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- Amakawa, Hiroshi, et al.
(author)
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Isotopic compositions of Ce, Nd and Sr in ferromanganese nodules from the Pacific and Atlantic Oceans, the Baltic and Barents Seas, and the Gulf of Bothnia
- 1991
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In: Earth and Planetary Science Letters. - 0012-821X .- 1385-013X. ; 105:4, s. 554-565
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Journal article (peer-reviewed)abstract
- Ferromanganese nodules from the Pacific and Atlantic Oceans, the Barents and Baltic Seas, and the Gulf of Bothnia were analyzed for the isotopic compositions of Ce, Nd and Sr and the abundances of REE, Ba and Sr. REE patterns of Barents, Baltic and Bothnian samples show no Ce anomaly, or even a negative one, in contrast to the positive anomaly observed for the Pacific and Atlantic samples. Moreover, the Baltic and Bothnian samples have distinctly low εNd values; average εNd values of the four regions are as follows: Pacific -5, Barents -10, Atlantic -11 and Baltic inclusive of Gulf of Bothnia -19. The characteristic low εNd values of the Baltic samples are indicative of the influence of Precambrian rocks from the Baltic shield. Of particular interest is the feature of the Ce isotopic composition that εCe values of the samples from the Pacific are negative and those from the other three regions positive. This novel finding might suggest a difference in sources of Ce between the Pacific and other regions. These results demonstrate that Ce isotopic ratios can be a useful tracer in marine geochemistry, in combination with isotopic compositions of Nd and Sr.
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