| 1. |
- Agnarsson, Björn, 1977, et al.
(author)
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Rutile TiO 2 thin films grown by reactive high power impulse magnetron sputtering
- 2013
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In: Thin Solid Films. - : Elsevier BV. - 0040-6090 .- 1879-2731. ; 545, s. 445-450
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Journal article (peer-reviewed)abstract
- Thin TiO 2 films were grown on Si(001) substrates by reactive dc magnetron sputtering (dcMS) and high power impulse magnetron sputtering (HiPIMS) at temperatures ranging from 300 to 700 C.Optical and structural properties of films were compared both before and after post-annealing using scanning electron microscopy, low angle X-ray reflection (XRR), grazing inc idence X-ray diffractometry and spectroscopic ellipsometry.Both dcMS- and HiPIMS-grown films reveal polycrystalline rutile TiO 2 , even prior to post-annealing.The HiPIMS-grown films exhibit significantly larger grains compared to that of dcMC-grown films, approaching 100% of the film thickness for films grown at 700 C.In addition, the XRR surface roughness of HiPIMS-grown films was significantly lower than that of dcMS-grown films over the whole temperature range 300-700 C.Dispersion curves could only be obtained for the HiPIMS-grown films, which were shown to have a refractive index in the range of 2.7-2.85 at 500 nm.The results show that thin, rutile TiO 2 films, with high refractive index, can be obtained by HiPIMS at relatively low growth temperatures, without post-annealing.Furthermore, these films are smoother and show better optical characteristics than their dcMS-grown counterparts.© 2013 Elsevier B.V.All rights reserved.
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| 2. |
- Dahlqvist, Martin, et al.
(author)
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Magnetically driven anisotropic structural changes in the atomic laminate Mn2GaC
- 2016
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In: Physical Review B. - : AMER PHYSICAL SOC. - 2469-9950 .- 2469-9969. ; 93:1
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Journal article (peer-reviewed)abstract
- Inherently layered magnetic materials, such as magnetic M(n+1)AX(n) (MAX) phases, offer an intriguing perspective for use in spintronics applications and as ideal model systems for fundamental studies of complex magnetic phenomena. The MAX phase composition M(n+1)AX(n) consists of M(n+1)AX(n) blocks separated by atomically thin A-layers where M is a transition metal, A an A-group element, X refers to carbon and/or nitrogen, and n is typically 1, 2, or 3. Here, we show that the recently discovered magnetic Mn2GaC MAX phase displays structural changes linked to the magnetic anisotropy, and a rich magnetic phase diagram which can be manipulated through temperature and magnetic field. Using first-principles calculations and Monte Carlo simulations, an essentially one-dimensional (1D) interlayer plethora of two-dimensioanl (2D) Mn-C-Mn trilayers with robust intralayer ferromagnetic spin coupling was revealed. The complex transitions between them were observed to induce magnetically driven anisotropic structural changes. The magnetic behavior as well as structural changes dependent on the temperature and applied magnetic field are explained by the large number of low energy, i.e., close to degenerate, collinear and noncollinear spin configurations that become accessible to the system with a change in volume. These results indicate that the magnetic state can be directly controlled by an applied pressure or through the introduction of stress and show promise for the use of Mn2GaC MAX phases in future magnetoelectric and magnetocaloric applications.
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| 3. |
- Frisk, Andreas, 1983-, et al.
(author)
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Tailoring anisotropy and domain structure in amorphous TbCo thin films through combinatorial methods
- 2016
-
In: Journal of Physics D. - : IOP Publishing. - 0022-3727 .- 1361-6463. ; 49:3
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Journal article (peer-reviewed)abstract
- We apply an in-plane external magnetic field during growth of amorphous TbCo thin films and examine the effects on the magnetic anisotropy and domain structure. A combinatorial approach is employed throughout the deposition and analysis to study a continuous range of compositions between 7–95 at.% Tb. Magnetometry measurements show that all samples have a strong out-of-plane anisotropy, much larger than any in-plane components, regardless of the presence of a growth field. However, magnetic force microscopy demonstrates that the growth field does indeed have a large effect on the magnetic domain structure, resulting in elongated domains aligned along the imprinting field direction. The results show that the anisotropy can be tuned in intricate ways in amorphous TbCo films giving rise to unusual domain structures. Furthermore the results reveal that a combinatorial approach is highly effective for mapping out these material properties.
