| 1. |
- Duan, Hongyu, et al.
(author)
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Co-exploitation of coal and geothermal energy through water-conducting structures : Improving extraction efficiency of geothermal well
- 2024
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In: Renewable energy. - : Elsevier BV. - 0960-1481 .- 1879-0682. ; 228
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Journal article (peer-reviewed)abstract
- Co-exploitation of coal and geothermal energy through water-conducting structures is one of the most promising methods for harnessing renewable energy in some coal mines. A rock compression-erosion coupling test system is built to investigate the extraction efficiency of geothermal wells in the co-exploitation scheme. Compression-erosion tests are carried out to analyze the evolution of mechanics and hydraulic characteristics of broken rocks. The testing results show that the hydrothermal flow erodes the fine rock particles, and compressive deformation can be observed during the erosion process. The erosion effect in broken rocks intensifies with the decrease of axial stress and the increase of fractal dimension, water pressure, and inner radius. Meanwhile, the rock sample shows more significant deformation. Two permeability forecasting models are adopted to forecast permeability evolution during geothermal extraction. The forecasting results indicate that the Brinkman model is better than the Hazen model, and the accuracy of the Brinkman model is lower for the samples with stronger compression-erosion effects. In addition, strategies to improve the extraction efficiency are proposed, i.e., reinforcing the broken rocks above the geothermal well, locating geothermal wells in rocks with higher fragmentation, increasing pumping pressure, and expanding the geothermal well size.
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| 2. |
- Hou, Qiong, et al.
(author)
-
A triphenylamine-based four-armed molecule for solution-processed organic solar cells with high photo-voltage
- 2013
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In: JOURNAL OF MATERIALS CHEMISTRY A. - : Royal Society of Chemistry. - 2050-7488 .- 2050-7496. ; 1:16, s. 4937-4940
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Journal article (peer-reviewed)abstract
- A new four-armed molecule Th-4(DTPAB) with a triphenylamine-benzothiadiazole-triphenylamine unit as the core and 4-hexylthiophene as arms was synthesized. Solution-processed organic solar cells based on blends of Th-4(DTPAB) and PC71BM demonstrate a power conversion efficiency of 3.18% with a high open circuit voltage of 0.96 V.
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| 3. |
- Ma, Dan, et al.
(author)
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A global optimization-based method for the prediction of water inrush hazard from mining floor
- 2018
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In: Water. - : MDPI AG. - 2073-4441. ; 10:11
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Journal article (peer-reviewed)abstract
- Water inrush hazards can be effectively reduced by a reasonable and accurate soft-measuring method on the water inrush quantity from the mine floor. This is quite important for safe mining. However, there is a highly nonlinear relationship between the water outburst from coal seam floors and geological structure, hydrogeology, aquifer, water pressure, water-resisting strata, mining damage, fault and other factors. Therefore, it is difficult to establish a suitable model by traditional methods to forecast the water inrush quantity from the mine floor. Modeling methods developed in other fields can provide adequate models for rock behavior on water inrush. In this study, a new forecast system, which is based on a hybrid genetic algorithm (GA) with the support vector machine (SVM) algorithm, a model structure and the related parameters are proposed simultaneously on water inrush prediction. With the advantages of powerful global optimization functions, implicit parallelism and high stability of the GA, the penalty coefficient, insensitivity coefficient and kernel function parameter of the SVM model are determined as approximately optimal automatically in the spatial dimension. All of these characteristics greatly improve the accuracy and usable range of the SVM model. Testing results show that GA has a useful ability in finding optimal parameters of a SVM model. The performance of the GA optimized SVM (GA-SVM) is superior to the SVM model. The GA-SVM enables the prediction of water inrush and provides a promising solution to the predictive problem for relevant industries.
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| 4. |
- Ma, Dan, et al.
