| 1. |
- Andersson, Lise-Lotte, et al.
(författare)
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Classification of Superdeformed Bands in the Mass A~60 Region
- 2008
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Ingår i: Nuclear Physics and Astrophysics. - : AIP. - 9780735406032 ; 1072, s. 211-214
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Konferensbidrag (refereegranskat)abstract
- The experimental knowledge of the Cu-61(29)32 and Zn-61(30)31 nuclei has been largely extended via the joint results from three experiments. The fusion-evaporation reaction used a Ar-36 beam and a Si-28 target foil to produce the two nuclei via the evaporation of either three protons (Cu-61) or two protons and a neutron (Zn-61). The experimental set-ups comprised the Ge-array GAMMASPHERE as well as neutron and charged-particle detectors placed around the target position. The resulting level schemes include around ten rotational superdeformed structures in each isotope. Most of them are linked to normally deformed states and in many cases spins and parities of the low-lying states in each structure have been determined. The collective structures are compared with results from configuration dependent Cranked Nilsson-Strutinsky calculations. The different structures are in general well understood from the calculation but the results do also suggest modifications of the standard Nilsson parameters in the mass A similar to 60 region.
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| 2. |
- Andersson, Lise-Lotte, et al.
(författare)
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Extensive Gamma-ray Spectroscopy of Normally and Superdeformed Structures in 61Cu
- 2008
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Ingår i: European Physical Journal A. Hadrons and Nuclei. - : Springer Science and Business Media LLC. - 1434-6001. ; 36:3, s. 251-278
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Tidskriftsartikel (refereegranskat)abstract
- A largely extended experimental knowledge of the Cu-61(29)32 nucleus has been obtained from three experiments. Excited states in Cu-61 were produced via the fusion-evaporation reaction Si-28(Ar-36, 3p)Cu-61. In addition to the Ge array GAMMASPHERE, neutron and charged-particle detectors placed around the target position were used for high-performance particle spectroscopy. The constructed level scheme includes more than 160 energy levels and 320 gamma-ray transitions belonging to both normally deformed as well as superdeformed rotational structures. The multipolarities have been determined for the gamma-ray transitions and as a result spin-parity assignments are given for nearly all energy levels. Experimental results in the normally deformed region are compared with predictions from large-scale shell model calculations. The collective structures are compared with results from cranked Nilsson-Strutinsky calculations. The results reveal the need to modify the standard Nilsson parameters in the mass A similar to 60 region.
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| 3. |
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| 4. |
- Bernhardsson, Bo, et al.
(författare)
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Solute transfer in on-line analytical flow-through dialyzers
- 1985
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Ingår i: Analytica Chimica Acta. - 1873-4324. ; 167, s. 111-122
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Tidskriftsartikel (refereegranskat)abstract
- Mass transfer in infinite parallel-plate dialyzers with co-flow between sample and detector streams is discussed for three different theoretical models. Analytical solutions with coupled diffusion and membrane transfer equations were obtained for plug flow in both channels. The finite-difference approximation method was used to obtain numerical solutions for a laminar-flow regime. Results obtained with a mixing-cup model under steady-state conditions were also included. With the dimensions typical for analytical dialyzers, there were only small differences between the laminar-flow and plug-flow models. The mixing-cup model predicted higher fluxes through the membrane than the other two models, particularly when the channel heights were increased. The theoretical results were compared with experimental results for dialysis of zinc(II) ions and the flow dependence agreed reasonably well with theory provided that the hydrostatic pressures were equal on both sides, and that stresses which could result in membrane bulging were kept low.Download full text in PDF
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| 5. |
- Bjarnason, Bjarni, et al.
(författare)
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Enzyme flow immunoassay using a Protein G column for the screening of triazine herbicides in surface and waste water
- 2001
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Ingår i: Analytica Chimica Acta. - 0003-2670. ; 426:2, s. 197-207
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Tidskriftsartikel (refereegranskat)abstract
- A method for screening of triazine herbicides in surface and waste water is presented. The method is based on an enzyme flow immunoassay (EFIA) for the detection of the free fraction of a horse radish peroxidase (HRP)-labelled antigen (tracer). This was accomplished by trapping the bound tracer fraction in a Protein G column, allowing the residual free tracer fraction to pass and be detected spectrophotometrically after incubation with an enzyme substrate. As compared with detecting the bound tracer fraction this reduces the regeneration requirements of the Protein G column used for capturing the bound fraction and, therefore, reduces assay time. A polyclonal antibody directed against simazine showed no reactivity towards tracers that were thiopropionic acid derivatives of atrazine, simazine and terbutylazine. It had good sensitivity towards tracers using derivatives of 2-chloro-4,6-(alkylamino)-s-triazines such as atrazine and simazine. The highest sensitivity was obtained with an Et/Cl/N-C5-HRP tracer because this tracer could be used in combination with the lowest concentration of antibody. The detection limit was 0.1 μgl-1 with a linear range between 0.1 and 10 μgl-1 and an assay throughput of 12 h-1. Natural water samples from various locations in Russia were analysed for triazines and the results were compared with a previously developed fluorescein flow immunoassay for triazines. The results were further verified by supported liquid membrane (SLM) extraction combined with HPLC. The results show that the two immunoassays behave differently and that the sample matrix influences their performance, however, no false negative results were obtained. The possible reasons for the different results between the two immunoassays are discussed. (C) 2001 Elsevier Science B.V.
