| 1. |
- Patil, Sayali Ashok, et al.
(author)
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2D Zinc Oxide - Synthesis, Methodologies, Reaction Mechanism, and Applications
- 2023
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In: Small. - : WILEY-V C H VERLAG GMBH. - 1613-6810 .- 1613-6829. ; 19:14
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Research review (peer-reviewed)abstract
- Zinc oxide (ZnO) is a thermally stable n-type semiconducting material. ZnO 2D nanosheets have mainly gained substantial attention due to their unique properties, such as direct bandgap and strong excitonic binding energy at room temperature. These are widely utilized in piezotronics, energy storage, photodetectors, light-emitting diodes, solar cells, gas sensors, and photocatalysis. Notably, the chemical properties and performances of ZnO nanosheets largely depend on the nano-structuring that can be regulated and controlled through modulating synthetic strategies. Two synthetic approaches, top-down and bottom-up, are mainly employed for preparing ZnO 2D nanomaterials. However, owing to better results in producing defect-free nanostructures, homogenous chemical composition, etc., the bottom-up approach is extensively used compared to the top-down method for preparing ZnO 2D nanosheets. This review presents a comprehensive study on designing and developing 2D ZnO nanomaterials, followed by accenting its potential applications. To begin with, various synthetic strategies and attributes of ZnO 2D nanosheets are discussed, followed by focusing on methodologies and reaction mechanisms. Then, their deliberation toward batteries, supercapacitors, electronics/optoelectronics, photocatalysis, sensing, and piezoelectronic platforms are further discussed. Finally, the challenges and future opportunities are featured based on its current development.
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| 2. |
- Bala, Manju, et al.
(author)
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Gentamicin in vitro activity and tentative gentamicin interpretation criteria for the CLSI and calibrated dichotomous sensitivity disc diffusion methods for Neisseria gonorrhoeae
- 2016
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In: Journal of Antimicrobial Chemotherapy. - Oxford, United Kingdom : Oxford University Press. - 0305-7453 .- 1460-2091. ; 71:7, s. 1856-1859
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Journal article (peer-reviewed)abstract
- Objectives: XDR Neisseria gonorrhoeae imposes the threat of untreatable gonorrhoea. Gentamicin is considered for future treatment; however, no interpretation criteria for the CLSI and calibrated dichotomous sensitivity (CDS) disc diffusion (DD) techniques are available for N. gonorrhoeae. We investigated the in vitro gentamicin activity by MIC and DD methods, proposed DD breakpoints and determined DD ranges for 10 international quality control (QC) strains.Methods: Gentamicin susceptibility of 333 N. gonorrhoeae isolates, including 323 clinical isolates and 10 QC strains, was determined. MIC determination (Etest) and DD methods (CLSI and CDS) were performed. The relationship between MIC, inhibition zone diameter and annular radius was determined by linear regression analysis and the correlation coefficient (r) was calculated.Results: Gentamicin MICs for the QC strains were within published ranges. Of the 323 clinical isolates, according to published breakpoints 75.9%, 23.5% and 0.6% were susceptible, intermediately susceptible and resistant, respectively. Based on error minimization with MICs of ≤4, 8-16 and ≥32 mg/L, breakpoints proposed are susceptible ≥16 mm, intermediately susceptible 13-15 mm and resistant ≤12 mm for the CLSI method and susceptible ≥6 mm, less susceptible 3-5 mm and resistant ≤2 mm for the CDS technique.Conclusions: Low resistance to gentamicin was identified and gentamicin might be a future treatment option for gonorrhoea. Tentative gentamicin zone breakpoints were defined for two DD methods and QC ranges for 10 international reference strains were established. Our findings suggest that in resource-poor settings where MIC testing is not a feasible option, the DD methods can be used to indicate gentamicin resistance.
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| 3. |
- Bhambri, Aksheev, et al.
(author)
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Large scale changes in the transcriptome of Eisenia fetida during regeneration
- 2018
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In: PLOS ONE. - : Public Library of Science (PLoS). - 1932-6203. ; 13:9
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Journal article (peer-reviewed)abstract
- Earthworms show a wide spectrum of regenerative potential with certain species like Eisenia fetida capable of regenerating more than two-thirds of their body while other closely related species, such as Paranais litoralis seem to have lost this ability. Earthworms belong to the phylum Annelida, in which the genomes of the marine oligochaete Capitella telata and the freshwater leech Helobdella robusta have been sequenced and studied. Herein, we report the transcriptomic changes in Eisenia fetida (Indian isolate) during regeneration. Following injury, E. fetida regenerates the posterior segments in a time spanning several weeks. We analyzed gene expression changes both in the newly regenerating cells and in the adjacent tissue, at early (15days post amputation), intermediate (20days post amputation) and late (30 days post amputation) by RNAseq based de novo assembly and comparison of transcriptomes. We also generated a draft genome sequence of this terrestrial red worm using short reads and mate-pair reads. An in-depth analysis of the miRNome of the worm showed that many miRNA gene families have undergone extensive duplications. Sox4, a master regulator of TGF-beta mediated epithelial-mesenchymal transition was induced in the newly regenerated tissue. Genes for several proteins such as sialidases and neurotrophins were identified amongst the differentially expressed transcripts. The regeneration of the ventral nerve cord was also accompanied by the induction of nerve growth factor and neurofilament genes. We identified 315 novel differentially expressed transcripts in the transcriptome, that have no homolog in any other species. Surprisingly, 82% of these novel differentially expressed transcripts showed poor potential for coding proteins, suggesting that novel ncRNAs may play a critical role in regeneration of earthworm.