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| 4. |
- George, Sebastian, 1990-
(author)
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Amorphous Magnetic Materials : A Versatile Foundation for Tomorrow’s Applications
- 2020
-
Doctoral thesis (other academic/artistic)abstract
- Amorphous magnetic materials exhibit a number of key differentiating properties with respect to crystalline magnets. In some cases, the differences may simply be in the values of macroscopic properties such as saturation magnetization, coercivity, Curie temperature, and electrical conductivity. Other cases are more fundamental, such as the possibility for many amorphous alloys to be produced with nearly arbitrary composition, something that is not always possible in crystal structures that may only be stable for certain specific compositions.Fundamentally, these properties arise due to the disordered arrangement of atoms in amorphous materials. However, this structure is challenging to probe and characterize, either experimentally or theoretically. A significant contribution of this thesis is the development of a new approach for studying the local atomic structure of amorphous materials, specifically amorphous SmCo and FeZr alloys. The strategy combines extended x-ray absorption spectroscopy (EXAFS) measurements with stochastic quenching (SQ) simulations in a way that provides more information than either method can offer alone. Additionally, this approach offers the potential for identifying any shortcomings in the theoretical models obtained via SQ.Having an accurate model of the atomic arrangement is not, however, a prerequisite for developing technical applications of amorphous magnetic materials. For that, it is sufficient to quantify those macroscopic properties that are relevant for a given application. Such is the value of the magnetic characterization of amorphous TbCo and CoFeZr alloy thin films presented here. Both investigations used methods such as vibrating sample magnetometry (VSM) and magneto-optic Kerr effect (MOKE) measurements to highlight the high tunability of the magnetic properties in these materials, which can be achieved simply by changing the chemical composition.The final portion of this thesis examines what can be achieved by combining amorphous SmCo and TbCo alloys together in bilayer structures. This is a step away from the alloy characterization studies, as it focuses on how new properties can be realized when multiple materials are brought together. MOKE measurements were used to identify the conditions under which the bilayers spontaneously become magnetized parallel to the film plane versus when the TbCo magnetization begins to tilt out of the plane. Further investigation combining x-ray circular magnetic dichroism (XMCD) measurements and micromagnetic simulations provided a depth-resolved model of the magnetization throughout the bilayers in the presence of a broad range of external field strengths and directions. These models also showed that the local magnetization just above and just below the SmCo/TbCo interface can be aligned either parallel or antiparallel to one another simply by varying the TbCo composition. This discovery offers a novel method for controlling the magnetic behavior in these materials, and may well be useful for all-optical switching or spintronics applications where amorphous TbCo alloys have already drawn attention.
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| 5. |
- George, Sebastian, 1990-, et al.
(author)
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Local structure in amorphous SmxCo1-x : a combined experimental and theoretical study
- 2020
-
In: Journal of Materials Science. - : Springer Science and Business Media LLC. - 0022-2461 .- 1573-4803. ; 55, s. 12488-12498
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Journal article (peer-reviewed)abstract
- Using a combination of extended X-ray absorption fine structure measurements, stochastic quenching (SQ) calculations and Voronoi tessellation analysis, the local atomic environments in thin films of amorphous SmxCo1−x (x= 0.10, 0.22 and 0.35) are investigated and also compared with crystalline stoichiometric Sm–Co alloys of similar compositions. It is found that the variations in local environment around Co atoms in the amorphous films increase with increasing x and that none of the films exhibit any pronounced short-range order around the Sm atoms. There are, however, signs of clustering of Sm atoms in the SQ-generated simulated amorphous materials. Furthermore, good agreement is observed between experimentally obtained parameters, e.g., interatomic distances and coordination numbers, and those extracted from the simulated alloys. This is a strong indication that SQ provides a powerful route to reliable local structure information for amorphous rare earth–transition metal alloys and that it could be used for designing materials with properties that meet the demands of specific applications.
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| 6. |
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| 7. |
- Hanifpour, Fatemeh, et al.
