1. |
- Aagaard Kristensen, Jeppe, et al.
(author)
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Development of a harmonised soil profile analytical database for Europe : A resource for supporting regional soil management
- 2019
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In: Soil. - : Copernicus GmbH. - 2199-3971 .- 2199-398X. ; 5:2, s. 289-301
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Journal article (peer-reviewed)abstract
- Soil mapping is an essential method for obtaining a spatial overview of soil resources that are increasingly threatened by environmental change and population pressure. Despite recent advances in digital soil-mapping techniques based on inference, such methods are still immature for large-scale soil mapping. During the 1970s, 1980s and 1990s, soil scientists constructed a harmonised soil map of Europe (1:1 000 000) based on national soil maps. Despite this extraordinary regional overview of the spatial distribution of European soil types, crude assumptions about soil properties were necessary for translating the maps into thematic information relevant to management. To support modellers with analytical data connected to the soil map, the European Soil Bureau Network (ESBW) commissioned the development of the soil profile analytical database for Europe (SPADE) in the late 1980s. This database contains soil analytical data based on a standardised set of soil analytical methods across the European countries. Here, we review the principles adopted for developing the SPADE database during the past five decades, the work towards fulfilling the milestones of full geographic coverage for dominant soils in all the European countries (SPADE level 1) and the addition of secondary soil types (SPADE level 2). We illustrate the application of the database by showing the distribution of the root zone capacity and by estimating the soil organic carbon (SOC) stocks at a depth of 1 m for Europe to be 60×1015 g. The increased accuracy, potentially obtained by including secondary soil types (level 2), is shown in a case study to estimate SOC stocks in Denmark. Until data from systematic cross-European soil-sampling programmes have sufficient spatial coverage for reliable data interpolation, integrating national soil maps and locally assessed analytical data into a harmonised database remains a powerful resource to support soil resources management at regional and continental scales by providing a platform to guide sustainable soil management and food production.
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2. |
- Aidas, Kestutis, et al.
(author)
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The Dalton quantum chemistry program system
- 2014
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In: WIREs Computational Molecular Science. - : Wiley. - 1759-0876 .- 1759-0884. ; 4:3, s. 269-284
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Journal article (peer-reviewed)abstract
- Dalton is a powerful general-purpose program system for the study of molecular electronic structure at the Hartree-Fock, Kohn-Sham, multiconfigurational self-consistent-field, MOller-Plesset, configuration-interaction, and coupled-cluster levels of theory. Apart from the total energy, a wide variety of molecular properties may be calculated using these electronic-structure models. Molecular gradients and Hessians are available for geometry optimizations, molecular dynamics, and vibrational studies, whereas magnetic resonance and optical activity can be studied in a gauge-origin-invariant manner. Frequency-dependent molecular properties can be calculated using linear, quadratic, and cubic response theory. A large number of singlet and triplet perturbation operators are available for the study of one-, two-, and three-photon processes. Environmental effects may be included using various dielectric-medium and quantum-mechanics/molecular-mechanics models. Large molecules may be studied using linear-scaling and massively parallel algorithms. Dalton is distributed at no cost from for a number of UNIX platforms.
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3. |
- Barbero-Palacios, Laura, et al.