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| 4. |
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| 5. |
- Minelli, Caterina, et al.
(author)
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Versailles project on advanced materials and standards (VAMAS) interlaboratory study on measuring the number concentration of colloidal gold nanoparticles
- 2022
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In: Nanoscale. - : Royal Society of Chemistry (RSC). - 2040-3372 .- 2040-3364. ; 14, s. 4690-4704
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Journal article (peer-reviewed)abstract
- We describe the outcome of a large international interlaboratory study of the measurement of particle number concentration of colloidal nanoparticles, project 10 of the technical working area 34, "Nanoparticle Populations" of the Versailles Project on Advanced Materials and Standards (VAMAS). A total of 50 laboratories delivered results for the number concentration of 30 nm gold colloidal nanoparticles measured using particle tracking analysis (PTA), single particle inductively coupled plasma mass spectrometry (spICP-MS), ultraviolet-visible (UV-Vis) light spectroscopy, centrifugal liquid sedimentation (CLS) and small angle X-ray scattering (SAXS). The study provides quantitative data to evaluate the repeatability of these methods and their reproducibility in the measurement of number concentration of model nanoparticle systems following a common measurement protocol. We find that the population-averaging methods of SAXS, CLS and UV-Vis have high measurement repeatability and reproducibility, with between-labs variability of 2.6%, 11% and 1.4% respectively. However, results may be significantly biased for reasons including inaccurate material properties whose values are used to compute the number concentration. Particle-counting method results are less reproducibile than population-averaging methods, with measured between-labs variability of 68% and 46% for PTA and spICP-MS respectively. This study provides the stakeholder community with important comparative data to underpin measurement reproducibility and method validation for number concentration of nanoparticles.
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| 6. |
- Peng, Shen, et al.
(author)
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Chance-constrained games with mixture distributions
- 2021
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In: Mathematical Methods of Operations Research. - : Springer Nature. - 1432-2994 .- 1432-5217. ; 94:1, s. 71-97
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Journal article (peer-reviewed)abstract
- In this paper, we consider an n-player non-cooperative game where the random payoff function of each player is defined by its expected value and her strategy set is defined by a joint chance constraint. The random constraint vectors are independent. We consider the case when the probability distribution of each random constraint vector belongs to a subset of elliptical distributions as well as the case when it is a finite mixture of the probability distributions from the subset. We propose a convex reformulation of the joint chance constraint of each player and derive the bounds for players’ confidence levels and the weights used in the mixture distributions. Under mild conditions on the players’ payoff functions, we show that there exists a Nash equilibrium of the game when the players’ confidence levels and the weights used in the mixture distributions are within the derived bounds. As an application of these games, we consider the competition between two investment firms on the same set of portfolios. We use a best response algorithm to compute the Nash equilibria of the randomly generated games of different sizes.
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| 7. |
- Peng, Shen, et al.
(author)
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Games with distributionally robust joint chance constraints
- 2021
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In: Optimization Letters. - : Springer Nature. - 1862-4472 .- 1862-4480.
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Journal article (peer-reviewed)abstract
- This paper studies an n-player non-cooperative game where each player has expected-value payoff function and chance-constrained strategy set. We consider the case where the row vectors defining the constraints are independent random vectors whose probability distributions are not completely known and belong to a certain distributional uncertainty set. The chance-constrained strategy sets are defined using a distributionally robust framework. We consider one density based uncertainty set and four two-moments based uncertainty sets. One of the considered uncertainty sets is based on a nonnegative support. Under the standard assumptions on the players’ payoff functions, we show that there exists a Nash equilibrium of a distributionally robust chance-constrained game for each uncertainty set. As an application, we study Cournot competition in electricity market and perform the numerical experiments for the case of two electricity firms.
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| 8. |
- Raghuwanshi, Vikram Singh, et al.
