| 1. |
- Coutens, A., et al.
(författare)
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The ALMA-PILS survey: First detections of deuterated formamide and deuterated isocyanic acid in the interstellar medium
- 2016
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 590
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Tidskriftsartikel (refereegranskat)abstract
- Formamide (NH2CHO) has previously been detected in several star-forming regions and is thought to be a precursor for different prebiotic molecules. Its formation mechanism is still debated, however. Observations of formamide, related species, and their isopotologues may provide useful clues to the chemical pathways leading to their formation. The Protostellar Interferometric Line Survey (PILS) represents an unbiased, high angular resolution and sensitivity spectral survey of the low-mass protostellar binary IRAS 16293-2422 with the Atacama Large Millimeter/submillimeter Array (ALMA). For the first time, we detect the three singly deuterated forms of NH2CHO (NH2CDO, cis-and trans-NHDCHO), as well as DNCO towards the component B of this binary source. The images reveal that the different isotopologues are all present in the same region. Based on observations of the 13C isotopologues of formamide and a standard 12C/13C ratio, the deuterium fractionation is found to be similar for the three different forms with a value of about 2%. The DNCO/HNCO ratio is also comparable to the D/H ratio of formamide (~1%). These results are in agreement with the hypothesis that NH2CHO and HNCO are chemically related through grain-surface formation.
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| 2. |
- Fayolle, E. C., et al.
(författare)
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Protostellar and cometary detections of organohalogens
- 2017
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Ingår i: Nature Astronomy. - : Springer Science and Business Media LLC. - 2397-3366. ; 1:10, s. 703-708
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Tidskriftsartikel (refereegranskat)abstract
- Organohalogens, a class of molecules that contain at least one halogen atom bonded to carbon, are abundant on the Earth where they are mainly produced through industrial and biological processes(1). Consequently, they have been proposed as biomarkers in the search for life on exoplanets(2). Simple halogen hydrides have been detected in interstellar sources and in comets, but the presence and possible incorporation of more complex halogen-containing molecules such as organohalogens into planet-forming regions is uncertain(3,4). Here we report the interstellar detection of two isotopologues of the organohalogen CH3Cl and put some constraints on CH3F in the gas surrounding the low-mass protostar IRAS 16293-2422, using the Atacama Large Millimeter/submillimeter Array (ALMA). We also find CH3Cl in the coma of comet 67P/Churyumov-Gerasimenko (67P/C-G) by using the Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA) instrument. The detections reveal an efficient pre-planetary formation pathway of organohalogens. Cometary impacts may deliver these species to young planets and should thus be included as a potential abiotical production source when interpreting future organohalogen detections in atmospheres of rocky planets.
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| 3. |
- Lykke, J. M., et al.
(författare)
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The ALMA-PILS survey: First detections of ethylene oxide, acetone and propanal toward the low-mass protostar IRAS 16293-2422
- 2017
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 597, s. A53-
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Tidskriftsartikel (refereegranskat)abstract
- Context. One of the open questions in astrochemistry is how complex organic and prebiotic molecules are formed. The unsurpassed sensitivity of the Atacama Large Millimeter/submillimeter Array (ALMA) takes the quest for discovering molecules in the warm and dense gas surrounding young stars to the next level. Aims. Our aim is to start the process of compiling an inventory of oxygen-bearing complex organic molecules toward the solar-type Class 0 protostellar binary IRAS 16293-2422 from an unbiased spectral survey with ALMA, Protostellar Interferometric Line Survey (PILS). Here we focus on the new detections of ethylene oxide (c-C2H4O), acetone (CH3COCH3), and propanal (C2H5CHO). Methods. With ALMA, we surveyed the spectral range from 329 to 363 GHz at 0.5? (60 AU diameter) resolution. Using a simple model for the molecular emission in local thermodynamical equilibrium, the excitation temperatures and column densities of each species were constrained. Results. We successfully detect propanal (44 lines), ethylene oxide (20 lines) and acetone (186 lines) toward one component of the protostellar binary, IRAS 16293B. The high resolution maps demonstrate that the emission for all investigated species originates from the compact central region close to the protostar. This, along with a derived common excitation temperature of Tex ? 125 K, is consistent with a coexistence of these molecules in the same gas. Conclusions. The observations mark the first detections of acetone, propanal and ethylene oxide toward a low-mass protostar. The relative abundance ratios of the two sets of isomers, a CH3COCH3/C2H5CHO ratio of 8 and a CH3CHO/c-C2H4O ratio of 12, are comparable to previous observations toward high-mass protostars. The majority of observed abundance ratios from these results as well as those measured toward high-mass protostars are up to an order of magnitude above the predictions from chemical models. This may reflect either missing reactions or uncertain rates in the chemical networks. The physical conditions, such as temperatures or densities, used in the models, may not be applicable to solar-type protostars either.
