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  • Bernigaud, Virgile, et al. (author)
  • Electron capture-induced dissociation of AK dipeptide dications : Influence of ion velocity, crown-ether complexation and collision gas
  • 2008
  • In: International Journal of Mass Spectrometry. - : Elsevier BV. - 1387-3806 .- 1873-2798. ; 276:2-3, s. 77-81
  • Journal article (peer-reviewed)abstract
    • The fragmentation of doubly protonated AK dipeptide ions has been investigated after collisional electron transfer. Electron capture leads to three dominant channels, H loss, NH3 loss, and N–Cα bond breakage to give either c+ or z+ fragment ions. The relative importance of these channels has been explored as a function of ion velocity, the degree of complexation with crown ether, and collision gas. Our results indicate that H loss and NH3 loss are competing channels whereas the probability of N–Cα bond breakage is more or less constant.
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