zhenzhong (1)
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University
Stockholm University (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
Year
2022 (1)

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