(author)
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Herbivore diversity effects on Arctic tundra ecosystems : a systematic review
- 2024
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In: Environmental Evidence. - : BioMed Central (BMC). - 2047-2382. ; 13:1
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Research review (peer-reviewed)abstract
- Background: Northern ecosystems are strongly influenced by herbivores that differ in their impacts on the ecosystem. Yet the role of herbivore diversity in shaping the structure and functioning of tundra ecosystems has been overlooked. With climate and land-use changes causing rapid shifts in Arctic species assemblages, a better understanding of the consequences of herbivore diversity changes for tundra ecosystem functioning is urgently needed. This systematic review synthesizes available evidence on the effects of herbivore diversity on different processes, functions, and properties of tundra ecosystems.Methods: Following a published protocol, our systematic review combined primary field studies retrieved from bibliographic databases, search engines and specialist websites that compared tundra ecosystem responses to different levels of vertebrate and invertebrate herbivore diversity. We used the number of functional groups of herbivores (i.e., functional group richness) as a measure of the diversity of the herbivore assemblage. We screened titles, abstracts, and full texts of studies using pre-defined eligibility criteria. We critically appraised the validity of the studies, tested the influence of different moderators, and conducted sensitivity analyses. Quantitative synthesis (i.e., calculation of effect sizes) was performed for ecosystem responses reported by at least five articles and meta-regressions including the effects of potential modifiers for those reported by at least 10 articles.Review findings: The literature searches retrieved 5944 articles. After screening titles, abstracts, and full texts, 201 articles including 3713 studies (i.e., individual comparisons) were deemed relevant for the systematic review, with 2844 of these studies included in quantitative syntheses. The available evidence base on the effects of herbivore diversity on tundra ecosystems is concentrated around well-established research locations and focuses mainly on the impacts of vertebrate herbivores on vegetation. Overall, greater herbivore diversity led to increased abundance of feeding marks by herbivores and soil temperature, and to reduced total abundance of plants, graminoids, forbs, and litter, plant leaf size, plant height, and moss depth, but the effects of herbivore diversity were difficult to tease apart from those of excluding vertebrate herbivores. The effects of different functional groups of herbivores on graminoid and lichen abundance compensated each other, leading to no net effects when herbivore effects were combined. In turn, smaller herbivores and large-bodied herbivores only reduced plant height when occurring together but not when occurring separately. Greater herbivore diversity increased plant diversity in graminoid tundra but not in other habitat types.Conclusions: This systematic review underscores the importance of herbivore diversity in shaping the structure and function of Arctic ecosystems, with different functional groups of herbivores exerting additive or compensatory effects that can be modulated by environmental conditions. Still, many challenges remain to fully understand the complex impacts of herbivore diversity on tundra ecosystems. Future studies should explicitly address the role of herbivore diversity beyond presence-absence, targeting a broader range of ecosystem responses and explicitly including invertebrate herbivores. A better understanding of the role of herbivore diversity will enhance our ability to predict whether and where shifts in herbivore assemblages might mitigate or further amplify the impacts of environmental change on Arctic ecosystems.
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4. |
- Eckdahl, Johan A., et al.
(author)
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Climate and forest properties explain wildfire impact on microbial community and nutrient mobilization in boreal soil
- 2023
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In: Frontiers in Forests and Global Change. - : Frontiers Media S.A.. - 2624-893X. ; 6
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Journal article (peer-reviewed)abstract
- The boreal landscape stores an estimated 40% of the earth's carbon (C) found in terrestrial vegetation and soils, with a large portion collected in thick organic soil layers. These ground stores are subject to substantial removals due to the centurial return of wildfire, which has strong impacts on the soil microbial community and nutrient cycling, which in turn can control ecosystem recovery patterns and process rates, such as C turnover. Currently, predictive knowledge used in assessing fire impacts is largely focused on ecosystems that experience only superficial burning and few robust observations exist regarding the effect that smoldering combustion in deeper active soil layers has on post-fire soil activity. This study provided a highly replicated and regionally extensive survey of wildfire impact on microbial community structure (using fatty acid biomarkers) and nutrient cycling (using in situ ionic resin capsules) across broad gradients of climate, forest properties and fire conditions within 50 separate burn scars and 50 additional matched unburnt boreal forest soils. The results suggest a strong metabolic shift in burnt soils due to heat impact on their structure and a decoupling from aboveground processes, releasing ecosystem N limitation and increasing mobilization of N, P, K, and S as excess in conjunction with an altered, C-starved microbial community structure and reduced root uptake due to vegetation mortality. An additional observed climatic control over burnt soil properties has implications for altered boreal forest function in future climate and fire regimes deserving of further attention.
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5. |
- Eckdahl, Johan A., et al.