(author)
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Deuterated Bacterial Cellulose Dissolution in Ionic Liquids
- 2021
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In: Macromolecules. - : American Chemical Society (ACS). - 0024-9297 .- 1520-5835. ; 54:14, s. 6982-6989
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Journal article (peer-reviewed)abstract
- Understanding the dissolution mechanism of deuterated bacterial cellulose (DBC) is important to engineer advanced material applications such as in quantifying and visualizing biomolecules at the cellulose interface for diagnostics. Small-angle neutron scattering (SANS) is applied to evaluate the distribution and volume fraction of dissolved DBC chains in 1-ethyl-3-methylimidazolium acetate (EMIM-Ac) ionic liquid (IL-h) solvent in three different ways: (i) DBC in IL-h, (ii) DBC in a mixture of N,N-dimethylformamide (DMF) with IL-h (IL-h/DMF), and (iii) modified DBC by dissolution in IL-h with dichloromethane (DCM), (DCM-DBC). EMIM-Ac is a highly viscous solvent, and the incorporation of DMF reduces its viscosity. DCM incorporation into EMIM-Ac leads to partial acetylation of the cellulose chains. The DBC dissolves differently in all the modified solvents studied. The DBC and DCM-DBC dissolution in IL-h shows the presence of surface fractals (power law relation of intensity to a scattering vector, q, of q-3.4) indicating compact aggregated DBC structures. The DBC structure is more open in the DMF/IL-h solvent, which is reflected in the SANS curve mass fractal analysis with a power law of q-2.5. At intermediate values of the scattering vector, a q-1 power law is observed, indicative of rigid segments of dissolved DBC chains. Analysis of the intensity in this range provides insights as to the dissolution mechanism. The observed higher intensity measured in the solutions of DBC and DCM-DBC in IL-h can be attributed to the tight binding adsorption of the acetate ions on the DBC surface. Moreover, the unique aspect of this experiment, using deuterated cellulose in a mixture of deuterated DMF with protiated EMINM-Ac, provides direct proof for formation of a shell layer of IL-h surrounding the DBC surface. The results obtained shed light on the dissolution mechanism of cellulose in EMIM-Ac, highlighting its potential application in engineering biosensors and bio-diagnostics.
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| 9. |
- Singh, Saket Vikram, et al.
(author)
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Quality of Experience of 360-degree Videos Played in Google Cardboard Devices
- 2020
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In: PROCEEDINGS OF THE 17TH INTERNATIONAL JOINT CONFERENCE ON E-BUSINESS AND TELECOMMUNICATIONS - DCNET, OPTICS, SIGMAP AND WINSYS (ICETE), VOL 2. - : SCITEPRESS. - 9789897584459 ; , s. 115-122
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Conference paper (peer-reviewed)abstract
- Google Cardboard boxes provide a cost-efficient way to introduce users to Virtual Reality (VR) applications. These devices are suitable to be utilized for entertainment, gaming, and online studies. The 360-degree videos also known as immersive videos, play panoramic view in a video. The videos are played with a mobile phone mounted on a cardboard box and are viewed by wearing or holding the cardboard box. This paper studies the QoE of users (N=60) with QoE features user comfort, presence, and interactivity with panoramic video, based on QoE factors such as lens quality, weight and handling properties of the device. The experimental data is analysed in terms of statistical properties such as Mean Opinion Scores (MOS) including confidence intervals, as well as Percents of Good or Better (%GoB) and Poor or Worse (%PoW). Furthermore, the correlations between user ratings with respect to different groups of QoE features are investigated. Overall, the paper shows cardboard boxes to yield good-to-fair QoE for viewing panoramic videos.
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| 10. |
- Singh, Vikram, et al.
(author)
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A Study on the Effect of Elevated Coolant Temperatures on HD Engines
- 2017
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In: SAE Technical Papers. - 400 Commonwealth Drive, Warrendale, PA, United States : SAE International. - 0148-7191. ; 2017-October
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Journal article (peer-reviewed)abstract
- In recent years, stricter regulations on emissions and higher demands for more fuel efficient vehicles have led to a greater focus on increasing the efficiency of the internal combustion engine. Nowadays, there is increasing interest in the recovery of waste heat from different engine sources such as the coolant and exhaust gases using, for example, a Rankine cycle. In diesel engines 15% to 30% of the energy from the fuel can be lost to the coolant and hence, does not contribute to producing work on the piston. This paper looks at reducing the heat losses to the coolant by increasing coolant temperatures within a single cylinder Scania D13 engine and studying the effects of this on the energy balance within the engine as well as the combustion characteristics. To do this, a GT Power model was first validated against experimental data from the engine. Using a Water-PEG mixture as coolant, the coolant temperature was then varied from 60°C to 200°C for both the liner and the cylinderhead. This sweep was done for multiple combinations of engine loads and speeds as well as for different air-fuel ratios. It was found that at the higher air-fuel ratios, an increase in coolant temperature led to an increase in indicated efficiency as well as an increase in exhaust gas temperature and enthalpy. However at lower air-fuel ratios there is a decrease in indicated efficiency with higher coolant temperatures. It was also seen that ignition delay at higher temperatures was shorter with the combustion duration being longer. The change in combustion phasing was found to be dependent on engine load. While the higher coolant temperature simplifies heat recovery from the coolant itself, the consequently higher exhaust gas temperatures observed means that the heat losses are moved more towards the exhaust where energy recovery is easier.
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