| 1. |
- Alsufyani, Maryam, et al.
(author)
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Lactone Backbone Density in Rigid Electron-Deficient Semiconducting Polymers Enabling High n-type Organic Thermoelectric Performance
- 2022
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In: Angewandte Chemie International Edition. - : WILEY-V C H VERLAG GMBH. - 1433-7851 .- 1521-3773. ; 61:7
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Journal article (peer-reviewed)abstract
- Three lactone-based rigid semiconducting polymers were designed to overcome major limitations in the development of n-type organic thermoelectrics, namely electrical conductivity and air stability. Experimental and theoretical investigations demonstrated that increasing the lactone group density by increasing the benzene content from 0 % benzene (P-0), to 50 % (P-50), and 75 % (P-75) resulted in progressively larger electron affinities (up to 4.37 eV), suggesting a more favorable doping process, when employing (N-DMBI) as the dopant. Larger polaron delocalization was also evident, due to the more planarized conformation, which is proposed to lead to a lower hopping energy barrier. As a consequence, the electrical conductivity increased by three orders of magnitude, to achieve values of up to 12 S cm and Power factors of 13.2 mu Wm(-1) K-2 were thereby enabled. These findings present new insights into material design guidelines for the future development of air stable n-type organic thermoelectrics.
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| 2. |
- Alsufyani, Maryam, et al.
(author)
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The effect of aromatic ring size in electron deficient semiconducting polymers for n-type organic thermoelectrics
- 2020
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In: Journal of Materials Chemistry C. - : ROYAL SOC CHEMISTRY. - 2050-7526 .- 2050-7534. ; 8:43, s. 15150-15157
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Journal article (peer-reviewed)abstract
- N-type semiconducting polymers have been recently utilized in thermoelectric devices, however they have typically exhibited low electrical conductivities and poor device stability, in contrast to p-type semiconductors, which have been much higher performing. This is due in particular to the n-type semiconductors low doping efficiency, and poor charge carrier mobility. Strategies to enhance the thermoelectric performance of n-type materials include optimizing the electron affinity (EA) with respect to the dopant to improve the doping process and increasing the charge carrier mobility through enhanced molecular packing. Here, we report the design, synthesis and characterization of fused electron-deficient n-type copolymers incorporating the electron withdrawing lactone unit along the backbone. The polymers were synthesized using metal-free aldol condensation conditions to explore the effect of enlarging the central phenyl ring to a naphthalene ring, on the electrical conductivity. When n-doped with N-DMBI, electrical conductivities of up to 0.28 S cm(-1), Seebeck coefficients of -75 mu V K-1 and maximum Power factors of 0.16 mu W m(-1) K-2 were observed from the polymer with the largest electron affinity of -4.68 eV. Extending the aromatic ring reduced the electron affinity, due to reducing the density of electron withdrawing groups and subsequently the electrical conductivity reduced by almost two orders of magnitude.
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| 3. |
- He, Wei, et al.
(author)
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Operational performance of a novel heat pump assisted solar facade loop-heat-pipe water heating system
- 2015
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In: Applied Energy. - : Elsevier BV. - 0306-2619 .- 1872-9118. ; 146, s. 371-382
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Journal article (peer-reviewed)abstract
- This paper aims to present an investigation into the operational performance of a novel heat pump assisted solar façade loop-heat-pipe (LHP) water heating system using both theoretical and experimental methods. This involved (1) development of a computer numerical model; (2) simulation of the operational performance of the system by using the model; (3) test rig construction; and (4) dedicated experiment for verification of the model. It was found that the established model is able to predict the operational performance of the system at a reasonable accuracy. Analyses of the research results indicated that under the selected testing conditions, the average thermal efficiency of the LHP module was around 71%, much higher than that of the loop heat pipe without heat pump assistance. The thermal efficiency of the LHP module grew when the heat pump was turned-on and fell when the heat pump was turned-off. The water temperature remained a steadily growing trend throughout the heat pump turned-on period. Neglecting the heat loss of the water tank, the highest coefficient of the performance could reach up to 6.14 and its average value was around 4.93. In overall, the system is a new façade integrated, highly efficient and aesthetically appealing solar water heating configuration; wide deployment of the system will help reduce fossil fuel consumption in the building sector and carbon emission to the environment.