(author)
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Investigation into the mechanism of electrochemical nitrogen reduction reaction to ammonia using niobium oxynitride thin-film catalysts
- 2022
-
In: Electrochimica Acta. - : Elsevier. - 0013-4686 .- 1873-3859. ; 403
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Journal article (peer-reviewed)abstract
- Niobium oxynitride (NbOxNy) thin films with varying combined non-metal vs. metal stoichiometries ( x + y ) and N/O stoichiometric ratios (y/x) are investigated for their ability to catalyze the nitrogen re-duction reaction and ammonia synthesis at ambient conditions. Electrochemical impedance spectroscopy and ammonia measurements show stark differences both in nitrogen vs. argon media on each surface and on the surfaces in the series when the combined stoichiometry of N + O vs. Nb increases. Surface stability checks at fixed intervals during the experiments and surface characterization after the experiments us -ing X-ray diffraction reveal the least changes occurred to the surface with the highest N + O stoichiometry. Based on these observations, an ammonia synthesis mechanism is proposed. Isotope labeling experiments on the most promising surface of the series, however, show no sign of catalytically produced ammonia, possibly due to the lack of stability of the surface to endure through the ammonia production cycle.
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| 8. |
- Hanifpour, Fatemeh, et al.
(author)
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Operando quantification of ammonia produced from computationally-derived transition metal nitride electro-catalysts
- 2022
-
In: Journal of Catalysis. - : Elsevier. - 0021-9517 .- 1090-2694. ; 413, s. 956-967
-
Journal article (peer-reviewed)abstract
- Electrochemical reduction of dinitrogen to ammonia is investigated in a micro-reactor flow-cell using thin films of VN, CrN, NbN and ZrN. Chronoamperometry loops are used for ammonia production analysis. Operando ammonia quantification is accomplished in a flow injection analyzer. Results show the effect of presence/absence of N-2(g) within both the electrochemical characterization and ammonia production for ZrN. However, no ammonia is detected from studies on CrN. VN and NbN are inactivated upon reacting their N atoms of the surface top layer(s). Results obtained from ammonia measurements, electrochemical impedance spectroscopy analysis, surface stability checks, and surface characterization using X-ray reflectivity, reveal certain trends indicating catalytic behavior for ZrN. However, the concentration of produced ammonia is below the detection limit of the methods devised to analyze the samples from isotope labeling experiments. The onset of ammonia production on ZrN appears to be in close agreement with that predicted previously by computational studies.
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| 9. |
- Ingason, Arni Sigurdur, et al.
(author)
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Magnetic Self-Organized Atomic Laminate from First Principles and Thin Film Synthesis
- 2013
-
In: Physical Review Letters. - : American Physical Society. - 0031-9007 .- 1079-7114. ; 110
-
Journal article (peer-reviewed)abstract
- he first experimental realization of a magnetic Mn+1AXn (MAX) phase, (Cr0.75Mn0.25)2GeC, is presented, synthesized as a heteroepitaxial single crystal thin film, exhibiting excellent structural quality. This self-organized atomic laminate is based on the well-known Cr2GeC, with Mn, a new element in MAX phase research, substituting Cr. The compound was predicted using first-principles calculations, from which a variety of magnetic behavior is envisaged, depending on the Mn concentration and Cr/Mn atomic configuration within the sublattice. The analyzed thin films display a magnetic signal at room temperature.
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| 10. |
- Leosson, K., et al.
(author)
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Comparing resonant photon tunneling via cavity modes and Tamm plasmon polariton modes in metal-coated Bragg mirrors
- 2012
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In: Optics Letters. - 0146-9592 .- 1539-4794. ; 37:19, s. 4026-4028
-
Journal article (peer-reviewed)abstract
- Resonant photon tunneling was investigated experimentally in multilayer structures containing a high-contrast (TiO2/SiO2) Bragg mirror capped with a semitransparent gold film. Transmission via a fundamental cavity resonance was compared with transmission via the Tamm plasmon polariton resonance that appears at the interface between a metal film and a one-dimensional photonic bandgap structure. The Tamm-plasmon-mediated transmission exhibits a smaller dependence on the angle and polarization of the incident light for similar values of peak transmission, resonance wavelength, and finesse. Implications for transparent electrical contacts based on resonant tunneling structures are discussed.
