1. |
- Nylén, H., et al.
(author)
-
O KVV Auger emission versus resonant photoemission at the O K edge of high-Tc superconductors
- 1998
-
In: Physica C: Superconductivity and its Applications. - 0921-4534. ; 300:3-4, s. 161-170
-
Journal article (peer-reviewed)abstract
- Photoelectron spectroscopy results on single crystals of the superconductors Bi2Sr2CaCu2O8,Bi2Sr 2CuO6, Ba0.6K0.4BiO3 and the semiconductor Ba0.9K0.1BiO3 are reported for the photon energy region around the O K absorption threshold. The development of the O-KVV Auger structure has been carefully monitored as a function of photon energy. A non-monotonic behavior displaying a feature at a constant binding energy of about 14 eV was found for Bi2Sr2CaCu2O8 and Bi2Sr2CuO6 in a narrow photon energy region of 1 eV at the main edge of the O K absorption spectrum around 530 eV. The corresponding enhancement, connected with the autoionization of O 2 p states, is absent in Ba1-xKxBiO3 in contrast to Bi2Sr2CaCu2O8 and Bi2Sr2CuO6. The resonant enhancement is more pronounced for Bi2Sr2CuO6 as compared to Bi2Sr2CaCu2O8, which can be explained by a lower charge carrier concentration in the former case, leading to a more localized nature of intermediate O 2 p states. The model parameters Cu d-d and O p-p Coulomb interactions and the charge transfer energy Δ are estimated from the experiments.
|
|
2. |
- Lev, L. L., et al.
(author)
-
Resonant photoemission study of La1-xSrxMnO3 single crystals
- 2005
-
In: Physica Scripta. - 0031-8949. ; T115, s. 654-657
-
Journal article (peer-reviewed)abstract
- A feature at a binding energy of similar to 2.5eV which has not previously been discussed in the literature is observed in the photoemission spectra of the valence band of La1-xSrxMnO3 single crystals. To reveal the origin of this feature measurements of resonant photoemission on La1-xSrxMnO3 were performed as well as absorption spectra at the La N and Mn L-2,L-3 edges at liquid nitrogen and room temperatures. Only for Mn L edge we observed a clear resonance for a binding energy corresponding to the feature of interest. Comparison with the calculated density of states led to the conclusion that the feature corresponds to Mn t(2g) states.
|
|
3. |
- Qvarford, M, et al.
(author)
-
Photoemission and x-ray absorption study of superconducting and semiconducting Ba1-xKxBiO3 single crystals
- 1996
-
In: Physical Review B Condensed Matter. - 0163-1829 .- 1095-3795. ; 54:9, s. 6700-6707
-
Journal article (peer-reviewed)abstract
- Semiconducting Ba0.9K0.1BiO3 and superconducting Ba0.6K0.4BiO3 single crystals cleaved in situ have been studied by core level and valence band photoelectron spectroscopy and O K edge x-ray absorption spectroscopy. It was found that the general shape of the valence band spectrum agrees with the shape predicted by band structure calculations, but the intensity near the Fermi level, was lower in the experimental spectrum as compared to the calculated. The O K edge spectra showed that the metallic phase is not related to the presence of doping inducted O 2p holes. This property of Ba1-xKxBiO3 shows that the semiconductor-metal transition of this system is of a different nature than that of the hole doped cuprate high-T-c superconductors. The core level photoemission spectra of the cations showed a small asymmetry for Ba0.9K0.1BiO3. Corresponding spectra for Ba0.6K0.4BiO3 showed a larger asymmetry resulting in a resolved high binding energy shoulder in the Bi 4f spectrum. The origin of this feature is discussed.
|
|
4. |
- Ivanov, A. A., et al.
(author)
-
Studying the effect of oxygen content on the electron structure of Nd1.85Ce0.15CuO4 by means of photoelectron spectromicroscopy
- 2007
-
In: Journal of Experimental and Theoretical Physics. - 1063-7761. ; 105:1, s. 241-245
-
Journal article (peer-reviewed)abstract
- Changes in the electron structure of the surface layer of Nd1.85Ce0.15CuO4 (NCCO) epitaxial films, which were caused by variation of the oxygen content and modification of the crystal structure of samples as a result of Ar+ ion etching and annealing, have been studied by means of photoelectron spectromicroscopy. A method is proposed for the cleaning the surface of oxygen-containing superconductors, which includes sequential stages of deep ion etching, high-temperature annealing in an oxygen-containing atmosphere (for the structural recovery and saturation with oxygen), a short-term ion etching (for the removal of an adsorbed layer of the oxidizer), and the final vacuum annealing of radiation-induced effects. The application of this procedure to NCCO films allowed an electron structure to be obtained, which was identical to that inherent in the surface of single crystals cleaved in situ in the measurement chamber.
|
|
5. |
|
|
6. |
- Monk, Bradley J., et al.
