1. |
- Adorno Lopes, Denise, et al.
(författare)
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Experimental and computational assessment of U-Si-N ternary phases
- 2019
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Ingår i: Journal of Nuclear Materials. - : Elsevier. - 0022-3115 .- 1873-4820. ; 516, s. 194-201
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Tidskriftsartikel (refereegranskat)abstract
- Uranium nitride-silicide composites are being considered as a high-density and high thermal conductivity fuel option for light water reactors. During development, chemical interactions were observed near the silicide melting point which resulted in formation of an unknown U-Si-N ternary phase. In the present work, U-Si-N composite samples were produced by arc-melting U3Si2 under an argon-nitrogen atmosphere to form the ternary phase. The resulting samples were characterized by SEM/EDS-EPMA and XRD, and demonstrated an equilibrium between U3Si2, UN, USi and a U-Si-N phase with a distinct crystallographic structure. Rietveld refinement of the ternary structure was performed, considering the ternary structures existent in the analogue U-Si-C system, and a good fit was obtained for the hexagonal U(20)Si(16)N(3 )phase. DFT + U calculations were performed in parallel to evaluate the thermodynamic and dynamic stability of the ternaries U20Si16N3 and U3Si2N2. The calculated enthalpy of formation and phonon dispersion support the existence of stable U20Si16N3 and U3Si2N2, although some soft modes in the U(20)Si(16)N(3)( )phase phonons are observed. The results presented here thus demonstrate the occurrence of at least one ternary phase in the U-Si-N system.
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2. |
- King, D. J. M., et al.
(författare)
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DFT study of the hexagonal high-entropy alloy fission product system
- 2017
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Ingår i: Journal of Nuclear Materials. - : Elsevier B.V.. - 0022-3115 .- 1873-4820. ; 488, s. 70-74
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Tidskriftsartikel (refereegranskat)abstract
- The metallic phase fission product containing Mo-Pd-Rh-Ru-Tc can be described as a hexagonal high-entropy alloy (HEA) and is thus investigated using atomic scale simulation techniques relevant to HEAs. Contrary to previous assumptions, the removal of Tc from the system to form the Mo-Pd-Rh-Ru analog is predicted to reduce the stability of the solid solution to the point that σ-Mo5Ru3 may precipitate out at typical fuel operating temperatures. The drive for segregation is attributed to the increased stability of the solid solution with the ejection of Mo and Ru. When Tc is included in the system, a single phase hexagonal solid solution is expected to form for a wider range of compositions. Furthermore, when cooled below 700 °C, this single phase solid solution is predicted to transition to a partially ordered structure. Future studies using the Tc-absent analogue will need to take these structural and chemical deliberations into consideration.
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3. |
- Obbard, E. G., et al.
(författare)
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Anisotropy in the thermal expansion of uranium silicide measured by neutron diffraction
- 2018
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Ingår i: Journal of Nuclear Materials. - : Elsevier. - 0022-3115 .- 1873-4820. ; 508, s. 516-520
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Tidskriftsartikel (refereegranskat)abstract
- In-situ neutron diffraction patterns were collected for a sample of as-cast U3Si2 during heating to 1600 degrees C. Anomalous changes were observed above 1000 degrees C, including the formation of a new diffraction peak not belonging to P4/mbm U3Si2, unequal changes in the peak intensities and onset of anisotropic lattice expansion. The large data-set enabled derivation of a function-fitted isotropic thermal expansion coefficient to high precision, in close agreement with previous dilatometry results but reducing linearly with temperature over the studied interval. Anisotropy in the instantaneous lattice thermal expansion corresponded to anomalies reported by White et al. (2015) at a similar temperature.
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