| 1. |
- Ekman, Simon, et al.
(author)
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Synthesis, Characterization, and Adsorption Properties of Nitrogen-Doped Nanoporous Biochar : Efficient Removal of Reactive Orange 16 Dye and Colorful Effluents
- 2023
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In: Nanomaterials. - : MDPI. - 2079-4991. ; 13:14
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Journal article (peer-reviewed)abstract
- In this work, nitrogen-doped porous biochars were synthesized from spruce bark waste using a facile single-step synthesis process, with H3PO4 as the chemical activator. The effect of nitrogen doping on the carbon material’s physicochemical properties and adsorption ability to adsorb the Reactive Orange 16 dye and treat synthetic effluents containing dyes were evaluated. N doping did not cause an important impact on the specific surface area values, but it did cause an increase in the microporosity (from 19% to 54% of micropores). The effect of the pH showed that the RO-16 reached its highest removal level in acidic conditions. The kinetic and equilibrium data were best fitted by the Elovich and Redlich–Peterson models, respectively. The adsorption capacities of the non-doped and doped carbon materials were 100.6 and 173.9 mg g−1, respectively. Since the biochars are highly porous, pore filling was the main adsorption mechanism, but other mechanisms such as electrostatic, hydrogen bond, Lewis acid-base, and π-π between mechanisms were also involved in the removal of RO-16 using SB-N-Biochar. The adsorbent biochar materials were used to treat synthetic wastewater containing dyes and other compounds and removal efficiencies of up to 66% were obtained. The regeneration tests have demonstrated that the nitrogen-doped biochar could be recycled and reused easily, maintaining very good adsorption performance even after five cycles. This work has demonstrated that N-doped biochar is easy to prepare and can be employed as an efficient adsorbent for dye removal, helping to open up new solutions for developing sustainable and effective adsorption processes to tackle water contamination.
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| 2. |
- Thivet, Simon, et al.
(author)
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Evidences of Plug Pressurization Enhancing Magma Fragmentation During the September 2016 Basaltic Eruption at Piton de la Fournaise (La Réunion Island, France)
- 2020
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In: Geochemistry, Geophysics, Geosystems. - 1525-2027. ; 21:2
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Journal article (peer-reviewed)abstract
- In September 2016, Piton de la Fournaise volcano, well known for its effusive and Hawaiian fountaining activity, produced, at the end of the eruption, an unusual phase of pulsating ash and bomb emission. Integration of geophysical data, with textural and petrological analysis of the samples, allowed us to constrain the main factors that controlled this sudden shift in activity, potentially dangerous for the tourist population that usually approach these “gentle” eruptive sites. Volcanic tremor, lava discharge rates, fountain heights, and SO2 emission changed rapidly during the eruption. Grain size and componentry of the tephra beds evolved from unimodal all along the sequence to bimodal on the last day of the activity, reflecting the contribution of both Hawaiian fountaining at the main vent (Vent A) and transient explosive activity at the second vent (Vent B). Hawaiian fountaining produced highly vesicular and almost microlite-free tephra (golden pumice and fluidal scoria) while transient explosive activity emitted denser and crystal-rich tephra (sideromelane and tachylite scoria) sometimes mingled with vesicular fragments. Permeability measurements on lapilli and bomb-sized samples reveal that golden pumice and fluidal scoria were more gas-permeable than the sideromelane and tachylite ones, while textural and chemical analyses of the ash support the hypothesis that these sideromelane and tachylite components were inherited from the subsurface crystallization of the initial golden pumice and fluidal scoria components. We thus suggest that Vent B accumulated a plug of degassed, cooled, and low-permeable magma, which modulated overpressure pulses under the late input of ascending magma.
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| 3. |
- Thivet, Simon, et al.
(author)
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Multi-Parametric Field Experiment Links Explosive Activity and Persistent Degassing at Stromboli
- 2021
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In: Frontiers in Earth Science. - : Frontiers Media S.A.. - 2296-6463. ; 9
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Journal article (peer-reviewed)abstract
- Visually unattainable magmatic processes in volcanic conduits, such as degassing, are closely linked to eruptive styles at the surface, but their roles are not completely identified and understood. To gain insights, a multi-parametric experiment at Stromboli volcano (Aeolian Islands, Italy) was installed in July 2016 focusing on the normal explosive activity and persistent degassing. During this experiment, gas-dominated (type 0) and particle-loaded (type 1) explosions, already defined by other studies, were clearly identified. A FLIR thermal camera, an Ultra-Violet SO2 camera and a scanning Differential Optical Absorption Spectroscopy were deployed to record pyroclast and SO2 masses emitted during individual explosions, as well as persistent SO2 fluxes, respectively. An ASHER instrument was also deployed in order to collect ash fallouts and to measure the grain size distribution of the samples. SO2 measurements confirm that persistent degassing was far greater than that emitted during the explosions. Further, we found that the data could be characterized by two periods. In the first period (25-27 July), activity was mainly characterized by type 0 explosions, characterized by high velocity jets. Pyroclast mass fluxes were relatively low (280 kg/event on average), while persistent SO2 fluxes were high (274 t/d on average). In the second period (29-30 July), activity was mainly characterized by type 1 explosions, characterized by low velocity jets. Pyroclast mass fluxes were almost ten times higher (2,400 kg/event on average), while persistent gas fluxes were significantly lower (82 t/d on average). Ash characterization also indicates that type 0 explosions fragments were characterized by a larger proportion of non-juvenile material compared to type 1 explosions fragments. This week-long field experiment suggests that, at least within short time periods, Stromboli's type 1 explosions can be associated with low levels of degassing and the mass of particles accompanying such explosive events depends on the volume of a degassed magma cap sitting at the head of the magma column. This could make the classic particle-loaded explosions of Stromboli an aside from the true eruptive state of the volcano. Instead, gas-dominated explosions can be associated with high levels of degassing and are indicative of a highly charged (with gas) system. We thus suggest that relatively deep magmatic processes, such as persistent degassing and slug formation can rapidly influence the superficial behavior of the eruptive conduit, modulating the presence or absence of degassed magma at the explosion/fragmentation level.
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