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1.	Jäger, Michael, et al. (author) Cyclometalated Ru-II Complexes with Improved Octahedral Geometry : Synthesis and Photophysical Properties 2010 In: Inorganic Chemistry. - : American Chemical Society (ACS). - 0020-1669 .- 1520-510X. ; 49:2, s. 374-376 Journal article (peer-reviewed)abstract Cyclometalated bis-tridentate ruthenium(II) complexes incorporating 2,6-diquinolin-8-ylpyridine ligands and exhibiting broad visible absorptions are described. A [Ru(N boolean AND N boolean AND N)(N boolean AND C boolean AND N)](+) complex based only on ligands with expanded bite angles has a metal-to-ligand charge-transfer excited-state lifetime of 16 ns, which is attributed to a strong ligand field and therefore reduced deactivation via metal-centered states.
2.	Sharma, Sanjeev, et al. (author) Resolution of Conformationally Chiral mer-[Ru(dqp)2]2+ and Crystallographic Analysis of [δ,δ-Ru(dqp)2][Δ-TRISPHAT]2 (dqp=2,6-Di(quinolin-8-yl)pyridine; TRISPHAT=Tris(tetrachlorocatecholate)phosphate) 2010 In: Chemistry - A European Journal. - : Wiley. - 0947-6539 .- 1521-3765. ; 16:24, s. 7078-7081 Journal article (peer-reviewed)abstract Resolving the problem! The conformationally chiral bistridentate [Ru(dqp)2]2+ complex (dqp=2,6-di(quinolin-8-yl)pyridine) was resolved by selective precipitation using [Δ-TRISPHAT]− (tris(tetrachlorocatecholate)phosphate) as the chiral auxiliary. The X-ray crystal structure of one diastereomer has been solved (see picture). No evidence for racemization was observed either at elevated temperature or with visible light.

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Type of publication: journal article (2)

Type of content: peer-reviewed (2)

Author/Editor: Johansson, Olof (2); Lombeck, Florian (2); Eriksson, Lars (1); Hammarström, Leif (1); Jäger, Michael (1); Sauvage, Jean-Pierre (1); show more...; Smeigh, Amanda (1); Gorls, Helmar (1); Collin, Jean-Paul (1); Sharma, Sanjeev (1); show less...

University: Uppsala University (2); Stockholm University (1)

Language: English (2)

Research subject (UKÄ/SCB): Natural sciences (2)

Year: 2010 (2)

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