(author)
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Climatic variation drives loss and restructuring of carbon and nitrogen in boreal forest wildfire
- 2022
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In: Biogeosciences. - : Copernicus GmbH. - 1726-4170 .- 1726-4189. ; 19:9, s. 2487-2506
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Journal article (peer-reviewed)abstract
- The boreal forest landscape covers approximately 10% of the earth's land area and accounts for almost 30 % of the global annual terrestrial sink of carbon (C). Increased emissions due to climate-change-amplified fire frequency, size, and intensity threaten to remove elements such as C and nitrogen (N) from forest soil and vegetation at rates faster than they accumulate. This may result in large areas within the region becoming a net source of greenhouse gases, creating a positive feedback loop with a changing climate. Meter-scale estimates of area-normalized fire emissions are limited in Eurasian boreal forests, and knowledge of their relation to climate and ecosystem properties is sparse. This study sampled 50 separate Swedish wildfires, which occurred during an extreme fire season in 2018, providing quantitative estimates of C and N loss due to fire along a climate gradient. Mean annual precipitation had strong positive effects on total fuel, which was the strongest driver for increasing C and N losses. Mean annual temperature (MAT) influenced both pre-and postfire organic layer soil bulk density and C: N ratio, which had mixed effects on C and N losses. Significant fire-induced loss of C estimated in the 50 plots was comparable to estimates in similar Eurasian forests but approximately a quarter of those found in typically more intense North American boreal wildfires. N loss was insignificant, though a large amount of fire-affected fuel was converted to a low C: N surface layer of char in proportion to increased MAT. These results reveal large quantitative differences in C and N losses between global regions and their linkage to the broad range of climate conditions within Fennoscandia. A need exists to better incorporate these factors into models to improve estimates of global emissions of C and N due to fire in future climate scenarios. Additionally, this study demonstrated a linkage between climate and the extent of charring of soil fuel and discusses its potential for altering C and N dynamics in postfire recovery.
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6. |
- Eckdahl, Johan A., et al.
(author)
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Mineral soils are an important intermediate storage pool of black carbon in fennoscandian boreal forests
- 2022
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In: Global Biogeochemical Cycles. - : John Wiley & Sons. - 0886-6236 .- 1944-9224. ; 36:11
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Journal article (peer-reviewed)abstract
- Approximately 40% of earth's carbon (C) stored in land vegetation and soil is within the boreal region. This large C pool is subjected to substantial removals and transformations during periodic wildfire. Fire-altered C, commonly known as pyrogenic carbon (PyC), plays a significant role in forest ecosystem functioning and composes a considerable fraction of C transport to limnic and oceanic sediments. While PyC stores are beginning to be quantified globally, knowledge is lacking regarding the drivers of their production and transport across ecosystems. This study used the chemo-thermal oxidation at 375°C (CTO-375) method to isolate a particularly refractory subset of PyC compounds, here called black carbon (BC), finding an average increase of 11.6 g BC m−2 at 1 year postfire in 50 separate wildfires occurring in Sweden during 2018. These increases could not be linked to proposed drivers, however BC storage in 50 additional nearby unburnt soils related strongly to soil mass while its proportion of the larger C pool related negatively to soil C:N. Fire approximately doubled BC stocks in the mineral layer but had no significant effect on BC in the organic layer where it was likely produced. Suppressed decomposition rates and low heating during fire in mineral subsoil relative to upper layers suggests potential removals of the doubled mineral layer BC are more likely transported out of the soil system than degraded in situ. Therefore, mineral soils are suggested to be an important storage pool for BC that can buffer short-term (production in fire) and long-term (cross-ecosystem transport) BC cycling.
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7. |
- Eckdahl, Johan A., et al.