(author)
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A state-of-the-art review on rock seepage mechanism of water inrush disaster in coal mines
- 2022
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In: International Journal of Coal Science & Technology. - : Springer Nature. - 2095-8293 .- 2198-7823. ; 9:1
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Research review (peer-reviewed)abstract
- Water inrush is one of the most dangerous disasters in coal mining. Due to the large-scale mining and complicated hydrogeological conditions, thousands of deaths and huge economic losses have been caused by water inrush disasters in China. There are two main factors determining the occurrence of water inrush: water source and water-conducting pathway. Research on the formation mechanism of the water-conducting pathway is the main direction to prevent and control the water inrush, and the seepage mechanism of rock mass during the formation of the water-conducting pathway is the key for the research on the water inrush mechanism. This paper provides a state-of-the-art review of seepage mechanisms during water inrush from three aspects, i.e., mechanisms of stress-seepage coupling, flow regime transformation and rock erosion. Through numerical methods and experimental analysis, the evolution law of stress and seepage fields in the process of water inrush is fully studied; the fluid movement characteristics under different flow regimes are clearly summarized; the law of particle initiation and migration in the process of water inrush is explored, and the effect of rock erosion on hydraulic and mechanical properties of the rock media is also studied. Finally, some limitations of current research are analyzed, and the suggestions for future research on water inrush are proposed in this review.
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| 5. |
- Ma, Dan, et al.
(author)
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Creep-erosion coupling water inrush model of weakly cemented fault rock mass
- 2023
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In: Meitan Xuebao/Journal of the China Coal Society. - : China Coal Society. - 0253-9993. ; 48:6, s. 2453-2464
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Journal article (peer-reviewed)abstract
- In order to investigate the temporal-spatial evolution properties of the water inrush disaster process of weakly cemented fault rock mass, a creep-erosion coupling water inrush model of weakly cemented fault rock mass is established. This model expands the equivalent continuum seepage theory, and a creep submodel and an erosion submodel are established respectively. The proposed creep submodel fully considers the mass conversion among materials, stress-strain and strain-porosity relationships. The proposed erosion submodel fully considers the mass conservation, particle migration and non-Darcy flow laws. According to the superposition principle of the mass conservation equations and three influence relationships (i.e., porosity-effective stress, porosity-creep material coefficient and creep strain-porosity-permeability relationships), the coupling between the submodels is realized, and the governing equations of the one-dimensional radial seepage direction coupling model are given. The solution conditions of the water inrush model are set, and the numerical computation method of the model in the temporal-spatial domain is established based on the COMSOL Multiphysics. By comparing the laboratory experimental results and the model calculation results of porosity evolution, the validity of the creep-erosion coupling model of weakly cemented surrounding rock is verified. On this basis, the temporal-spatial evolution law of the creep-erosion characteristics of weakly cemented surrounding rocks of the roadway is solved and analyzed. The calculated results show that in terms of the creep characteristics evolution, the effective stress decreases and the creep strain increases with time, and the samples exhibit the accelerated creep characteristics. The inhomogeneity of the spatial distribution of effective stress and creep strain increases with the creep-erosion coupling process. As for the evolution of the erosion characteristics, in the initial stage of the creep-erosion coupling process, the fine rock particles migrate out continuously under the effect of water flow, the volume fraction of fluidized particles, the permeability and flow velocity continuously increase, and new water-conducting channels are constantly formed in the weakly cemented rock mass. Subsequently, the erosion effect is weakened and finally stagnates due to the increasing creep effect. The closer to the inner wall of the roadway, the stronger the erosion effect. The spatial distribution of porosity and permeability after the stagnation of erosion shows obvious inhomogeneous characteristics, and the spatial distribution of water pressure presents a nonlinear-linear-nonlinear trend in the creep-erosion coupling process.
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| 6. |
- Ma, D., et al.
