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- Strandberg, B, et al.
(author)
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Organochlorine compounds in the Gulf of Bothnia : sediment and benthic species
- 2000
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In: Chemosphere. ; 40:9-11, s. 1205-1211
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Journal article (peer-reviewed)abstract
- Surface sediment, amphipods (Monoporeia affinis), isopods (Saduria entomon) and fourhorn sculpins (Oncocottus quadricornis) were collected at two coastal stations in the Gulf of Bothnia, one in the Bothnian Bay and the other in the Bothnian Sea. The objective was to study the concentrations, composition profiles, bioaccumulation features and spatial differences of organochlorine compounds such as hexachlorocyclohexanes (HCHs), DDTs, hexachlorobenzene (HCBz), chlordanes (CHLs), dieldrin, Mirex and polychlorinated biphenyls (PCBs). All groups of compounds were found in every sample investigated, with the exception of Mirex that was not detected in the sediment samples. The concentrations for e.g. PCBs and CHLs ranged from 700 to 2400 and 70 to 400 ng/g lipid in the specimens. For the corresponding sediments the results were 9.0-9.3 ng/g dw for PCBs and 0.54-0.57 ng/g dw for CHLs, respectively. Bioaccumulation differences between the species with regard to both degree of and type of compound were observed. The highest accumulation potential was found for the cyclodiene compounds including CHLs and Mirex in isopod. Finally, there were only small concentration and bioaccumulation differences between the two stations.
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- Engwall, Magnus, 1965-, et al.
(author)
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Biological and chemical determination of contaminant levels in settling particulate matter and sediments : a Swedish river system before, during, and after dredging of PCB-contaminated lake sediments
- 1998
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In: Ambio. - 0044-7447 .- 1654-7209. ; 27:5, s. 403-410
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Journal article (peer-reviewed)abstract
- A sensitive bioassay, based on EROD induction in cultured chicken embryo livers, was used together with chemical analysis to determine levels of dioxin-like contaminants in particulate matter in Eman. Extracts of sediment and settling particulate matter (SPM) collected in the river system before, during, and after dredging of a PCB contaminated lake, Lake Jarnsjon, were separated into three fractions containing a) monoaromatic/aliphatic; b) diaromatic (e.g., PCBs and polychlorinated dibenzodioxins and dibenzofurans); and c) polyaromatic compounds (e.g., polycyclic aromatic hydrocarbons). The samples from Lake Jarnsjon contained the highest PCB concentrations and the diaromatic extracts from Lake Jarnsjon samples showed the highest activities of EROD-inducing diaromatic compounds. The dioxin-like activity of the diaromatic fraction in sediment collected after the dredging of Jarnsjon had only around 1% of the activity of the pre-dredging sediment, showing that the remediation was successful in terms of removal of the PCB-contaminated sediment from the lake. In SPM collected immediately downstream from Jarnsjon, levels of diaromatic dioxin-like compounds were elevated during the dredging, and decreased after that. The post-dredging concentrations were however higher than in SPM from lakes upstream of Jarnsjon, showing that elevated levels of dioxin-like diaromatic compounds were still present in the water System downstream of Jarnsjon a couple of years after the dredging.
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