| 1. |
|
|
| 2. |
- Mikkonen, K. S., et al.
(author)
-
Glucomannan composite films with cellulose nanowhiskers
- 2010
-
In: Cellulose. - : Springer Science and Business Media LLC. - 0969-0239 .- 1572-882X. ; 17:1, s. 69-81
-
Journal article (peer-reviewed)abstract
- Spruce galactoglucomannans (GGM) and konjac glucomannan (KGM) were mixed with cellulose nanowhiskers (CNW) to form composite films. Remarkable effects of CNW on the appearance of the films were detected when viewed with regular and polarizing optical microscopes and with a scanning electron microscope. Addition of CNW to KGM-based films induced the formation of fiberlike structures with lengths of several millimeters. In GGM-based films, rodlike structures with lengths of several tens of micrometers were formed. The degree of crystallinity of mannan in the plasticized KGM-based films increased slightly when CNW were added, from 25 to 30%. The tensile strength of the KGM-based films not containing glycerol increased with increasing CNW content from 57 to 74 MPa, but that of glycerol-plasticized KGM and GGM films was not affected. Interestingly, the notable differences in the film structure did not appear to be related to the thermal properties of the films.
|
|
| 3. |
|
|
| 4. |
|
|
| 5. |
- Stevanic, J. S., et al.
(author)
-
Bacterial Nanocellulose-Reinforced Arabinoxylan Films MELL TE, 1964, V19, P247
- 2011
-
In: Journal of Applied Polymer Science. - : Wiley. - 1097-4628 .- 0021-8995. ; 122:2, s. 1030-1039
-
Journal article (peer-reviewed)abstract
- There is an increasing interest in substituting today's films for food packaging applications with films based on renewable resources. For this purpose, rye arabinoxylans, unmodified and enzymatically debranched, were studied for the preparation of neat films and composite films reinforced with bacterial cellulose (BC). Mixing in a homogenizer produced optically transparent, uniform films. Physical and mechanical characteristics of such films are here reported. Debranching of the arabinoxylan caused an increase in its crystallinity of 20%. Debranching as well as reinforcement with BC resulted in a decrease of the moisture sorption of the films. The debranching also resulted in a reduced breaking strain while the reinforcement with BC increased stiffness and strength of the films. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 122: 1030-1039, 2011
|
|