(author)
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Numerical Simulation of Water–Silt Inrush Hazard of Fault Rock : A Three-Phase Flow Model
- 2022
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In: Rock Mechanics and Rock Engineering. - : Springer Nature. - 0723-2632 .- 1434-453X. ; 55:8, s. 5163-5182
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Journal article (peer-reviewed)abstract
- Fault rock is a typical hazardous material of water–silt inrush during the excavation in underground mines. To investigate hydraulic characteristics of fault rock during the water–silt inrush, a one-dimensional radial three-phase flow model of water–rock–silt was established in this study. In the proposed model, the mass conservation and continuity equations of the three-phase flow were obtained; the rock particle migration and the momentum conservation of the three-phase fluid migration were described by erosion constitutive equations and non-Darcy flow equations, respectively. The laboratory tests of porosity and the evolution of volume discharge rate were compared, and the accuracy of the proposed three-phase model was verified by the comparison results. From the test and numerical results, a high standard deviation of repeated results is observed in the case with high silt concentrations, and the erosion effect is inhibited by the silt flow. Last but not least, the temporal–spatial distribution of hydraulic properties is obtained by the numerical simulation: With the progress of the three-phase flow, rock particles near the fluid outlet are first fluidized and constantly migrate outward, resulting in an increase of the porosity and permeability in fault rock. Subsequently, water-conducting pathways are gradually formed inside the fault rock, and then more fluidized rock particles flow out. Finally, the fluidized rock particles have completely migrated, and the porosity and permeability tend to be stable with the more significant non-uniform spatial distribution.
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| 7. |
- Ma, Dan, et al.
(author)
-
Water–rock two-phase flow model for water inrush and instability of fault rocks during mine tunnelling
- 2023
-
In: International Journal of Coal Science and Technology. - : Springer Nature. - 2095-8293 .- 2198-7823. ; 10:1
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Journal article (peer-reviewed)abstract
- Water inrush hazard is one of the major threats in mining tunnel construction. Rock particle migration in the seepage process is the main cause of water inrush pathway and rock instability. In this paper, a radial water–rock mixture flow model is established to study the evolution laws of water inrush and rock instability. The reliability of the proposed model is verified by the experimental data from a previous study. Through the mixture flow model, temporal-spatial evolution laws of different hydraulic and mechanical properties are analysed. And the proposed model’s applicability and limitations are discussed by comparing it with the existing water inrush model. The result shows that this model has high accuracy both in temporal evolution and spatial distribution. The accuracy of the model is related to the fluctuation caused by particle migration and the deviation of the set value. During the seepage, the porosity, permeability, volume discharge rate and volume concentration of the fluidized particle increase rapidly due to the particle migration, and this phenomenon is significant near the fluid outlet. As the seepage progresses, the volume concentration at the outlet decreases rapidly after reaching the peak, which leads to a decrease in the growth rate of permeability and porosity, and finally a stable seepage state can be maintained. In addition, the pore pressure is not fixed during radial particle migration and decreases with particle migration. Under the effect of particle migration, the downward radial displacement and decrease in effective radial stress are observed. In addition, both cohesion and shear stress of the rock material decreased, and the rock instability eventually occurred at the outlet.
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| 8. |
- Wang, Gang, et al.
(author)
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Estimating sea spray volume flux with a laser gauge in a self-consistent system
- 2023
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In: Frontiers in Marine Science. - : Frontiers Media SA. - 2296-7745. ; 9
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Journal article (peer-reviewed)abstract
- Sea spray is one of the drivers of heat, mass, and gas exchange between the ocean and the atmosphere, and its volume flux could be estimated by the record of the laser intensity. In the laboratory experiments, the relationship between sea spray and laser intensity could be established since the returned laser intensity of the observing gauge and spray concentration can be observed instantaneously. However, the difficulty to generalize the laboratory result to field observations is that the measurement of sea spray is usually unavailable on the open seas. Recent studies introduced an environment variable (atmospheric extinction coefficient for instance) to relate the laser intensity to spray volume flux for both laboratory and field observations so that the relationship established in the laboratory experiments could be extended to open seas. These studies however gave estimations of great difference since the relationships between each pair of the variables (spray volume flux, laser intensity, and the atmospheric extinction coefficient) are considered separately. This work established a self-consistent system composed of the three variables, in which the relationship between each pair of the variables in the system is consistent with that deduced from their respective relationships with the third variable. Consistency here we means that if Y=f(X), Y=g(Z) and Z=h(X), then Y=g(h(X))=f(X) is expected. The consistency of the relationships ensures that the estimation of the sea spray volume flux from laser intensity is robust. We established self-consistent relationships for the variables in the system composed of laser intensity, environment variable, and sea spray volume flux, for both laboratory and field experiments. Among them, the relationship between wind speed and spray volume flux is a reasonable reflection of the physical properties in two ways: a threshold value of spray volume flux at low wind speeds and the saturation at strong wind speeds. For a uniform regression of wind speed onto spray volume, a dimensionless parameter concerning wind speed is needed.
