| 1. |
- Li, Peng, et al.
(author)
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The effects of domain division types on the performance prediction of a rim-driven thruster
- 2023
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In: Ocean Engineering. - 0029-8018. ; 287
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Journal article (peer-reviewed)abstract
- The rim-driven thruster (RDT) is an innovative propulsion thruster. The rotating subdomain can contain different assemblies with different domain division types (DDT). This paper tried to figure out the effects of DDT on the performance of RDT. This paper uses the Delayed Detached Eddy Simulation (DDES) turbulence model to conduct the simulations. Three DDTs are carefully analyzed to understand their effects on predictive performance. The convergence analysis is performed by taking a typical method: Grid Convergence Index (GCI). Some theoretical results and the experimental hydrodynamics of a popular combination of Ka 4–70 and MARIN 19 A are used to validate the numerical method. The numerical results demonstrate that the computational efficiency is influenced by the cell number on the interfaces between two subdomains and an inherent characteristic of DDT. Moreover, the torques acting on rim surfaces are closely accounting for the gap flow. Moreover, regarding the morphology and variables of the vortex system, the third type of DDT enhances vortices presenting in the hub region and vortex-instability region. Although the present analysis is performed for an RDT, the findings should be generally applicable for other RDT designs with similar structures and operational conditions.
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| 2. |
- Shen, Nannan, et al.
(author)
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Designing Polymorphic Bi3+-Containing Ionic Liquids for Stimuli-Responsive Luminescent Materials
- 2019
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In: Inorganic Chemistry. - : American Chemical Society (ACS). - 0020-1669 .- 1520-510X. ; 58:12, s. 8079-8085
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Journal article (peer-reviewed)abstract
- Solid-state luminescent materials that possess reversible fluorescence changes toward external multistimuli are of immense interest because of their potential applications in data storage and sensors. While the recent developments in this field are mainly focused on the pi-conjugated organic molecules. Herein two polymorphic luminescent ionic liquid (IL)-based stimuli-responsive materials were designed by the supramolecular assemblies of an organic-decorated chlorobismuthate anion and a rotationally flexible imidazolium cation, namely, alpha (1)/beta (2)-[Bmmim][BiCl4(2,2'-bpy)] (Bmmim = 1-butyl-2,3-dimethylimidazolium; 2,2'-bpy = 2,2'-bipyridine). Because of the different conformations of the n-butyl chains on the imidazolium cations, tuning of the supramolecular packing structures as well as luminescent colors for 1 and 2 was realized. Single-crystal X-ray diffraction and Hirshfeld surface analyses disclose that the poly-morphism-dependent emission may be attributed to the different weak interactions, especially to the pi-pi interactions between adjacent [BiCl4(2,2'-bpy)](-) anions in two compounds. Additionally, compound 2 could be transformed into 1 spontaneously at ambient conditions, which could be triggered by the moisture in the air. Both of the title compounds could detect NH(3 )vapor selectively through the luminescence "turn-off" method rapidly and reversibly because of the destruction of intermolecular interactions, indicating their stimuli-responsive property toward NH3.
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