| 1. |
- Lewerentz, Alexander, 1987-
(author)
-
Fluid-induced alteration of metasedimentary rocks in the Scottish Highlands
- 2017
-
Doctoral thesis (other academic/artistic)abstract
- Fluids, mainly H2O and CO2, are released from H- and C-bearing phases during prograde metamorphism. Because of the buoyancy of these fluids, they rise within the crust towards the surface of the Earth. Metamorphic fluids take advantage of permeable horizons, shear zones, fold hinges, fractures, and are channelled into high-flux zones. Fluid fluxes for channelized fluid flow may exceed background pervasive fluxes by several orders of magnitude. Metamorphic fluids react with the surrounding rock during fluid flow, and altered zones are commonly observed adjacent to high-flux conduits. Fluid-altered rock is texturally, mineralogically, chemically, and isotopically different from rock unaffected by fluid flow. In this thesis, fluid-rock interaction is studied at two localities in the Scottish Highlands: Glen Esk and the Isle of Islay.Glen Esk is one of the type localities used by George Barrow (1853-1932) to propose the concept of metamorphic zones and metamorphic index minerals as an approximate determination of metamorphic grade. In several of the metamorphic zones in Glen Esk, index mineral distribution is highly dependent on proximity to veins. The occurrence of index minerals is therefore not only controlled by pressure and temperature, but also by the availability of metamorphic fluids. Evidence of a retrograde fluid flow event from the North Esk Fault is observed in Glen Esk, for which a time-averaged fluid flux of 0.0003 – 0.0126 m3∙m-2∙yr-1 is calculated. The duration of the fluid event is estimated to between 16 and 334 kyr.On the Isle of Islay, kyanite is observed in rocks of chlorite or lower-biotite metamorphic grade, i.e. much lower temperatures than usually associated with kyanite formation. The favoured explanation for this is retrograde infiltration of extremely high-CO2 fluids, at least locally XCO2 > 0.7, at ~340°C, which altered these rocks and stabilised kyanite in a carbonate-bearing assemblage. Oxygen and carbon stable isotope profiles across the Islay Anticline reveals highly channelized fluid flow along the axial region of this fold, with fluid:rock ratios at least four times higher than in rock farther away from the fold. Although carbon and oxygen isotope ratios of metacarbonate rocks were altered along the Islay Anticline, negative anomalies observed below and above the Port Askaig Tillite Formation cannot solely be attributed to metamorphic fluid flow, which implies that these rocks to varying degree retain their primary paleoclimatological isotopic signatures.
|
|
| 2. |
- Nosenzo, Francesco, 1993-
(author)
-
Chemical and isotopic records of polycyclic histories in a subducted continental crust (Dora-Maira Massif, Western Alps)
- 2023
-
Doctoral thesis (other academic/artistic)abstract
- At convergent plate margin, part of the continental crust can be subducted and exhumed. During continental subduction a pre-existing crust is reworked. Remnants of an older orogen are recycled and subjected to (ultra)-high-pressure metamorphism. During subduction, polycyclic rocks undertake a second metamorphic cycle, whereas monocyclic rocks are metamorphosed for the first time. In reworked rocks the pre-subduction record is overprinted and partially or completely lost. Despite this difficulty, reconstructing the pre-subduction history of the recycled crust is crucial, because pre-subduction characters (such as H2O content) can strongly influence how rocks respond to reworking during subduction.The Dora-Maira Massif is worldwide renowned as a (ultra)-high-pressure continental terrane. However, its northern part remained essentially unexplored in recent times. In this thesis work the northern Dora-Maira Massif is used as a case study to investigate recycling of continental crust. The aim is to constrain what type of crust is subducted and exhumed and to unravel the role of fluids during subduction of polycyclic material. Field work, petrology, thermodynamic modelling and geochronology are integrated.New field and geochronological evidence indicate that the northern Dora-Maira Massif displays an internal architecture more complex than what previously thought. It is subdivided in several tectonic units likewise the southern Dora-Maira Massif. Chemical and isotopic records of the reworked rocks reveal a pre-Alpine history spanning from the Lower Palaeozoic to the Mesozoic. A polycyclic basement preserves relicts of a pre-Alpine Barrovian metamorphism connected with the Variscan orogenesis. The absence of granulite-facies partially molten pre-Alpine rocks indicates that only the upper crust was reworked in the Dora-Maira Massif.Thermodynamic modelling indicates that polycyclic micaschists were rehydrated between the Variscan and the Alpine peak metamorphism. Polycyclic garnet texture and chemistry and metamorphic zircon record a main episode of fluid infiltration at the end of the Variscan cycle and not during the Alpine cycle. Pre-Alpine re-hydration of the upper crust allowed high-pressure re-equilibration during subduction.
|
|
