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  • Cousins, David L., et al. (author)
  • Pyrimidin-6-yl Trifluoroborate Salts as Versatile Templates for Heterocycle Synthesis
  • 2021
  • In: Angewandte Chemie International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 133:17, s. 9498-9501
  • Journal article (peer-reviewed)abstract
    • We report a novel and general method to access a highly under‐studied privileged scaffold – pyrimidines bearing a trifluoroborate at C4, and highlight the broad utility of these intermediates in a rich array of downstream functionalization reactions. This chemistry is underpinned by the unique features of the trifluoroborate group; its robustness provides an opportunity to carry out chemoselective reactions at other positions on the pyrimidine while providing a pathway for elaboration at the C‐B bond when suitably activated.
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