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| 4. |
- Murillo, N. M., et al.
(författare)
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Tracing the cold and warm physico-chemical structure of deeply embedded protostars: IRAS 16293−2422 versus VLA 1623−2417 N.
- 2018
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 617
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Tidskriftsartikel (refereegranskat)abstract
- Context. Much attention has been placed on the dust distribution in protostellar envelopes, but there are still many unanswered questions regarding the physico-chemical structure of the gas. Aims. Our aim is to start identifying the factors that determine the chemical structure of protostellar regions, by studying and com- paring low-mass embedded systems in key molecular tracers. Methods. The cold and warm chemical structures of two embedded Class 0 systems, IRAS 16293−2422 and VLA 1623−2417 were characterized through interferometric observations. DCO+, N2H+, and N2D+ were used to trace the spatial distribution and physics of the cold regions of the envelope, while c−C3H2 and C2H from models of the chemistry are expected to trace the warm (UV-irradiated) regions. Results. The two sources show a number of striking similarities and differences. DCO+ consistently traces the cold material at the disk-envelope interface, where gas and dust temperatures are lowered due to disk shadowing. N2H+ and N2D+, also tracing cold gas, show low abundances toward VLA 1623−2417, but for IRAS 16293−2422, the distribution of N2D+ is consistent with the same chemical models that reproduce DCO+. The two systems show different spatial distributions c−C3H2 and C2H. For IRAS 16293−2422, c−C3H2 traces the outflow cavity wall, while C2H is found in the envelope material but not the outflow cavity wall. In contrast, toward VLA 1623−2417 both molecules trace the outflow cavity wall. Finally, hot core molecules are abundantly observed toward IRAS 16293−2422 but not toward VLA 1623−2417. Conclusions. We identify temperature as one of the key factors in determining the chemical structure of protostars as seen in gaseous molecules. More luminous protostars, such as IRAS 16293−2422, will have chemical complexity out to larger distances than colder protostars, such as VLA 1623−2417. Additionally, disks in the embedded phase have a crucial role in controlling both the gas and dust temperature of the envelope, and consequently the chemical structure. Key
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| 5. |
- van der Wiel, M. H. D., et al.
(författare)
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The ALMA-PILS survey: gas dynamics in IRAS 16293-2422 and the connection between its two protostars
- 2019
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 626
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Tidskriftsartikel (refereegranskat)abstract
- Context. The majority of stars form in binary or higher order systems. The evolution of each protostar in a multiple system may start at different times and may progress differently. The Class 0 protostellar system IRAS 16293-2422 contains two protostars, "A" and "B", separated by similar to 600 au and embedded in a single, 10(4) au scale envelope. Their relative evolutionary stages have been debated. Aims. We aim to study the relation and interplay between the two protostars A and B at spatial scales of 60 au up to similar to 10(3) au. Methods. We selected molecular gas line transitions of the species CO, H2CO, HCN, CS, SiO, and C2H from the ALMA-PILS spectral imaging survey (329-363 GHz) and used them as tracers of kinematics, density, and temperature in the IRAS 16293-2422 system. The angular resolution of the PILS data set allows us to study these quantities at a resolution of 0.5 '' (60 au at the distance of the source). Results. Line-of-sight velocity maps of both optically thick and optically thin molecular lines reveal: (i) new manifestations of previously known outflows emanating from protostar A; (ii) a kinematically quiescent bridge of dust and gas spanning between the two protostars, with an inferred density between 4 x 10(4) cm(-3) and similar to 3 x 10(7) cm(-3); and (iii) a separate, straight filament seemingly connected to protostar B seen only in C2H, with a flat kinematic signature. Signs of various outflows, all emanating from source A, are evidence of high-density and warmer gas; none of them coincide spatially and kinematically with the bridge. Conclusions. We hypothesize that the bridge arc is a remnant of filamentary substructure in the protostellar envelope material from which protostellar sources A and B have formed. One particular morphological structure appears to be due to outflowing gas impacting the quiescent bridge material. The continuing lack of clear outflow signatures unambiguously associated to protostar B and the vertically extended shape derived for its disk-like structure lead us to conclude that source B may be in an earlier evolutionary stage than source A.
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| 6. |
- Calcutt, Hannah, 1988, et al.
