| 1. |
- Warthegau, Stefan S., et al.
(author)
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Heterocyclic [9]Helicenes Exhibiting Bright Circularly Polarized Luminescence
- 2023
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In: Chemistry - A European Journal. - : Wiley. - 0947-6539 .- 1521-3765. ; 29:58
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Journal article (peer-reviewed)abstract
- We describe a concise synthetic strategy for the preparation of heterocyclic [9]helicenes and a simple preparative-scale protocol for the optical resolution of the resulting M- and P-enantiomers. The helicenes were characterized by single-crystal X-ray diffraction along with a range of spectroscopic and computational techniques. A fluorescence quantum yield of up to 65 % was observed, and the chiroptical properties of both M- and P-helicenes revealed large dissymmetry factors. The circularly polarized luminescence brightness reaches up to 17 M−1 cm−1, as measured experimentally and verified computationally, which makes this the highest circularly polarized luminescence brightness among heterocyclic helicenes. We describe how chiroptical properties (both circular dichroism and circularly polarized luminescence) can be described and predicted using quantum chemical calculations. The synthetic approach also reveals by-products that originate from internal oxidation reactions, presumably mediated by the close proximity of the π-surfaces in the helicene structure.
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| 2. |
- Farnocchia, Davide, et al.
(author)
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The Second International Asteroid Warning Network Timing Campaign: 2005 LW3
- 2023
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In: The Planetary Science Journal. - : Institute of Physics (IOP). - 2632-3338. ; 4:11
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Journal article (peer-reviewed)abstract
- The Earth close approach of near-Earth asteroid 2005 LW3 on 2022 November 23 represented a good opportunity for a second observing campaign to test the timing accuracy of astrometric observation. With 82 participating stations, the International Asteroid Warning Network collected 1046 observations of 2005 LW3 around the time of the close approach. Compared to the previous timing campaign targeting 2019 XS, some individual observers were able to significantly improve the accuracy of their reported observation times. In particular, U.S. surveys achieved good timing performance. However, no broad, systematic improvement was achieved compared to the previous campaign, with an overall negative bias persisting among the different observers. The calibration of observing times and the mitigation of timing errors should be important future considerations for observers and orbit computers, respectively.
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| 3. |
- Geem, Jooyeon, et al.
(author)
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Spectral type and geometric albedo of (98943) 2001 CC21, the Hayabusa2# mission target
- 2023
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In: Monthly Notices of the Royal Astronomical Society: Letters. - : Oxford University Press. - 1745-3925 .- 1745-3933. ; 525:1, s. L17-L21
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Journal article (peer-reviewed)abstract
- We conducted optical polarimetry and near-infrared spectroscopy of Japan Aerospace Exploration Agency (JAXA)'s Hayabusa2# mission target, (98943) 2001 CC21, in early 2023. Our new observations indicate that this asteroid has a polarimetric inversion angle of ∼20°, absorption bands around 0.9 and 1.9 μm, and a geometric albedo of 0.23 ± 0.04. All these features are consistent with those of S types but inconsistent with L types. Based on this evidence, we conclude that JAXA's Hayabusa2# spacecraft will explore an S-type asteroid (more specifically, an L or LL chondrite-like object) with albedo and size (0.44-0.53 km when we assume the absolute magnitude of 18.8) similar to (25143) Itokawa.
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