1. |
- Kjær, Kurt H., et al.
(author)
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A 2-million-year-old ecosystem in Greenland uncovered by environmental DNA
- 2022
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In: Nature. - : Springer Nature. - 0028-0836 .- 1476-4687. ; 612:7939, s. 283-291
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Journal article (peer-reviewed)abstract
- Late Pliocene and Early Pleistocene epochs 3.6 to 0.8 million years ago1 had climates resembling those forecasted under future warming2. Palaeoclimatic records show strong polar amplification with mean annual temperatures of 11–19 °C above contemporary values3,4. The biological communities inhabiting the Arctic during this time remain poorly known because fossils are rare5. Here we report an ancient environmental DNA6 (eDNA) record describing the rich plant and animal assemblages of the Kap København Formation in North Greenland, dated to around two million years ago. The record shows an open boreal forest ecosystem with mixed vegetation of poplar, birch and thuja trees, as well as a variety of Arctic and boreal shrubs and herbs, many of which had not previously been detected at the site from macrofossil and pollen records. The DNA record confirms the presence of hare and mitochondrial DNA from animals including mastodons, reindeer, rodents and geese, all ancestral to their present-day and late Pleistocene relatives. The presence of marine species including horseshoe crab and green algae support a warmer climate than today. The reconstructed ecosystem has no modern analogue. The survival of such ancient eDNA probably relates to its binding to mineral surfaces. Our findings open new areas of genetic research, demonstrating that it is possible to track the ecology and evolution of biological communities from two million years ago using ancient eDNA.
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2. |
- Arvhult, Carl, et al.
(author)
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Thermodynamic assessment of the Fe-Te system. Part I : Experimental study
- 2019
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In: Journal of Alloys and Compounds. - : Elsevier. - 0925-8388 .- 1873-4669. ; 773, s. 314-326
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Journal article (peer-reviewed)abstract
- A thermodynamic description of the Fe-Te system needs to be developed in order to model internal corrosion by fission products in fuel pins of Generation IV nuclear reactors. In preparation for a thermodynamic assessment of the system, an experimental study has been performed in order to clarify some unknown or conflicting phase diagram data. New phase diagram data have been obtained using Differential Thermal Analysis and isothermal heat treatments followed by electron microscopy with EDS and WDS analysis. The DTA analysis revealed new phase boundary data, and confirmed a very steep Fe-rich liquidus, supporting the possibility of a liquid miscibility gap in the Fe-FeTe region. The analyses also confirmed the probable eutectoid reaction δ→β+δ’ at 523 °C. The invariant arrests of the unknown γ phase were consistent with information available in literature, but the phase was not identified via XRD of samples at its postulated composition. However, metallography of the samples revealed an unexpected microstructure pertaining to the δ phase, which might be the γ phase, and is discussed in this paper. The monoclinic space group C2/m is proposed for the δ phase based on XRD. The collected data will be used together with that available in literature to perform a thermodynamic Calphad assessment in a subsequent paper Part II: Thermodynamic modeling.
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3. |
- Arvhult, Carl-M, et al.
(author)
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Thermodynamic assessment of the Fe-Te system. Part II : Thermodynamic modeling
- 2018
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In: Journal of Alloys and Compounds. - : Elsevier. - 0925-8388 .- 1873-4669. ; 767, s. 883-893
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Journal article (peer-reviewed)abstract
- A thermodynamic description of the Fe-Te system modeled via the Calphad method is proposed, based on data published in a preceding publication Part I: Experimental study, and that available in literature. End-member formation energies for the phases beta, beta', delta, delta' and epsilon, as well as lattice stabilities of FCC and BCC tellurium, have been evaluated via DFT and used in the numerical optimization. The final Gibbs energy models fit thermodynamic and phase diagram data well, and inconsistencies are discussed. The thermodynamic description is then used to evaluate Gibbs energy of formation for selected Fe-Te compounds of interest for the modeling of internal corrosion of stainless steel fuel pin cladding during operation of Liquid Metal-cooled Fast Reactors (LMFR).
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4. |
- Arvhult, Carl, et al.
