1. |
- Dash, Aditya, 2023-, et al.
(author)
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Spontaneous Modulation Doping in Semi‐Crystalline Conjugated Polymers Leads to High Conductivity at Low Doping Concentration
- 2023
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In: Advanced Materials. - : Wiley-VCH Verlagsgesellschaft. - 0935-9648 .- 1521-4095.
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Journal article (peer-reviewed)abstract
- The possibility to control the charge carrier density through doping is one of the defining properties of semiconductors. For organic semiconductors, the doping process is known to come with several problems associated with the dopant compromising the charge carrier mobility by deteriorating the host morphology and/or introducing Coulomb traps. While for inorganic semiconductors these factors can be mitigated through (top-down) modulation doping, this concept has not been employed in organics. Here, this work shows that properly chosen host/dopant combinations can give rise to spontaneous, bottom-up modulation doping, in which the dopants preferentially sit in an amorphous phase, while the actual charge transport occurs predominantly in a crystalline phase with an unaltered microstructure, spatially separating dopants and mobile charges. Combining experiments and numerical simulations, this work shows that this leads to exceptionally high conductivities at relatively low dopant concentrations.
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2. |
- Derewjanko, Dennis, et al.
(author)
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Delocalization Enhances Conductivity at High Doping Concentrations
- 2022
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In: Advanced Functional Materials. - : Wiley. - 1616-3028 .- 1616-301X. ; 32:20
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Journal article (peer-reviewed)abstract
- Many applications of organic semiconductors require high electrical conductivities and hence high doping levels. Therefore, it is indispensable for effective material design to have an accurate understanding of the underlying transport mechanisms in this regime. In this study, own and literature experimental data that reveal a power-law relation between the conductivity and charge density of strongly p-doped conjugated polymers are combined. This behavior cannot consistently be described with conventional models for charge transport in energetically disordered materials. Here, it is shown that the observations can be explained in terms of a variable range hopping model with an energy-dependent localization length. A tight-binding model is used to quantitatively estimate of the energy-dependent localization length, which is used in an analytical variable range hopping model. In the limit of low charge densities, the model reproduces the well-known Mott variable range hopping behavior, while for high charge densities, the experimentally observed superlinear increase in conductivity with charge density is reproduced. The latter behavior occurs when the Fermi level reaches partially delocalized states. This insight can be anticipated to lead to new strategies to increase the conductivity of organic semiconductors.
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3. |
- Liu, Jian, 1985, et al.
(author)
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Electrically Programmed Doping Gradients Optimize the Thermoelectric Power Factor of a Conjugated Polymer
- 2024
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In: Advanced Functional Materials. - 1616-3028 .- 1616-301X. ; 34:18
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Journal article (peer-reviewed)abstract
- Functionally graded materials (FGMs) are widely explored in the context of inorganic thermoelectrics, but not yet in organic thermoelectrics. Here, the impact of doping gradients on the thermoelectric properties of a chemically doped conjugated polymer is studied. The in-plane drift of counterions in moderate electric fields is used to create lateral doping gradients in films composed of a polythiophene with oligoether side chains, doped with 2,3,5,6-tetrafluoro-tetracyanoquinodimethane (F4TCNQ). Raman microscopy reveals that a bias voltage of as little as 5 V across a 50 µm wide channel is sufficient to trigger counterion drift, resulting in doping gradients. The effective electrical conductivity of the graded channel decreases with bias voltage, while an overall increase in Seebeck coefficient is observed, yielding an up to eight-fold enhancement in power factor. Kinetic Monte Carlo simulations of graded films explain the increase in power factor in terms of a roll-off of the Seebeck coefficient at high electrical conductivities in combination with a mobility decay due to increased Coulomb scattering at high dopant concentrations. Therefore, the FGM concept is found to be a way to improve the thermoelectric performance of not yet optimally doped organic semiconductors, which may ease the screening of new materials as well as the fabrication of devices.
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4. |
- Scheunemann, Dorothea, et al.
