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- Zaccarini, Frederica, et al.
(author)
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Chromite and platinum group elements mineralization in the Santa Elena Ultramafic Nappe (Costa Rica) : Geodynamic implications
- 2011
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In: Geologica Acta. - 1695-6133 .- 1696-5728. ; 9:3-4, s. 407-423
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Journal article (peer-reviewed)abstract
- Chromitites associated with strongly altered peridotite from six distinct localities in the Santa Elena ultramaficnappe (Costa Rica) have been investigated for the first time. Santa Elena chromitites commonly display acompositional variation from extremely chromiferous (Cr/(Cr+Al)=0.81) to intermediate and aluminous(Cr/(Cr+Al)=0.54). This composition varies along a continuous trend, corresponding to calculated parental liquidswhich may have been derived from the differentiation of a single batch of boninitic magma with Cr-rich and(Al, Ti)-poor initial composition. Fractional precipitation of chromite probably occurred during differentiation ofthe boninitic melt and progressive metasomatic reaction with mantle peridotite. The distribution of platinum groupelements (PGE) displays the high (Os+Ir+Ru)/(Rh+Pt+Pd) ratio typical of ophiolitic chromitites and, consistently,the platinum group minerals (PGM) encountered are mainly Ru-Os-Ir sulfides and arsenides. Textural relations ofmost of the platinum group elements suggest crystallization at magmatic temperatures, possibly under relativelyhigh sulfur fugacity as indicated by the apparent lack of primary Os-Ir-Ru alloys.The chemical and mineralogical characteristics of chromitites from the Santa Elena ultramafic nappe have astrong affinity to podiform chromitites in the mantle section of supra-subduction-zone ophiolites. Calculatedparental melts of the chromitites are consistent with the differentiation of arc-related magmas, and do not supportthe oceanic spreading center geodynamic setting previously proposed by some authors.
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- Aiglsperger, Thomas, et al.
(author)
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Geochemistry of REE-rich karst bauxite ore deposits from the Sierra de Bahoruco, Dominican Republic
- 2019
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In: Proceedings of the 15th SGA Biennial Meeting, 27-30 August. - : University of Glasgow Publicity Services. ; , s. 1834-1836
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Conference paper (peer-reviewed)abstract
- In this work the geochemistry of REE-rich karst bauxite ore from several deposits of the Sierra de Bahoruco (Dominican Republic) has been investigated. The bauxite ores are geochemically heterogenous and show differences with respect to major, minor and trace elements. According to their major element geochemistry, the studied ores classify mostly as Fe-rich bauxites. The minor elements Cr and Ni are in general relatively high (up to 1250 and 2370 ppm, respectively), hence pointing towards a (ultra-)mafic source for the bauxite formation. The sum of REE contents range from similar to 400 to similar to 5400 ppm (average similar to 1200 ppm) at varying LREE/HREE between similar to 1 and similar to 25 (average similar to 8). In general, REE chondrite-normalized patterns for studied bauxites show negative Ce and Eu anomalies with rather flat segments for HREE. However, three samples from different bauxite ore deposits with the highest REE contents show significant enrichment trends for heavier REE, particularly for Pr, Nd, Sm, Gd as well as for Tb and Dy (one sample). Mineralogical studies reveal that formation of secondary REE-bearing minerals (i.e. phosphates, carbonates and oxides) occurred. Karst bauxite ores hosted in the Sierra de Bahoruco represent an excellent natural laboratory to study the geochemical behaviour of REE in weathering systems.
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- Aiglsperger, Thomas, et al.
(author)
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Open system Re-Os isotope behavior in platinum-group minerals during laterization?
- 2021
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In: Minerals. - : MDPI. - 2075-163X. ; 11:10
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Journal article (peer-reviewed)abstract
- In this short communication, we present preliminary data on the Re-Os isotopic systematics of platinum-group minerals (PGM) recovered from different horizons in the Falcondo Ni-laterite in the Dominican Republic. The results show differences in the Os-isotope composition in different populations of PGM: (i) pre-lateritic PGM yield 187 Os/188 Os varying from 0.11973 ± 0.00134 to 0.12215 ± 0.00005 (2σ uncertainty) whereas (ii) lateritic PGM are more radiogenic in terms of 187 Os/188 Os (from 0.12390 ± 0.00001 to 0.12645 ± 0.00005; 2σ uncertainty). We suggest that these differences reflect the opening of the Re-Os system in individual grains of PGM during lateritic weathering. The implications of these results are twofold as they will help to (1) elucidate the small-scale mobility of noble metals in the supergene setting and therefore the possible formation of PGM at these very low temperatures, (2) better refine the Os-isotopic datasets of PGM that are currently being used for defining dynamic models of core–mantle separation, crustal generation, and fundamental plate-tectonic processes such as the opening of oceans.
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