(författare)
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The ALMA-PILS survey: first detection of methyl isocyanide (CH3NC) in a solar-type protostar
- 2018
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 617
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Tidskriftsartikel (refereegranskat)abstract
- Methyl isocyanide (CH3NC) is the isocyanide with the largest number of atoms confirmed in the interstellar medium (ISM), but it is not an abundant molecule, having only been detected towards a handful of objects. Conversely, its isomer, methyl cyanide (CH3CN), is one of the most abundant complex organic molecules detected in the ISM, with detections in a variety of low- and high-mass sources. We use ALMA observations from the Protostellar Interferometric Line Survey (PILS) to search for methyl isocyanide and compare its abundance with that of its isomer methyl cyanide. We use a new line catalogue from the Cologne Database for Molecular Spectroscopy (CDMS) to identify methyl isocyanide lines. We also model the chemistry with an updated version of the three-phase chemical kinetics model MAGICKAL, presenting the first chemical modelling of methyl isocyanide to date. We detect methyl isocyanide for the first time in a solar-type protostar, IRAS 16293-2422 B, and present upper limits for its companion protostar, IRAS 16293-2422 A. Methyl isocyanide is found to be at least 20 times more abundant in source B compared to source A, with a CH3CN/CH3NC abundance ratio of 200 in IRAS 16293-2422 B and >5517 in IRAS 16293-2422 A. We also present the results of a chemical model of methyl isocyanide chemistry in both sources, and discuss the implications on methyl isocyanide formation mechanisms and the relative evolutionary stages of both sources.
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| 7. |
- Coutens, A., et al.
(författare)
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First detection of cyanamide (NH2CN) towards solar-type protostars
- 2018
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 612
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Tidskriftsartikel (refereegranskat)abstract
- Searches for the prebiotically relevant cyanamide (NH 2 CN) towards solar-type protostars have not been reported in the literature. We present here the first detection of this species in the warm gas surrounding two solar-type protostars, using data from the Atacama Large Millimeter/Submillimeter Array Protostellar Interferometric Line Survey (PILS) of IRAS 16293-2422 B and observations from the IRAM Plateau de Bure Interferometer of NGC 1333 IRAS2A. We also detected the deuterated and 13 C isotopologs of NH 2 CN towards IRAS 16293-2422 B. This is the first detection of NHDCN in the interstellar medium. Based on a local thermodynamic equilibrium analysis, we find that the deuteration of cyanamide (∼1.7%) is similar to that of formamide (NH 2 CHO), which may suggest that these two molecules share NH 2 as a common precursor. The NH 2 CN/NH 2 CHO abundance ratio is about 0.2 for IRAS 16293-2422 B and 0.02 for IRAS2A, which is comparable to the range of values found for Sgr B2. We explored the possible formation of NH 2 CN on grains through the NH 2 + CN reaction using the chemical model MAGICKAL. Grain-surface chemistry appears capable of reproducing the gas-phase abundance of NH 2 CN with the correct choice of physical parameters.
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| 8. |
- Jorgensen, J. K., et al.
(författare)
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The ALMA Protostellar Interferometric Line Survey (PILS) First results from an unbiased submillimeter wavelength line survey of the Class 0 protostellar binary IRAS 16293-2422 with ALMA
- 2016
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 595, s. Art no A117-
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Tidskriftsartikel (refereegranskat)abstract
- Context. The inner regions of the envelopes surrounding young protostars are characterized by a complex chemistry, with prebiotic molecules present on the scales where protoplanetary disks eventually may form. The Atacama Large Millimeter/submillimeter Array (ALMA) provides an unprecedented view of these regions zooming in on solar system scales of nearby protostars and mapping the emission from rare species. Aims. The goal is to introduce a systematic survey, the Protostellar Interferometric Line Survey (PILS), of the chemical complexity of one of the nearby astrochemical templates, the Class 0 protostellar binary IRAS 16293 2422, using ALMA in order to understand the origin of the complex molecules formed in its vicinity. In addition to presenting the overall survey, the analysis in this paper focuses on new results for the prebiotic molecule glycolaldehyde, its isomers, and rarer isotopologues and other related molecules. Methods. An unbiased spectral survey of IRAS 16293 2422 covering the full frequency range from 329 to 363 GHz (0.8 mm) has been obtained with ALMA, in addition to a few targeted observations at 3.0 and 1.3 mm. The data consist of full maps of the protostellar binary system with an angular resolution of 0.5 '' (60 AU diameter), a spectral resolution of 0.2 km s(-1), and a sensitivity of 4-5 mJy beam(-1) km s(-1), which is approximately two orders of magnitude better than any previous studies. Results. More than 10 000 features are detected toward one component in the protostellar binary, corresponding to an average line density of approximately one line per 3 km s(-1). Glycolaldehyde; its isomers, methyl formate and acetic acid; and its reduced alcohol, ethylene glycol, are clearly detected and their emission well-modeled with an excitation temperature of 300 K. For ethylene glycol both lowest state conformers, aGg' and gGg', are detected, the latter for the first time in the interstellar medium (ISM). The abundance of glycolaldehyde is comparable to or slightly larger than that of ethylene glycol. In comparison to the Galactic Center these two species are over-abundant relative to methanol, possibly an indication of formation of the species at low temperatures in CO-rich ices during the infall of the material toward the central protostar. Both C-13 and the deuterated isotopologues of glycolaldehyde are detected, also for the first time ever in the ISM. For the deuterated species, a D/H ratio of approximate to 5% is found with no differences between the deuteration in the different functional groups of glycolaldehyde, in contrast to previous estimates for methanol and recent suggestions of significant equilibration between water and-OH functional groups at high temperatures. Measurements of the C-13-species lead to a C-12:C-13 ratio of approximate to 30, lower than the typical ISM value. This low ratio may reflect an enhancement of (CO)-C-13 in the ice due to either ion-molecule reactions in the gas before freeze-out or to differences in the temperatures where (CO)-C-12 and (CO)-C-13 ices sublimate. Conclusions. The results reinforce the importance of low-temperature grain surface chemistry for the formation of prebiotic molecules seen here in the gas after sublimation of the entire ice mantle. Systematic surveys of the molecules thought to be chemically related, as well as the accurate measurements of their isotopic composition, hold strong promise for understanding the origin of prebiotic molecules in the earliest stages of young stars.