(author)
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Non-Wiedemann-Franz behavior of the thermal conductivity of organic semiconductors
- 2020
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In: Physical Review B. - : AMER PHYSICAL SOC. - 2469-9950 .- 2469-9969. ; 101:7
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Journal article (peer-reviewed)abstract
- Organic semiconductors have attracted increasing interest as thermoelectric converters in recent years due to their intrinsically low thermal conductivity compared to inorganic materials. This boom has led to encouraging practical results in which the thermal conductivity has predominantly been treated as an empirical number. However, in an optimized thermoelectric material, the electronic component can dominate the thermal conductivity, in which case the figure of merit ZT becomes a function of thermopower and Lorentz factor only. Hence the design of effective organic thermoelectric materials requires understanding the Lorenz number. Here, analytical modeling and kinetic Monte Carlo simulations are combined to study the effect of energetic disorder and length scales on the correlation of electrical and thermal conductivity in organic semiconductor thermoelectrics. We show that a Lorenz factor up to a factor similar to 5 below the Sommerfeld value can be obtained for weakly disordered systems, in contrast with what has been observed for materials with band transport. Although the electronic contribution dominates the thermal conductivity within the application-relevant parameter space, reaching ZT amp;gt; 1 would require minimization of both the energetic disorder and also the lattice thermal conductivity to values below kappa(1at) amp;lt; 0.2 W/mK.
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5. |
- Scheunemann, Dorothea, et al.
(author)
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Rubbing and Drawing: Generic Ways to Improve the Thermoelectric Power Factor of Organic Semiconductors?
- 2020
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In: Advanced Electronic Materials. - : WILEY. - 2199-160X. ; 6:8
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Journal article (peer-reviewed)abstract
- Highly oriented polymer films can show considerable anisotropy in the thermoelectric properties leading to power factors beyond those predicted by the widely obeyed power law linking the thermopowerSand the electrical conductivity sigma asS proportional to sigma(-1/4). This has led to encouraging practical results with respect to the electrical conductivity, notwithstanding that the conditions necessary to enhance sigma andSsimultaneously are less clear. Here, kinetic Monte Carlo simulations are used to study the impact of structural anisotropy on the thermoelectric properties of disordered organic semiconductors. It is found that stretching is a suitable strategy to improve the conductivity along the direction of strain, whereas the effect on the power factor depends on the morphology the polymer crystallizes. In general, crystalline polymers show a simultaneous increase in sigma andSwhich is not the case for amorphous polymers. Moreover, it is shown that the trends resulting from simulations based on variable-range hopping are in good agreement with experiments and can describe the different functional dependencies in theSversus sigma behavior of different directions.
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6. |
- Untilova, Viktoriia, et al.
(author)
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High Thermoelectric Power Factor of Poly(3-hexylthiophene) through In-Plane Alignment and Doping with a Molybdenum Dithiolene Complex
- 2020
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In: Macromolecules. - : American Chemical Society (ACS). - 1520-5835 .- 0024-9297. ; 53:15, s. 6314-6321
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Journal article (peer-reviewed)abstract
- We report a record thermoelectric power factor of up to 160 μW m-1 K-2 for the conjugated polymer poly(3-hexylthiophene) (P3HT). This result is achieved through the combination of high-temperature rubbing of thin films together with the use of a large molybdenum dithiolene p-dopant with a high electron affinity. Comparison of the UV-vis-NIR spectra of the chemically doped samples to electrochemically oxidized material reveals an oxidation level of 10%, i.e., one polaron for every 10 repeat units. The high power factor arises due to an increase in the charge-carrier mobility and hence electrical conductivity along the rubbing direction. We conclude that P3HT, with its facile synthesis and outstanding processability, should not be ruled out as a potential thermoelectric material. ©
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7. |
- Upreti, Tanvi, et al.
(author)
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Experimentally Validated Hopping-Transport Model for Energetically Disordered Organic Semiconductors
- 2019
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In: Physical Review Applied. - : AMER PHYSICAL SOC. - 2331-7019. ; 12:6
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Journal article (peer-reviewed)abstract
- Charge transport in disordered organic semiconductors occurs by hopping of charge carriers between localized sites that are randomly distributed in a strongly energy-dependent density of states. Extracting disorder and hopping parameters from experimental data, such as temperature-dependent current-voltage characteristics, typically relies on parametrized mobility functionals that are integrated in a drift-diffusion solver. Surprisingly, the functional based on the extended Gaussian disorder model (eGDM) is extremely successful at this, despite it being based on the assumption of nearest neighbor hopping (nnH) on a regular lattice. We here propose a variable-range hopping (VRH) model that is integrated in a freeware drift-diffusion solver. The mobility model is calibrated using kinetic Monte Carlo calculations and shows good agreement with the Monte Carlo calculations over the experimentally relevant part of the parameter space. The model is applied to temperature-dependent space-charge-limited current (SCLC) measurements of different systems. In contrast to the eGDM, the VRH model provides a consistent description of both p- and n-type devices. We find a critical ratio of a(NN)/alpha (mean intersite distance:localization radius) of about three, below which hopping to non-nearest neighbors becomes important around room temperature and the eGDM cannot be used for parameter extraction. Typical (Gaussian) disorder values in the range 45-120 meV are found, without any clear correlation with photovoltaic performance, when the same active layer is used in an organic solar cell.