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| 6. |
- Johansson, Gillis, et al.
(författare)
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Multistage countercurrent distrubution
- 1995
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Ingår i: The Encyclopedia of Analytical Science. - 0122267001
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Bokkapitel (övrigt vetenskapligt/konstnärligt)
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| 7. |
- Khayyami, Masoud, et al.
(författare)
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An Amperometric Lactate Sensor Based on a NAD+-Analog and Lactate Dehydrogenase Coimmobilized on Reticulated Vitreous Carbon
- 1997
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Ingår i: Electroanalysis. - : Wiley. - 1040-0397 .- 1521-4109. ; 9:7, s. 523-526
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Tidskriftsartikel (refereegranskat)abstract
- A NAD+-analog was coimmobilized with lactate dehydrogenase (LDH) on reticulated vitreous carbon (RVC) to give an amperometric lactate biosensor. Both LDH and the NAD+ -analog were bound covalently with carbodiimide to the surface of the porous RVC-material. The electrode was operated in a FIA-arrangement in the presence or absence of a soluble mediator. Meldola Blue. The stability was poor when the electrode was operated at +400 mV (vs. Ag/AgCl) in the absence of mediator but improved most significantly in the presence of 5 μM mediator, so that 65% of the original activity remained after 16 days. The amperometric currents were smaller with regeneration by mediator at −100 mV than with direct electrochemical oxidation at +400 mV, indicating that the additional steps slow down the reaction rate. Linear calibration plots were obtained from the detection limit, 1 μM, to 500 μM lactate with 5 μM mediator, reoxidized at −100 mV. The sample throughput was about 60 h−1.
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| 8. |
- Khayyami, M, et al.
(författare)
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Development of an amperometric biosensor based on acetylcholine esterase covalently bound to a new support material
- 1998
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Ingår i: Talanta. - 1873-3573. ; 45:3, s. 557-563
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Tidskriftsartikel (refereegranskat)abstract
- A new type of amperometric biosensor based on immobilised acetylcholine esterase was designed and constructed. The enzyme was immobilised on a flow-through working electrode, which was prepared from reticulated vitreous carbon (RVC) or from a composite material consisting of RVC and superporous agarose. The sensor was operated in FIA mode using acetylthiocholine as a substrate. The sensor responded to inhibitors such as paraoxon—10−9 mol was detected by the sensor in a non-optimised configuration. The practical lifetime of the sensor was at least 1 month.
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| 9. |
- Khayyami, Masoud, et al.
(författare)
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Flow-injection determination of trace hydrogen peroxide or glucose utilizing an amperometric biosensor based on glucose oxidase bound to a reticulated vitreous carbon electrode
- 1996
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Ingår i: Talanta. - : Elsevier BV. - 0039-9140. ; 43:6, s. 957-962
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Tidskriftsartikel (refereegranskat)abstract
- An electron transfer mediator, 8-dimethylamino-2,3-benzophenoxazine (Meldola Blue), dissolved in the carrier solution in a flow-injection system, was found to reduce the oxidation potential for hydrogen peroxide from 600-1200 mV without mediator to - 100 mV vs. Ag/AgCl with the mediator present. The very low background current of reticulated vitreous carbon (RVC) at this potential makes it possible to detect very low levels of hydrogen peroxide or glucose. Glucose oxidase was covalently coupled with carbodiimide to RVC, and the RVC was formed into a column inserted in a flow-injection system. The calibration curve was linear from 30 nM to 10 μM glucose with 5 μM mediator. At higher mediator concentrations, the linear range was extended to 1000 μM, but with a much higher background current. The sample throughput was about 60 h-1. The current response decreased to 50% of the original response after 20 days. The coulometric yield was high because the sample was pumped through the pores of the RVC. It was 16% and 55% at a flow rate of 1 ml min -1 at mediator concentrations of 5 and 50 μM respectively.
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| 10. |
- Sundström, Gerdt, et al.
(författare)
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Innan döden skiljer oss åt
- 2003
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Ingår i: Aldring og livslöp. - 1503-0849. ; :1, s. 24-29
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Tidskriftsartikel (refereegranskat)
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