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- 2019
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Tidskriftsartikel (refereegranskat)
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| 2. |
- Leebens-Mack, James H., et al.
(författare)
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One thousand plant transcriptomes and the phylogenomics of green plants
- 2019
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Ingår i: Nature. - : Nature Publishing Group. - 0028-0836 .- 1476-4687. ; 574:7780, s. 679-
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Tidskriftsartikel (refereegranskat)abstract
- Green plants (Viridiplantae) include around 450,000-500,000 species(1,2) of great diversity and have important roles in terrestrial and aquatic ecosystems. Here, as part of the One Thousand Plant Transcriptomes Initiative, we sequenced the vegetative transcriptomes of 1,124 species that span the diversity of plants in a broad sense (Archaeplastida), including green plants (Viridiplantae), glaucophytes (Glaucophyta) and red algae (Rhodophyta). Our analysis provides a robust phylogenomic framework for examining the evolution of green plants. Most inferred species relationships are well supported across multiple species tree and supermatrix analyses, but discordance among plastid and nuclear gene trees at a few important nodes highlights the complexity of plant genome evolution, including polyploidy, periods of rapid speciation, and extinction. Incomplete sorting of ancestral variation, polyploidization and massive expansions of gene families punctuate the evolutionary history of green plants. Notably, we find that large expansions of gene families preceded the origins of green plants, land plants and vascular plants, whereas whole-genome duplications are inferred to have occurred repeatedly throughout the evolution of flowering plants and ferns. The increasing availability of high-quality plant genome sequences and advances in functional genomics are enabling research on genome evolution across the green tree of life.
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| 3. |
- Xu, Weidong, 1988-, et al.
(författare)
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Rational molecular passivation for high-performance perovskite light-emitting diodes
- 2019
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Ingår i: Nature Photonics. - : Springer Nature Publishing AG. - 1749-4885 .- 1749-4893. ; 13:6, s. 418-424
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Tidskriftsartikel (refereegranskat)abstract
- A major efficiency limit for solution-processed perovskite optoelectronic devices, for example light-emitting diodes, is trap-mediated non-radiative losses. Defect passivation using organic molecules has been identified as an attractive approach to tackle this issue. However, implementation of this approach has been hindered by a lack of deep understanding of how the molecular structures influence the effectiveness of passivation. We show that the so far largely ignored hydrogen bonds play a critical role in affecting the passivation. By weakening the hydrogen bonding between the passivating functional moieties and the organic cation featuring in the perovskite, we significantly enhance the interaction with defect sites and minimize non-radiative recombination losses. Consequently, we achieve exceptionally high-performance near-infrared perovskite light-emitting diodes with a record external quantum efficiency of 21.6%. In addition, our passivated perovskite light-emitting diodes maintain a high external quantum efficiency of 20.1% and a wall-plug efficiency of 11.0% at a high current density of 200 mA cm−2, making them more attractive than the most efficient organic and quantum-dot light-emitting diodes at high excitations.
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| 4. |
- Zhang, Jianjun, et al.
(författare)
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Wavy Two-Dimensional Conjugated Metal-Organic Framework with Metallic Charge Transport
- 2023
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Ingår i: Journal of the American Chemical Society. - 0002-7863 .- 1520-5126. ; 145:43, s. 23630-23638
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Tidskriftsartikel (refereegranskat)abstract
- Two-dimensional conjugated metal–organic frameworks (2D c-MOFs) have emerged as a new class of crystalline layered conducting materials that hold significant promise for applications in electronics and spintronics. However, current 2D c-MOFs are mainly made from organic planar ligands, whereas layered 2D c-MOFs constructed by curved or twisted ligands featuring novel orbital structures and electronic states remain less developed. Herein, we report a Cu-catecholate wavy 2D c-MOF (Cu3(HFcHBC)2) based on a fluorinated core-twisted contorted hexahydroxy-hexa-cata-hexabenzocoronene (HFcHBC) ligand. We show that the resulting film is composed of rod-like single crystals with lengths up to ∼4 μm. The crystal structure is resolved by high-resolution transmission electron microscopy (HRTEM) and continuous rotation electron diffraction (cRED), indicating a wavy honeycomb lattice with AA-eclipsed stacking. Cu3(HFcHBC)2 is predicted to be metallic based on theoretical calculation, while the crystalline film sample with numerous grain boundaries apparently exhibits semiconducting behavior at the macroscopic scale, characterized by obvious thermally activated conductivity. Temperature-dependent electrical conductivity measurements on the isolated single-crystal devices indeed demonstrate the metallic nature of Cu3(HFcHBC)2, with a very weak thermally activated transport behavior and a room-temperature conductivity of 5.2 S cm–1. Furthermore, the 2D c-MOFs can be utilized as potential electrode materials for energy storage, which display decent capacity (163.3 F g–1) and excellent cyclability in an aqueous 5 M LiCl electrolyte. Our work demonstrates that wavy 2D c-MOF using contorted ligands are capable of intrinsic metallic transport, marking the emergence of new conductive MOFs for electronic and energy applications.