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| 11. |
- Magnfält, Daniel
(author)
-
Nucleation and stress generation in thin films deposited with a pulsed energetic deposition flux
- 2013
-
Licentiate thesis (other academic/artistic)abstract
- This thesis presents fundamental mechanisms of nucleation and early growth of and stress generation in thin polycrystalline metal films deposited using pulsed energetic deposition fluxes. The effects of a pulsed deposition flux and energetic bombardment on film nucleation was investigated using in situ stress measurements and in situ ellipsometry to determine the film thickness at which the films become continuous. Ag films where deposited using high power impulse magnetron sputtering (HiPIMS) in two series - one with constant low pulse power to minimize energetic bombardment while varying the pulse frequency and one with a constant pulse frequency while varying the pulse power, resulting in different amounts of energetic bombardment and different deposition rates - to separate the effects of a pulsed deposition flux and energetic bombardment. The thickness at which the film becomes continuous was found to decrease both with increasing pulse frequency and increasing pulse power. The effects of the increased energetic bombardment and deposition rate cannot be separated due to their coupling. Adatom lifetimes and the coalescence times for islands where calculated for different coverages and island sizes and compared to the time between pulses. It was found that the time between pulses was lower than the adatom lifetimes for certain conditions; this leads to an increase in the adatom density and therefore an increase of the nucleation density resulting in smaller thicknesses for the formation of continuous film. It was also found that the coalescence time for clusters becomes longer than the time between pulses, retarding the coalescence process; this leads to formation of long lived elongated clusters also resulting in a decrease of the thickness at which the films become continuous.Energetic bombardment during growth of Mo films using HiPIMS is found to result in large compressive stresses without the commonly observed defect induced associated lattice expansion seen when depositing films using energetic bombardment. This and a correlation between the magnitude of the compressive stress and the film density allow us to conclude that the compressive stress is generated by grain boundary densification. Two mechanisms leading to grain boundary densification and thus generation of compressive stresses are proposed.
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| 12. |
- Magnus, Fridrik, et al.
(author)
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Current-voltage-time characteristics of the reactive Ar/N2 high power impulse magnetron sputtering discharge
- 2011
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In: Journal of Applied Physics. - : American Institute of Physics (AIP). - 0021-8979 .- 1089-7550. ; 110:8
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Journal article (peer-reviewed)abstract
- The discharge current and voltage waveforms have been measured in a reactive high power impulse magnetron sputtering (HiPIMS) Ar/N2" role="presentation">N2 discharge with a Ti target for 400 μs" role="presentation">μs long pulses. We observe that the current waveform in the reactive Ar/N2" role="presentation">N2 HiPIMS discharge is highly dependent on the pulse repetition frequency, unlike the non-reactive Ar discharge. The current is found to increase significantly as the frequency is lowered. This is attributed to an increase in the secondary electron emission yield during the self-sputtering phase, when the nitride forms on the target at low frequencies. In addition, self-sputtering runaway occurs at lower discharge voltages when nitrogen is added to the discharge. This illustrates the crucial role of self-sputtering in the behavior of the reactive HiPIMS discharge.
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| 13. |
- Magnus, Fridrik, et al.
(author)
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Current-voltage-time characteristics of the reactive Ar/O2 high power impulse magnetron sputtering discharge
- 2012
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In: Journal of Vacuum Science & Technology. A. Vacuum, Surfaces, and Films. - : American Institute of Physics (AIP). - 0734-2101 .- 1520-8559. ; 30:5
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Journal article (peer-reviewed)abstract
- The discharge current–voltage–time waveforms are studied in the reactive Ar/O2 high power impulse magnetron sputtering discharge with a titanium target for 400 μs long pulses. The discharge current waveform is highly dependent on both the pulse repetition frequency and discharge voltage and the current increases with decreasing frequency or voltage. The authors attribute this to an increase in the secondary electron emission yield during the self-sputtering phase of the pulse, as an oxide forms on the target.
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| 14. |
- Magnus, Fridrik, et al.