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| 9. |
- Ligterink, N. F. W., et al.
(författare)
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The ALMA-PILS survey: Stringent limits on small amines and nitrogen-oxides towards IRAS 16293–2422B
- 2018
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 619
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Tidskriftsartikel (refereegranskat)abstract
- Context. Hydroxylamine (NH2OH) and methylamine (CH3NH2) have both been suggested as precursors to the formation of amino acids and are therefore, of interest to prebiotic chemistry. Their presence in interstellar space and formation mechanisms, however, are not well established. Aims. We aim to detect both amines and their potential precursor molecules NO, N2O, and CH2NH towards the low-mass protostellar binary IRAS 16293–2422, in order to investigate their presence and constrain their interstellar formation mechanisms around a young Sun-like protostar. Methods. ALMA observations from the unbiased, high-angular resolution and sensitivity Protostellar Interferometric Line Survey (PILS) are used. Spectral transitions of the molecules under investigation are searched for with the CASSIS line analysis software. Results. CH2NH and N2O are detected for the first time, towards a low-mass source, the latter molecule through confirmation with the single-dish TIMASSS survey. NO is also detected. CH3NH2 and NH2OH are not detected and stringent upper limit column densities are determined. Conclusions. The non-detection of CH3NH2 and NH2OH limits the importance of formation routes to amino acids involving these species. The detection of CH2NH makes amino acid formation routes starting from this molecule plausible. The low abundances of CH2NH and CH3NH2 compared to Sgr B2 indicate that different physical conditions influence their formation in low- and high-mass sources.
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| 10. |
- Manigand, S., et al.
(författare)
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The ALMA-PILS survey: First detection of the unsaturated 3-carbon molecules Propenal (C2H3CHO) and Propylene (C3H6) towards IRAS 16293-2422 B
- 2021
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 645
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Tidskriftsartikel (refereegranskat)abstract
- Context. Complex organic molecules with three carbon atoms are found in the earliest stages of star formation. In particular, propenal (C2H3CHO) is a species of interest due to its implication in the formation of more complex species and even biotic molecules. Aims. This study aims to search for the presence of C2H3CHO and other three-carbon species such as propylene (C3H6) in the hot corino region of the low-mass protostellar binary IRAS 16293-2422 to understand their formation pathways. Methods. We use ALMA observations in Band 6 and 7 from various surveys to search for the presence of C3H6 and C2H3CHO towards the protostar IRAS 16293-2422 B (IRAS 16293B). The identification of the species and the estimates of the column densities and excitation temperatures are carried out by modeling the observed spectrum under the assumption of local thermodynamical equilibrium. Results. We report the detection of both C3H6 and C2H3CHO towards IRAS 16293B, however, no unblended lines were found towards the other component of the binary system, IRAS 16293A. We derive column density upper limits for C3H8, HCCCHO, n-C3H7OH, i-C3H7OH, C3O, and cis-HC(O)CHO towards IRAS 16293B. We then use a three-phase chemical model to simulate the formation of these species in a typical prestellar environment followed by its hydrodynamical collapse until the birth of the central protostar. Different formation paths, such as successive hydrogenation and radical-radical additions on grain surfaces, are tested and compared to the observational results in a number of different simulations, to assess which are the dominant formation mechanisms in the most embedded region of the protostar. Conclusions. The simulations reproduce the abundances within one order of magnitude from those observed towards IRAS 16293B, with the best agreement found for a rate of 10-12 cm3 s-1 for the gas-phase reaction C3 + O → C2 + CO. Successive hydrogenations of C3, HC(O)CHO, and CH3OCHO on grain surfaces are a major and crucial formation route of complex organics molecules, whereas both successive hydrogenation pathways and radical-radical addition reactions contribute to the formation of C2H5CHO.
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