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- Cronin, T. M., et al.
(author)
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Holocene paleoceanography and glacial history of Lincoln Sea, Ryder Glacier, Northern Greenland, based on foraminifera and ostracodes
- 2022
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In: Marine Micropaleontology. - : Elsevier BV. - 0377-8398 .- 1872-6186. ; 175
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Journal article (peer-reviewed)abstract
- We reconstructed Holocene paleoceanography of the Sherard Osborn Fjord (SOF), N Greenland, and Lincoln Sea in the eastern Arctic Ocean using sediment properties and micropaleontology from cores obtained during the Ryder 2019 Expedition. Our aims were to better understand faunal indicators of water mass influence on Ryder Glacier and the Lincoln Sea at water depths >500 m. Benthic microfaunal reflect glacio-marine interval during late deglaciation ~10.5 to 8.5 ka (kiloannum) during the Holocene Thermal Maximum (HTM) with dominant benthic foraminiferal species Cassidulina neoteretis, Cassidulina reniforme, and the ostracode Rabilimis mirabilis. Casssidulina neoteretis is considered an indicator of Atlantic Water (AW) throughout the Arctic Ocean and Nordic Seas; C. reniforme reflects glacio-marine conditions from the retreating Ryder Glacier. Deglaciation was followed by a period of elevated productivity and diverse ostracode faunal assemblages that suggest AW influence from 8.5 to 6 ka in the Lincoln Sea and inside SOF. The Holocene occurrence of the ostracode species Acetabulastoma arcticum, that appears in low numbers in the Lincoln Sea and briefly (~ 4–3 ka) in SOF, reflects the presence of variable sea ice in this region. Based on the similarities of the Lincoln Sea and fjord ostracodes to modern and glacial-deglacial faunas from the central Arctic Ocean, the AW influence likely originates from recirculation of AW water from the central Arctic Basin. In general, our results suggest a strong but temporally varying influence of AW during the entire 10.5 kyr record of the Lincoln Sea and SOF.
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- Heiss, M., et al.
(author)
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Self-assembled quantum dots in a nanowire system for quantum photonics
- 2013
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In: Nature Materials. - 1476-4660. ; 12:5, s. 439-444
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Journal article (peer-reviewed)abstract
- Quantum dots embedded within nanowires represent one of the most promising technologies for applications in quantum photonics. Whereas the top-down fabrication of such structures remains a technological challenge, their bottom-up fabrication through self-assembly is a potentially more powerful strategy. However, present approaches often yield quantum dots with large optical linewidths, making reproducibility of their physical properties difficult. We present a versatile quantum-dot-innanowire system that reproducibly self-assembles in core-shell GaAs/AlGaAs nanowires. The quantum dots form at the apex of a GaAs/AlGaAs interface, are highly stable, and can be positioned with nanometre precision relative to the nanowire centre. Unusually, their emission is blue-shifted relative to the lowest energy continuum states of the GaAs core. Large-scale electronic structure calculations show that the origin of the optical transitions lies in quantum confinement due to Al-rich barriers. By emitting in the red and self-assembling on silicon substrates, these quantum dots could therefore become building blocks for solid-state lighting devices and third-generation solar cells.
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- Lepp, Allison P., et al.
(author)
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Insights into glacial processes from micromorphology of silt-sized sediment
- 2024
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In: The Cryosphere. - 1994-0416 .- 1994-0424. ; 18:5, s. 2297-2319
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Journal article (peer-reviewed)abstract
- Silt-rich meltwater plume deposits (MPDs) analyzed from marine sediment cores have elucidated relationships that are clearly connected, yet difficult to constrain, between subglacial hydrology, ice-marginal landforms, and grounding-zone retreat patterns for several glacial catchments. Few attempts have been made to infer details of subglacial hydrology, such as flow regime, geometry of drainage pathways, and mode(s) of sediment transport through time, from grain-scale characteristics of MPDs. Using sediment samples from MPD, till, and grounding-zone proximal diamicton collected offshore of six modern and relict glacial catchments in both hemispheres, we examine grain shape distributions and microtextures (collectively, grain micromorphology) of the silt fraction to explore whether grains are measurably altered from their subglacial sources via meltwater action. We find that 75 % of all imaged grains (n = 9400) can be described by 25 % of the full range of measured shape morphometrics, indicating grain shape homogenization through widespread and efficient abrasive processes in subglacial environments. Although silt grains from MPDs exhibit edge rounding more often than silt grains from tills, grain surface textures indicative of fluvial transport (e.g., v-shaped percussions) occur in only a modest number of grains. Furthermore, MPD grain surfaces retain several textures consistent with transport beneath glacial ice (e.g., straight or arcuate steps, (sub)linear fractures) in comparable abundances to till grains. Significant grain shape alteration in MPDs compared to their till sources is observed in sediments from glacial regions where (1) high-magnitude, potentially catastrophic meltwater drainage events are inferred from marine sediment records and (2) submarine landforms suggest supraglacial melt contributed to the subglacial hydrological budget. This implies that quantifiable grain shape alteration in MPDs could reflect a combination of high-energy flow of subglacial meltwater, persistent sediment entrainment, and/or long sediment transport distances through subglacial drainage pathways. Integrating grain micromorphology into analysis of MPDs in site-specific studies could therefore aid in distinguishing periods of persistent, well-connected subglacial discharge from periods of sluggish or disorganized drainage. In the wider context of deglacial marine sedimentary and bathymetric records, a grain micromorphological approach may bolster our ability to characterize ice response to subglacial meltwater transmission through time. This work additionally demonstrates that glacial and fluvial surface textures are retained on silt-sized quartz grains in adequate amounts for microtexture analysis, which has heretofore been conducted exclusively on the sand fraction. Therefore, grain microtextures can be examined on silt-rich glaciogenic deposits that contain little to no sand as a means to evaluate sediment transport processes.
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- Moia, Davide, et al.
(author)
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The Role of Hole Transport between Dyes in Solid-State Dye-Sensitized Solar Cells
- 2015
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In: The Journal of Physical Chemistry C. - : AMER CHEMICAL SOC. - 1932-7447 .- 1932-7455. ; 119:33, s. 18975-18985
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Journal article (peer-reviewed)abstract
- In dye-sensitized solar cells (DSSCs) photo-generated positive charges are normally considered to be carried away from the dyes by a separate phase of hole-transporting material (HTM). We show that there can also be significant transport within the dye monolayer itself before the hole reaches the HTM. We quantify the fraction of dye regeneration in solid-state DSSCs that can be attributed to this process. By using cyclic voltammetry and transient anisotropy spectroscopy, we demonstrate that the rate of interdye hole transport is prevented both on micrometer and nanometer length scales by reducing the dye loading on the TiO2 surface. The dye regeneration yield is quantified for films with high and low dye loadings (with and without hole percolation in the dye monolayer) infiltrated with varying levels of HTM. Interdye hole transport can account for >50% of the overall dye regeneration with low HTM pore filling. This is reduced to about 5% when the infiltration of the HTM in the pores is optimized in 2 mu m thick films. Finally, we use hole transport in the dye monolayer to characterize the spatial distribution of the HTM phase in the pores of the dyed mesoporous TiO2.
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