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  • Heims, Florian, et al. (author)
  • Synthesis and Spectroscopic Characterisation of a Heterodinuclear Iron(III)-Copper(II) Complex Based on an Asymmetric Dinucleating Ligand System
  • 2012
  • In: European Journal of Inorganic Chemistry. - : Wiley. - 1099-0682 .- 1434-1948. ; :29, s. 4565-4569
  • Journal article (peer-reviewed)abstract
    • The site-directed generation of a heterodinuclear FeIIICuII complex by using a new asymmetric dinucleating ligand FloH is reported. The iron(III) ion is introduced first on the preferential metal-binding site of the ligand that leads to the formation of the thermodynamically favored five-membered chelate rings upon metal-binding. Copper(II) is introduced in the next step. The stepwise metalation strategy reported here may be extended to the preparation of other heterometallic complexes with the view of avoiding a statistical distribution. Such complexes can offer novel spectroscopic properties, electronic structures, and reactivities in comparison to their homometallic analogues.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Mebs, Stefan (1)
Greco, Claudio (1)
Powell, Annie K. (1)
Ciancetta, Antonella (1)
Heims, Florian (1)
Mereacre, Valeriu (1)
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Ray, Kallol (1)
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University
Lund University (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
Year
2012 (1)

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