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Search: WFRF:(Jongejan Hugo)

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  • Högberg, Hans-Erik, et al. (author)
  • Formation of hemiacetal esters in lipase-catalysed reactions of vinyl esters with secondary alcohols
  • 2000
  • In: Tetrahedron Letters. ; 41, s. 3193-3196
  • Journal article (peer-reviewed)abstract
    • Normally many lipases are efficient catalysts for the acetylation of alcohols with vinyl acetate. Unexpectedly, we found that some sterically hindered secondary alcohols react slowly to yield hemiacetal esters as mixtures of diastereomers. Their formation can be explained by the reaction of the alcohol with acetaldehyde that is produced by the lipase-catalysed splitting of vinyl acetate and subsequent acetylation of the resulting hemiacetal by the lipase.
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  • Result 1-1 of 1
Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Högberg, Hans-Erik (1)
Sjödin, Kristina (1)
Isaksson, Dan (1)
Lindmark, Marica (1)
Franssen, Maurice (1)
Jongejan, Hugo (1)
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Wijnberg, Joannes (1)
de Groot, Aeede (1)
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University
Royal Institute of Technology (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
Year
2000 (1)

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