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Träfflista för sökning "WFRF:(Radebe Mduduzi P.) "

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  • Elantabli, Fatma M., et al. (author)
  • Thiophene based imino-pyridyl palladium(II) complexes : Synthesis, molecular structures and Heck coupling reactions
  • 2017
  • In: Journal of Organometallic Chemistry. - : Elsevier BV. - 0022-328X. ; 843, s. 40-47
  • Journal article (peer-reviewed)abstract
    • The new compounds (5-methyl-2-thiophene-2-pyridyl(R))imine [R = methyl (L1); R = ethyl (L2)] and (5-bromo-2-thiophene-2-pyridyl(R)imine [R = methyl (L3); R = ethyl (L4)] were successfully synthesized via Schiff base condensation reaction and obtained in good yields. These potential ligands were reacted with [PdCl2(COD)] and [PdClMe(COD)] to give the corresponding complexes [PdCl2(L)] (L = L1-L4; 1–4) and [PdClMe(L)] (L = L1-L4; 5–8). All compounds were characterized by IR, 1H and 13C NMR spectroscopy, elemental analysis and mass spectrometry. The molecular structures of 1, 2, 6 and 8 were confirmed by X-ray crystallography. The complexes were evaluated as catalyst precursors for standard Heck coupling reactions and showed significant catalytic activities that could be correlated with steric and electronic influences.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Haukka, Matti (1)
Nordlander, Ebbe (1)
Ekengard, Erik (1)
Elantabli, Fatma M. (1)
Radebe, Mduduzi P. (1)
Motswainyana, Willia ... (1)
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Owaga, Bernard O. (1)
El-Medani, Samir M. (1)
Onani, Martin O. (1)
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University
Lund University (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
Year
2017 (1)

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