(author)
-
A Randomized, Phase III Trial to Evaluate Rucaparib Monotherapy as Maintenance Treatment in Patients With Newly Diagnosed Ovarian Cancer (ATHENA-MONO/GOG-3020/ENGOT-ov45)
- 2022
-
In: Journal of Clinical Oncology. - : Lippincott, Williams & Wilkins. - 0732-183X .- 1527-7755. ; 40:34, s. 3952-3964
-
Journal article (peer-reviewed)abstract
- PURPOSEATHENA (ClinicalTrials.gov identifier: ) was designed to evaluate rucaparib first-line maintenance treatment in a broad patient population, including those without BRCA1 or BRCA2 (BRCA) mutations or other evidence of homologous recombination deficiency (HRD), or high-risk clinical characteristics such as residual disease. We report the results from the ATHENA-MONO comparison of rucaparib versus placebo.METHODSPatients with stage III-IV high-grade ovarian cancer undergoing surgical cytoreduction (R0/complete resection permitted) and responding to first-line platinum-doublet chemotherapy were randomly assigned 4:1 to oral rucaparib 600 mg twice a day or placebo. Stratification factors were HRD test status, residual disease after chemotherapy, and timing of surgery. The primary end point of investigator-assessed progression-free survival was assessed in a step-down procedure, first in the HRD population (BRCA-mutant or BRCA wild-type/loss of heterozygosity high tumor), and then in the intent-to-treat population.RESULTSAs of March 23, 2022 (data cutoff), 427 and 111 patients were randomly assigned to rucaparib or placebo, respectively (HRD population: 185 v 49). Median progression-free survival (95% CI) was 28.7 months (23.0 to not reached) with rucaparib versus 11.3 months (9.1 to 22.1) with placebo in the HRD population (log-rank P = .0004; hazard ratio [HR], 0.47; 95% CI, 0.31 to 0.72); 20.2 months (15.2 to 24.7) versus 9.2 months (8.3 to 12.2) in the intent-to-treat population (log-rank P < .0001; HR, 0.52; 95% CI, 0.40 to 0.68); and 12.1 months (11.1 to 17.7) versus 9.1 months (4.0 to 12.2) in the HRD-negative population (HR, 0.65; 95% CI, 0.45 to 0.95). The most common grade & GE; 3 treatment-emergent adverse events were anemia (rucaparib, 28.7% v placebo, 0%) and neutropenia (14.6% v 0.9%).CONCLUSIONRucaparib monotherapy is effective as first-line maintenance, conferring significant benefit versus placebo in patients with advanced ovarian cancer with and without HRD.
|
|
7. |
- Tsetlin, M. B., et al.
(author)
-
Investigation of Epitaxial Nd1.85Ce0.15CuO4-y Film Surface by Low Energy Electron Diffractometry
- 2008
-
In: Journal Of Surface Investigation-X-Ray Synchrotron And Neutron Techniques. - 1027-4510. ; 2:6, s. 928-930
-
Journal article (peer-reviewed)abstract
- The surface of epitaxial Nd1.85Ce0.15CuO4-y(001) (NCCO) film has been studied by low energy electron diffractometry (LEED) and photoelectron spectroscopy. Ar+ ion etching of a surface with subsequent annealing in oxygen at atmosphere pressure has been found to lead to the ordered structure restoration of surface layers with the symmetry type and lattice parameters corresponding to the NCCO phase. Annealing in vacuum at temperatures close to the boundary of thermodynamic phase stability results in the formation of epitaxial Ce0.5Nd0.5O1.75 phase on a surface that is indicated in the LEED pattern as additional spots corresponding to the surface lattice (root 2 x root 2) R45 degrees.
|
|
8. |
- Tsetlin, M. B., et al.
(author)
-
Spatial Structures Formed during High-Temperature Vacuum Annealing of Diamond-Like Film Deposited on a Silicon Substrate
- 2009
-
In: Journal Of Surface Investigation-X-Ray Synchrotron And Neutron Techniques. - 1027-4510. ; 3:5, s. 752-755
-
Journal article (peer-reviewed)abstract
- The process of an ultrahigh vacuum annealing of a diamond-like carbon film deposited on a silicon substrate has been studied in situ using a photoemission microscope mounted at the MAX-lab synchrotron's radiation source. After the annealing the film was examined ex situ using an atomic force microscope. It is revealed that the graphitization of the film occurs and round formations of several microns in size with a core of similar to 0.2 mu m in size appear on its surface at the temperature exceeding 1000 degrees C. Photoemission images of these formations have shown the presence of silicon on their surface. Apparently, the interaction between the carbon film and silicon substrate begins in the middle of the formation and spreads to the adjacent region at the following stage.
|
|