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  • Yue, Bingbing, et al. (author)
  • Photoexcitation-Based Supramolecular Access to Full-Scale Phase-Diagram Structures through in situ Phase-Volume Ratio Phototuning
  • 2022
  • In: Angewandte Chemie International Edition. - : John Wiley & Sons. - 1433-7851 .- 1521-3773. ; 61:43
  • Journal article (peer-reviewed)abstract
    • Controlling phase separation and transition plays a core role in establishing and maintaining the function of diverse self-assembled systems. However, it remains challenging to achieve wide-range continuous phase transition for dynamically producing a variety of assembled structures. Here, we developed a far-from-equilibrium system, upon the integration of photoexcitation-induced aggregation molecules and block copolymers, to establish an in situ phase-volume ratio photocontrol strategy. Thus, full-scale phase-diagram structures, from lamellar structure to gyroidal, cylindrical, and finally to a spherical one, can be accessed under different irradiation periods. Moreover, the phase transition was accompanied by considerable aggregation-induced phosphorescence and hydrophilicity/hydrophobicity change for building a functional surface. This strategy allows for a conceptual advance of accessing a wide range of distinct self-assembled structures and functions in real time.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Baryshnikov, Glib (1)
Ågren, Hans (1)
Zhang, Man (1)
Zhu, Liangliang (1)
Jin, Xin (1)
Yue, Bingbing (1)
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Shen, Shen (1)
Jia, Xiaoyong (1)
Feng, Xicheng (1)
Lu, Yunle (1)
Luo, Mengkai (1)
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University
Uppsala University (1)
Linköping University (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
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