(author)
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Restricted plant diversity limits carbon recapture after wildfire in warming boreal forests
- 2024
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In: Communications Earth & Environment. - : Nature Publishing Group. - 2662-4435. ; 5:1
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Journal article (peer-reviewed)abstract
- Incomplete wildfire combustion in boreal forests leaves behind legacy plant-soil feedbacks known to restrict plant biodiversity. These restrictions can inhibit carbon recapture after fire by limiting ecosystem transition to vegetation growth patterns that are capable of offsetting warmth-enhanced soil decomposition under climate change. Here, we field-surveyed plant regrowth conditions 2 years after 49 separate, naturally-occurring wildfires spanning the near-entire climatic range of boreal Fennoscandia in order to determine the local to regional scale drivers of early vegetation recovery. Minimal conifer reestablishment was found across a broad range of fire severities, though residual organic soil and plant structure was associated with restricted growth of a variety of more warmth-adapted vegetation, such as broadleaf trees. This dual regeneration limitation coincided with greater concentrations of bacterial decomposers in the soil under increased mean annual temperature, potentially enhancing soil carbon release. These results suggest that large portions of the boreal region are currently at risk of extending postfire periods of net emissions of carbon to the atmosphere under limitations in plant biodiversity generated by wildfire and a changing climate.
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8. |
- Hoppe, Camilla, et al.
(author)
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Intake and sources of gluten in 20- to 75-year-old Danish adults: a national dietary survey
- 2017
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In: European Journal of Nutrition. - : Springer Science and Business Media LLC. - 1436-6207 .- 1436-6215 .- 1435-1293. ; 56:1, s. 107-117
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Journal article (peer-reviewed)abstract
- Purpose: Celiac disease, an immunological response triggered by gluten, affects ~1 % of the Western population. Information concerning gluten intake in the general population is scarce. We determined intake of gluten from wheat, barley, rye and oat in the Danish National Survey of Diet and Physical Activity 2005–2008. The study population comprised a random cross-sectional sample of 1494 adults 20–75 years, selected from the Danish Civil Registration System. Methods: Protein content in wheat, rye, barley and oat was determined from the National Danish Food Composition Table and multiplied with the amount of cereal used in recipes. Amount of gluten was calculated as amount of cereal protein ×0.80 for wheat and oat, ×0.65 for rye and ×0.50 for barley. Dietary intake was recorded daily during seven consecutive days in pre-coded food diaries with open-answer possibilities. Results: Mean total gluten intake was 10.4 ± 4.4 g/day (10th–90th percentiles; 5.4–16.2 g/day), in men 12.0 ± 4.6 g/day and 9.0 ± 3.4 g/day in women. It was higher among men than among women in all age groups (20–75 years; P
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9. |
- Kjær, Kurt H., et al.
(author)
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A 2-million-year-old ecosystem in Greenland uncovered by environmental DNA
- 2022
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In: Nature. - : Springer Nature. - 0028-0836 .- 1476-4687. ; 612:7939, s. 283-291
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Journal article (peer-reviewed)abstract
- Late Pliocene and Early Pleistocene epochs 3.6 to 0.8 million years ago1 had climates resembling those forecasted under future warming2. Palaeoclimatic records show strong polar amplification with mean annual temperatures of 11–19 °C above contemporary values3,4. The biological communities inhabiting the Arctic during this time remain poorly known because fossils are rare5. Here we report an ancient environmental DNA6 (eDNA) record describing the rich plant and animal assemblages of the Kap København Formation in North Greenland, dated to around two million years ago. The record shows an open boreal forest ecosystem with mixed vegetation of poplar, birch and thuja trees, as well as a variety of Arctic and boreal shrubs and herbs, many of which had not previously been detected at the site from macrofossil and pollen records. The DNA record confirms the presence of hare and mitochondrial DNA from animals including mastodons, reindeer, rodents and geese, all ancestral to their present-day and late Pleistocene relatives. The presence of marine species including horseshoe crab and green algae support a warmer climate than today. The reconstructed ecosystem has no modern analogue. The survival of such ancient eDNA probably relates to its binding to mineral surfaces. Our findings open new areas of genetic research, demonstrating that it is possible to track the ecology and evolution of biological communities from two million years ago using ancient eDNA.
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