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8. |
- Wilken, Sebastian, et al.
(author)
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How to Reduce Charge Recombination in Organic Solar Cells: There are Still Lessons to Learn from P3HT:PCBM
- 2021
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In: Advanced Electronic Materials. - : Wiley. - 2199-160X .- 2199-160X. ; 7:5
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Journal article (peer-reviewed)abstract
- Suppressing charge recombination is key for organic solar cells to become commercial reality. However, there is still no conclusive picture of how recombination losses are influenced by the complex nanoscale morphology. Here, new insight is provided by revisiting the P3HT:PCBM blend, which is still one of the best performers regarding reduced recombination. By changing small details in the annealing procedure, two model morphologies are prepared that vary in phase separation, molecular order, and phase purity, as revealed by electron tomography and optical spectroscopy. Both systems behave very similarly with respect to charge generation and transport, but differ significantly in bimolecular recombination. Only the system containing P3HT aggregates of high crystalline quality and purity is found to achieve exceptionally low recombination rates. The high-quality aggregates support charge delocalization, which assists the re-dissociation of interfacial charge-transfer states formed upon the encounter of free carriers. For devices with the optimized morphology, an exceptional long hole diffusion length is found, which allows them to work as Shockley-type solar cells even in thick junctions of 300 nm. In contrast, the encounter rate and the size of the phase-separated domains appear to be less important.
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9. |
- Xu, Kai, et al.
(author)
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On the Origin of Seebeck Coefficient Inversion in Highly Doped Conducting Polymers
- 2022
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In: Advanced Functional Materials. - : Wiley-V C H Verlag GMBH. - 1616-301X .- 1616-3028. ; 32:20
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Journal article (peer-reviewed)abstract
- A common way of determining the majority charge carriers of pristine and doped semiconducting polymers is to measure the sign of the Seebeck coefficient. However, a polarity change of the Seebeck coefficient has recently been observed to occur in highly doped polymers. Here, it is shown that the Seebeck coefficient inversion is the result of the density of states filling and opening of a hard Coulomb gap around the Fermi energy at high doping levels. Electrochemical n-doping is used to induce high carrier density (>1 charge/monomer) in the model system poly(benzimidazobenzophenanthroline) (BBL). By combining conductivity and Seebeck coefficient measurements with in situ electron paramagnetic resonance, UV-vis-NIR, Raman spectroelectrochemistry, density functional theory calculations, and kinetic Monte Carlo simulations, the formation of multiply charged species and the opening of a hard Coulomb gap in the density of states, which is responsible for the Seebeck coefficient inversion and drop in electrical conductivity, are uncovered. The findings provide a simple picture that clarifies the roles of energetic disorder and Coulomb interactions in highly doped polymers and have implications for the molecular design of next-generation conjugated polymers.
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10. |
- Yu, Liyang, 1986, et al.
(author)
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Sequential doping of solid chunks of a conjugated polymer for body-heat-powered thermoelectric modules
- 2021
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In: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 119:18
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Journal article (peer-reviewed)abstract
- Sequential doping of 1 mm3 sized cubes of regio-regular poly(3-hexylthiophene) (P3HT) with 2,3,5,6-tetrafluoro-tetracyanoquinodimethane is found to result in a doping gradient. The dopant ingresses into the solid material and after two weeks of sequential doping yields a 250 μm thick doped surface layer, while the interior of the cubes remains undoped. The doping gradient is mapped with energy dispersive x-ray spectroscopy (EDX), which is used to estimate a diffusion coefficient of 1 × 10-10 cm2 s-1 at room temperature. The cubes, prepared by pressing at 150 °C, feature alignment of polymer chains along the flow direction, which yields an electrical conductivity of 2.2 S cm-1 in the same direction. A 4-leg thermoelectric module was fabricated with slabs of pressed and doped P3HT, which generated a power of 0.22 μW for a temperature gradient of 10.2 °C generated by body heat.
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