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| 5. |
- Jones, Benedict C, et al.
(författare)
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To which world regions does the valence-dominance model of social perception apply?
- 2021
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Ingår i: Nature Human Behaviour. - : Springer Science and Business Media LLC. - 2397-3374. ; 5:1, s. 159-169
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Tidskriftsartikel (refereegranskat)abstract
- Over the past 10 years, Oosterhof and Todorov's valence-dominance model has emerged as the most prominent account of how people evaluate faces on social dimensions. In this model, two dimensions (valence and dominance) underpin social judgements of faces. Because this model has primarily been developed and tested in Western regions, it is unclear whether these findings apply to other regions. We addressed this question by replicating Oosterhof and Todorov's methodology across 11 world regions, 41 countries and 11,570 participants. When we used Oosterhof and Todorov's original analysis strategy, the valence-dominance model generalized across regions. When we used an alternative methodology to allow for correlated dimensions, we observed much less generalization. Collectively, these results suggest that, while the valence-dominance model generalizes very well across regions when dimensions are forced to be orthogonal, regional differences are revealed when we use different extraction methods and correlate and rotate the dimension reduction solution. PROTOCOL REGISTRATION: The stage 1 protocol for this Registered Report was accepted in principle on 5 November 2018. The protocol, as accepted by the journal, can be found at https://doi.org/10.6084/m9.figshare.7611443.v1 .
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| 6. |
- Wang, Jiabin, et al.
(författare)
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A numerical investigation on the improvement of anti-snow performance of the bogies of a high-speed train
- 2020
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Ingår i: Proceedings of the Institution of Mechanical Engineers, Part F: Journal of Rail and Rapid Transit. - : SAGE Publications. - 0954-4097 .- 2041-3017. ; 234:10, s. 1319-1334
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Tidskriftsartikel (refereegranskat)abstract
- In this paper, numerical simulations combining unsteady Reynolds-averaged Navier-Stokes (URANS) simulation and the discrete phase model are used to study the application of countermeasure for snow accumulation in the regions of bogie cavities of a high-speed train. The influence of the cowcatcher heights and guide structure configurations on the flow features and snow accumulation was studied. The results of the study show that the cowcatcher with a downward elongation of 4% of the distance between the two axles decreases the snow accumulation in the first and the second bogie regions by about 56.6% and 13.6%, respectively. Furthermore, the guide structures have been found to significantly alter the velocity and pressure distribution in the second bogie region, resulting in a relatively large snow-accumulation reduction. The deflector is found to perform better in reducing snow accumulation when compared to the diversion slots. The cowcatcher, elongated in the downward direction, and the deflector proved to be a good countermeasure for snow accumulation around the bogies of high-speed trains operating in snowy weather conditions. © IMechE 2019.
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| 7. |
- Wang, Jiabin, et al.
(författare)
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An improved delayed detached eddy simulation study of the bogie cavity length effects on the aerodynamic performance of a high-speed train
- 2020
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Ingår i: Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science. - : SAGE Publications. - 2041-2983 .- 0954-4062. ; 234:12, s. 2386-2401
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Tidskriftsartikel (refereegranskat)abstract
- This paper uses an improved delayed detached eddy simulation method to investigate the unsteady flow features of the high-speed trains with various cavity lengths at Re = 1.85x10(6). The improved delayed detached eddy simulation results are validated against the experimental data obtained during previous wind tunnel tests. The effects of cavity length on the resistance force, flow structures beneath the high-speed train and in the wake are analyzed. The results show that a longer cavity significantly increases the streamwise velocity level near the rear plates and forms a stronger impinging flow on the rear plates, and thus contributes to a higher value of resistance. Furthermore, a longer cavity decreases the pressure coefficients around the near wake region from the top of the ballast to the tail nose in the vertical direction and thereby increases the pressure drag of the high-speed train. Additionally, a longer bogie cavity is found to increase the longitudinal vortex scales in the near wake region. All these changes on the flow field bring to 5.8% and 11.5% drag increase when the bogie cavities are elongated by 20% and 40%, respectively, of the wheelbase.
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| 8. |
- Wang, Jiabin, et al.
(författare)
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Impact of bogie cavity shapes and operational environment on snow accumulating on the bogies of high-speed trains
- 2018
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Ingår i: Journal of Wind Engineering and Industrial Aerodynamics. - : Elsevier BV. - 0167-6105. ; 176, s. 211-224
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Tidskriftsartikel (refereegranskat)abstract
- In this paper, the snow accumulation on the bogies of high-speed trains has been investigated using a numerical simulation method based on the unsteady Reynolds-Averaged Navier-Stokes simulations (URANS) coupled with the Discrete Phase Model (DPM). The effects of bogie cut outs’ shape, running speed of high-speed trains and snow particle density and diameter on the snow accumulation and particle movement characteristics are discussed. The results show that the bogie installation region with inclined plates shows better anti-snow performance than the configuration with straight plates, which greatly affects the flow structure and snow concentration distribution in the upper space of bogie regions. The running speed of high-speed trains has dominant effect on the snow accumulation on the bogies, and the snow accumulation issue of bogie becomes more serious with increasing running speed. Furthermore, the snow particle density and diameter also have large influence on the snow accumulation on the bogies. With the increase of snow particle density and diameter, the flow range at height direction around bogie region of snow particles become lower and the quality of snow accumulation decrease significantly.