(author)
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Thermodynamic assessment of the Fe–Ni–Te system
- 2019
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In: Calphad. - : Elsevier. - 0364-5916 .- 1873-2984. ; 67
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Journal article (peer-reviewed)abstract
- For the purpose of modeling internal corrosion of the stainless steel fuel pins in fast nuclear reactors, the present work presents a thermodynamic description of the Fe–Ni–Te system modeled via the Calphad method. The liquid phase was modeled using the ionic 2-sublattice liquid model. Only binary parameters were optimized in the β2, δ and τ solid phases, to fit the isothermal section at 600 °C. The liquid did not require much adjustment from the extrapolation from the binary Fe–Te, Ni–Te and Fe–Ni systems. The paper presents a re-optimization of the Fe–Te liquid description in order to remove inverted liquid miscibility gaps at high temperatures. The resulting phase diagrams reproduce experimental isothermal sections well, and fits liquidus and solidus data very well. The description will be incorporated into the Thermodynamics of Advanced Fuels - International Database (TAF-ID). This will then be coupled with the Germinal system code to model the fission-product induced corrosion in nuclear fuel pins.
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5. |
- Davies, Neil S., et al.
(author)
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Wood jams or beaver dams? : pliocene life, sediment and landscape interactions in the Canadian High Arctic
- 2022
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In: Palaios. - : Society for Sedimentary Geology. - 0883-1351 .- 1938-5323. ; 37:6, s. 330-347
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Journal article (peer-reviewed)abstract
- During the mid-Pliocene (Zanclean, ca. ∼ 3.9 Ma), parts of the Canadian High Arctic experienced mean annual temperatures that were 14–22°C warmer than today and supported diverse boreal-type forests. The landscapes of this vegetated polar region left behind a fragmented sedimentary record that crops out across several islands in the Canadian Arctic Archipelago as the Beaufort Formation and correlative strata. Paleoecological information from these strata provides a high-fidelity window onto Pliocene environments, and prominent fossil sites yield unparalleled insights into Cenozoic mammal evolution. Significantly, many of the strata reveal evidence for life-sediment interactions in a warm-climate Arctic, most notably in the form of extensive woody debris and phytoclast deposits. This paper presents original field data that refines the sedimentological context of plant debris accumulations from the anactualistic High Arctic forests, most notably at the ‘Fyles Leaf Beds' and ‘Beaver Pond' fossil-bearing sites in the ‘high terrace deposits' of central Ellesmere Island. The former is a remarkably well-preserved, leaf-rich deposit that is part of a complex of facies associations representing lacustrine, fluvio-deltaic and mire deposition above a paleotopographic unconformity. The latter yields tooth-marked woody debris within a peat layer that also contains a rich assemblage of vertebrate and plant fossils including abundant remains from the extinct beaver-group Dipoides. Here we present sedimentological data that provide circumstantial evidence that the woody debris deposit at Beaver Pond could record dam-building in the genus, by comparing the facies motif with new data from known Holocene beaver dam facies in England. Across the Pliocene of the High Arctic region, woody debris accumulations are shown to represent an array of biosedimentary deposits and landforms including mires, driftcretions, woody bedforms, and possible beaver dams, which help to contextualize mammal fossil sites, provide facies models for high-latitude forests, and reveal interactions between life and sedimentation in a vanished world that may be an analogue to that of the near-future.
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6. |
- Journeau, C., et al.
(author)
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Safest roadmap for corium experimental research in Europe
- 2018
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In: ASCE-ASME J of Risk & Uncertainty in Engineering Systems Part B. - : ASME Press. - 2332-9017 .- 2332-9025. ; 4:3
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Journal article (peer-reviewed)abstract
- Severe accident facilities for European safety targets (SAFEST) is a European project networking the European experimental laboratories focused on the investigation of a nuclear power plant (NPP) severe accident (SA) with reactor core melting and formation of hazardous material system known as corium. The main objective of the project is to establish coordinated activities, enabling the development of a common vision and severe accident research roadmaps for the next years, and of the management structure to achieve these goals. In this frame, a European roadmap on severe accident experimental research has been developed to define research challenges to contribute to further reinforcement of Gen II and III NPP safety. The roadmap takes into account different SA phenomena and issues identified and prioritized in the analyses of severe accidents at commercial NPPs and in the results of the recent European stress tests carried out after the Fukushima accident. Nineteen relevant issues related to reactor core meltdown accidents have been selected during these efforts. These issues have been compared to a survey of the European SA research experimental facilities and corium analysis laboratories. Finally, the coherence between European infrastructures and R&D needs has been assessed and a table linking issues and infrastructures has been derived. The comparison shows certain important lacks in SA research infrastructures in Europe, especially in the domains of core late reflooding impact on source term, reactor pressure vessel failure and molten core release modes, spent fuel pool (SFP) accidents, as well as the need for a large-scale experimental facility operating with up to 500 kg of chemically prototypic corium melt.
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