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1.	Balmes, Olivier, et al. (author) Reversible formation of a PdCx phase in Pd nanoparticles upon CO and O-2 exposure 2012 In: Physical Chemistry Chemical Physics. - : Royal Society of Chemistry (RSC). - 1463-9084 .- 1463-9076. ; 14:14, s. 4796-4801 Journal article (peer-reviewed)abstract The structure and chemical composition of Pd nanoparticles exposed to pure CO and mixtures of CO and O-2 at elevated temperatures have been studied in situ by a combination of X-ray Diffraction and X-ray Photoelectron Spectroscopy in pressures ranging from ultra high vacuum to 10 mbar and from room temperature to a few hundred degrees celsius. Our investigation shows that under CO exposure, above a certain temperature, carbon dissolves into the Pd particles forming a carbide phase. Upon exposure to CO and O-2 mixtures, the carbide phase forms and disappears reversibly, switching at the stoichiometric ratio for CO oxidation. This finding opens new scenarios for the understanding of catalytic oxidation of C-based molecules.
2.	Balmes, Olivier, et al. (author) Reversible Formation of Palladium Carbide on Palladium Nanoparticles under CO Oxidation Conditions 2012 Conference paper (peer-reviewed)
3.	van Rijn, Richard, et al. (author) Comment on "CO Oxidation on Pt-Group Metals from Ultrahigh Vacuum to Near Atmospheric Pressures. 2. Palladium and Platinum" 2010 In: Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 114:14, s. 6875-6876 Journal article (other academic/artistic)

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Type of publication: journal article (2); conference paper (1)

Type of content: peer-reviewed (2); other academic/artistic (1)

Author/Editor: Lundgren, Edvin (3); Felici, Roberto (3); Gustafson, Johan (3); Balmes, Olivier (3); Wermeille, Didier (3); van Rijn, Richard (3); show more...; Deppert, Knut (2); Andersen, Jesper N (2); Blomberg, Sara (2); Bluhm, Hendrik (2); Messing, Maria (2); Westerström, Rasmus (2); Resta, Andrea (2); Liu, Zhi (2); Grass, Michael E. (2); Frenken, Joost W. M. (2); Westerstroem, Rasmus (1); Frenken, Joost W (1); show less...

University: Lund University (3)

Language: English (3)

Research subject (UKÄ/SCB): Natural sciences (3)

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