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| 9. |
- Wang, Hongyu, et al.
(author)
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Co/Fe co-doped ZIF-8 derived hierarchically porous composites as high-performance electrode materials for Cu2+ions capacitive deionization
- 2023
-
In: Chemical Engineering Journal. - : ELSEVIER SCIENCE SA. - 1385-8947 .- 1873-3212. ; 460
-
Journal article (peer-reviewed)abstract
- Due to a threat to human life from heavy metal ions pollution, unprecedented interest has been gained in the development of water purification technologies. Here, we explore another new approach to exploit a prospective carbon material for removing copper ions from aqueous solution based on rapid and easy capacitive deionization (CDI). Reasonable carbon materials modification with ideal composition and improved morphological structure is essential to additionally optimize the capabilities of CDI. We prepared a nitrogen-rich hierarchically porous carbon composites (CoFe-NC) with uniform cobalt (Co) and iron (Fe) doped metal in carbon skeleton by a simple impregnation and pyrolysis method, derived from zeolitic imidazolate framework-8, to use as highly effective CDI electrode for copper ions removal. The addition of Fe can facilitate the uniform dispersion of metals, and enable the formation of a stable carbon cage after pyrolysis. It can sufficiently expose active sites of the electrode materials and promote interfacial charge transfer, thus improving CDI electrosorption efficiency. CoFe-NC composites electrode can achieve outstanding deionization capacity (91.31 mg g-1) in 25 mg L-1 CuSO4 solu-tion. The carbon cage structure of CoFe-NC not only prevents aggregation of metals and avoids destruction of rich multistage pore system by pyrolysis, but also induces a faster ions transport rate. In addition, density functional theory calculations demonstrated that the co-doping of Co and Fe can remarkably increase the adsorption en-ergies of Cu2+ ions, leading to excellent selectivity, which indicates that CoFe-NC composites can be a desired CDI electrode material.
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| 10. |
- Zhen, Hongyu, et al.
(author)
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Solution-processed bulk-heterojunction organic solar cells employing Ir complexes as electron donors
- 2014
-
In: Journal of Materials Chemistry A. - : Royal Society of Chemistry. - 2050-7488 .- 2050-7496. ; 2:31, s. 12390-12396
-
Journal article (peer-reviewed)abstract
- To explore enhancing photocurrent in organic solar cells (OSCs) via harvesting triplet excitons, two novel bicycloiridium complexes (R-1 and R-2) are designed and synthesized. Conventional bulk-heterojunction triplet OSCs are solution processed using R-1 or R-2 as sole electron donors and phenyl-C-71-butyric acid methyl ester (PC71BM) as the electron acceptor. A decent short circuit current (J(sc)) of 6.5 mA cm(-2) is achieved though the overlap between the absorption spectrum (with similar to 550 nm absorption onset) of R-2 and the solar flux is relatively small. With an open circuit voltage of 0.74 V and a fill factor of 0.42, an encouraging power conversion efficiency of 2.0% is achieved in the OSCs based on R-2 and PC71BM without any processing additives and post-treatments. Our preliminary result demonstrates the possibility of utilizing Ir complexes as sole electron donors in OSCs, which extends available soluble small molecules for OSCs.
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