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| 4. |
- He, Wei, et al.
(author)
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Recent development and application of thermoelectric generator and cooler
- 2015
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In: Applied Energy. - : Elsevier BV. - 0306-2619 .- 1872-9118. ; 143, s. 1-25
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Journal article (peer-reviewed)abstract
- Energy crisis and environment deterioration are two major problems for 21st century. Thermoelectric device is a promising solution for those two problems. This review begins with the basic concepts of the thermoelectric and discusses its recent material researches about the figure of merit. It also reports the recent applications of the thermoelectric generator, including the structure optimization which significantly affects the thermoelectric generator, the low temperature recovery, the heat resource and its application area. Then it reports the recent application of the thermoelectric cooler including the thermoelectric model and its application area. It ends with the discussion of the further research direction.
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| 5. |
- He, Wei, et al.
(author)
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Theoretical investigation of the thermal performance of a novel solar loop-heat-pipe facade-based heat pump water heating system
- 2014
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In: Energy and Buildings. - : Elsevier BV. - 0378-7788 .- 1872-6178. ; 77, s. 180-191
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Journal article (peer-reviewed)abstract
- The aim of the paper was to present a dedicated theoretical investigation into the thermal performance of a novel solar loop-heat-pipe façade based heat pump water heating system. This involved thermo-fluid analyses, computer numerical model development, the model running up, modelling result analyses and conclusion. An energy balance network was established on each part and the whole range of the system to address the associated energy conversion and transfer processes. On basis of this, a computer numerical model was developed and run up to predict the thermal performance of such a system at different system configurations, layouts and operational conditions. It was suggested that the loop heat pipes could be filled with either water, R134a, R22 or R600a; of which R600a is the favourite working fluid owing to its relatively larger heat transfer capacity and positive pressure in operation. Variations in the system configuration, i.e., glazing covers, heat exchangers, would lead to identifiable differences in the thermal performance of the system, represented by the thermal efficiency and COP. Furthermore, impact of the external operational parameters, i.e., solar radiation and ambient air temperature, to the system's thermal performance was also investigated. The research was based on an innovative loop-heat-pipe façade and came up with useful results reflecting the thermal performance of the combined system between the façade and heat pump. This would help promote development and market penetration of such an innovative solar heating technology, and thus contribute to achieving the global targets in energy saving and carbon emission reduction.
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| 6. |
- Marks, Adam, et al.
(author)
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Synthetic Nuances to Maximize n-Type Organic Electrochemical Transistor and Thermoelectric Performance in Fused Lactam Polymers
- 2022
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In: Journal of the American Chemical Society. - : American Chemical Society (ACS). - 0002-7863 .- 1520-5126. ; 144:10, s. 4642-4656
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Journal article (peer-reviewed)abstract
- A series of fully fused n-type mixed conduction lactam polymers p(g(7)NC(n)N), systematically increasing the alkyl side chain content, are synthesized via an inexpensive, nontoxic, precious-metal-free aldol polycondensation. Employing these polymers as channel materials in organic electrochemical transistors (OECTs) affords state-of-the-art n-type performance with p(g(7)NC(10)N) recording an OECT electron mobility of 1.20 x 10(-2) cm(2) V-1 s(-1) and a mu C* figure of merit of 1.83 F cm(-1) V-1 s(-1). In parallel to high OECT performance, upon solution doping with (4-(1,3-dimethyl-2,3-dihydro-1H-benzoimidazol-2-yl)phenyl)dimethylamine (N-DMBI), the highest thermoelectric performance is observed for p(g(7)NC(4)N), with a maximum electrical conductivity of 7.67 S cm(-1) and a power factor of 10.4 mu Wm(-1) K-2. These results are among the highest reported for n-type polymers. Importantly, while this series of fused polylactam organic mixed ionic-electronic conductors (OMIECs) highlights that synthetic molecular design strategies to bolster OECT performance can be translated to also achieve high organic thermoelectric (OTE) performance, a nuanced synthetic approach must be used to optimize performance. Herein, we outline the performance metrics and provide new insights into the molecular design guidelines for the next generation of high-performance n-type materials for mixed conduction applications, presenting for the first time the results of a single polymer series within both OECT and OTE applications.
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