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| 9. |
- Wang, Jiabin, et al.
(författare)
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Impact of rotation of wheels and bogie cavity shapes on snow accumulating on the bogies of high-speed trains
- 2019
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Ingår i: Cold Regions Science and Technology. - : Elsevier BV. - 0165-232X. ; 159, s. 58-70
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Tidskriftsartikel (refereegranskat)abstract
- The snow accumulation on the bogies of a high-speed train was studied using the unsteady Reynolds-Averaged Navier-Stokes simulations (URANS) coupled with the Discrete Phase Model (DPM). The effects of the rotation of wheels, shape of bogie fairings and length of bogie cavities on the flow characteristics and snow accumulation around bogie regions are discussed. The results show that the rotation of wheels significantly affects the flow characteristic and snow distribution around rear plates and the snow accumulation on the top surface of bogies. The shape of bogie fairings has been found to have large influence on the velocity profiles at the inlet and the outlet of bogie cavity, and thereby on the snow accumulation. The bogies without fairing have been found to be less influenced by the snow in the flows without crosswinds. The length of the bogie's cavity was found to have dominant role on the distribution of particle concentration and snow accumulation on the bogie surface. The total mass of snow accumulation on the bogie surface was shown to decrease with the shorter bogie cavity. Finally, the shorter bogie cavity is recommended for the design of the high-speed trains running under the circumstances permitted by the vehicle gauge.
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| 10. |
- Wang, Yan, 1987-
(författare)
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Exploring Biopolymer-Clay Nanocomposite Materials by Molecular Modelling
- 2015
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- In this thesis, bio-nanocomposites made from two alternative biopolymers and montmorillonite (Mnt) clay have been investigated by molecular modelling. These biopolymers are xyloglucan (XG) and chitosan (CHS), both of which are abundant, renewable, and cost-effective. After being reinforced by Mnt clay nanoparticles, the polymer nanocomposites gains in multifunctionality and in the possibility to register unique combinations of properties, like mechanical, biodegradable, electrical, thermal and gas barrier properties. I apply molecular dynamics (MD) simulations to study the interfacial mechanisms of the adhesion of these biopolymers to the Mnt nanoplatelets at an atomic level.For the XG-Mnt system, a strong binding affinity of XG to a fully hydrated Mnt interface was demonstrated. It was concluded that the dominant driving force for the interfacing is the enthalpy, i.e. the potential energy of the XG-Mnt interacting system. The adsorbed XG favors a flat conformation with a galactose residue in its side chain that facilitates the adsorption of the polymer to the nanoclay. The XG adsorption was found do depend strongly on the hydration ability of counterions. The binding affinity of XG to Mnt was found to be strongest in the K-Mnt/XG system, followed by, in decreasing order, Na-Mnt/XG, Li-Mnt/XG, and Ca-Mnt/XG. The competing mechanism between ions, water and the XG in the interlayer region was shown to play an important role.The dimensional stability upon moisture exposure, i.e. the ability of a material to resist swelling, is an important parameter for biopolymer-clay nanocomposites. While pure clay swells significantly even at low hydration levels, it is here shown that for the XG-Mnt system, at a hydration level below 50%, the inter-lamellar spacing is well preserved, suggesting a stable material performance. However, at higher hydration levels, the XG-Mnt composite was found to exhibit swelling at the same rate as the pure hydrated Mnt clay.For the CHS-Mnt system, the significant electrostatic interactions from the direct charge-charge attraction between the polymer and the Mnt clay play a key role in the composite formation. Varying the degree of acetylation (DA) and the degree of protonation (DPr) resulted in different effects on the polymer-clay interaction. For the heavily acetylated CHS (DA > 50%, also known as chitin), the strong adhesion of the neutral chitin to the Mnt clay was attributed to strong correlation between the acetyl functional groups and the counterions which act as an electrostatic “glue”. Similarly, the poor adhesion of the fully deprotonated (DPr = 0%) neutral CHS to the clay is attributed to a weak correlation between the amino functional group and the counterions.The stress-strain behavior of the CHS-Mnt composite shows that the mechanical properties are highly affected by the volume fraction of the Mnt clay and the degree of exfoliation of the composite. The material structure has a close relationship to the material properties.Biopolymer-clay nanocomposites hold a bright future to replace petroleum-derived polymer plastics and will become widely used in common life. The theme of the thesis is that further critical improvements of these materials can be accomplished by development of the experimental methods in conjunction with increased understanding of the interactions between polymer, clay, water, ions, solutions in the polymer-clay mixtures provided by molecular modelling.
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