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  • Chubarova, Elena V., et al. (author)
  • Self-assembly of a heteropolyoxopalladate nanocube : [PdII 13AsV 8O34(OH)6] 8-
  • 2008
  • In: Angewandte Chemie International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 47:49, s. 9542-9546
  • Journal article (peer-reviewed)abstract
    • (Chemical Equation Presented) Not like the others: A molecular palladium oxide cluster was formed by self-assembly of palladium(II) and arsenic(V) using mild reaction conditions. The resulting heteropolypalladate [Pd II 13AsV 8O34(OH) 6]8- has a distorted cubic shape and edge lengths of about 1 nm. The thirteen PdII ions retain four-coordinate square-planar geometry, in marked contrast to all other known discrete polyoxometalates.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Chubarova, Elena V. (1)
Dickman, M. H. (1)
Nadjo, L. (1)
Kortz, U. (1)
Keita, B. (1)
Miserque, F. (1)
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Mifsud, M. (1)
Arends, I. W. C. E. (1)
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University
Royal Institute of Technology (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
Year
2008 (1)

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