(author)
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Digital Smoothing of the Langmuir Probe I-V Characteristic
- 2008
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In: Review of Scientific Instruments. - : American Institute of Physics (AIP). - 0034-6748 .- 1089-7623. ; 79:7
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Journal article (peer-reviewed)abstract
- Electrostatic probes or Langmuir probes are the most common diagnostic tools in plasma discharges. The second derivative of the Langmuir probe I-V characteristic is proportional to the electron energy distribution function. Determining the second derivative accurately requires some method of noise suppression. We compare the Savitzky-Golay filter, the Gaussian filter, and polynomial fitting to the Blackman filter for digitally smoothing simulated and measured I-V characteristics. We find that the Blackman filter achieves the most smoothing with minimal distortion for noisy data.
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| 15. |
- Magnus, Fridrik, et al.
(author)
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Giant magnetic domains in amorphous SmCo thin films
- 2014
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In: Physical Review B. Condensed Matter and Materials Physics. - 1098-0121 .- 1550-235X. ; 89:22, s. 224420-1-224420-5
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Journal article (peer-reviewed)abstract
- The potential for tuning of magnetic properties and the exceptional uniformity are among the features that make amorphous magnetic materials attractive for technology. Here it is shown that the magnetization reversal in amorphous SmCo thin films takes place through the formation of giant magnetic domains, over a centimeter across. The domain structure is found to be dictated by the direction of the imprinted in-plane easy axis and the film boundaries. This is a consequence of the size of the anisotropy and the structural uniformity of the films, which also allows the movement of millimeter-long domain walls over distances of several millimeters. The results demonstrate the possibility of tailoring the magnetic domain structure in amorphous magnets over a wide range of length scales, up to centimeters. Moreover, they highlight an important consequence of the structural perfection of amorphous films.
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| 16. |
- Magnus, Fridrik, et al.
(author)
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Long-range magnetic interactions and proximity effects in an amorphous exchange-spring magnet
- 2016
-
In: Nature Communications. - : Springer Science and Business Media LLC. - 2041-1723. ; 7
-
Journal article (peer-reviewed)abstract
- Low-dimensional magnetic heterostructures are a key element of spintronics, where magnetic interactions between different materials often define the functionality of devices. Although some interlayer exchange coupling mechanisms are by now well established, the possibility of direct exchange coupling via proximity-induced magnetization through non-magnetic layers is typically ignored due to the presumed short range of such proximity effects. Here we show that magnetic order can be induced throughout a 40-nm-thick amorphous paramagnetic layer through proximity to ferromagnets, mediating both exchange-spring magnet behaviour and exchange bias. Furthermore, Monte Carlo simulations show that nearest-neighbour magnetic interactions fall short in describing the observed effects and long-range magnetic interactions are needed to capture the extent of the induced magnetization. The results highlight the importance of considering the range of interactions in low-dimensional heterostructures and how magnetic proximity effects can be used to obtain new functionality.
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| 17. |
- Magnus, Fridrik, et al.
(author)
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Magnetostrictive properties of amorphous SmCo thin films with imprinted anisotropy
- 2014
-
In: Physical Review B. Condensed Matter and Materials Physics. - 1098-0121 .- 1550-235X. ; 89:13, s. 134414-1-134414-6
-
Journal article (peer-reviewed)abstract
- We examine the magnetostriction in amorphous SmCo thin films with a composition in the range 4-27 at.% Sm. The magnetostriction increases significantly with increasing Sm content but is small compared to terbium-based ferromagnetic compounds, despite the large imprinted anisotropy. The magnetostriction and anisotropy both increase approximately linearly as the temperature is reduced. The magnetoelastic energy is found to be far smaller than the anisotropy energy so the magnetoelastic atomic displacements during growth cannot be the origin of the imprinted anisotropy. The anisotropy is only slightly altered by the application of large tensile stresses, indicating that the local strain fields involved in magnetostriction are not equivalent to the global strain produced by mechanical bending.
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| 18. |
- Magnus, Fridrik, et al.
(author)
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Nucleation and resistivity of ultrathin TiN films grown by high power impulse magnetron sputtering
- 2012
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In: IEEE Electron Device Letters. - : IEEE. - 0741-3106 .- 1558-0563. ; 33:7, s. 1045-1047
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Journal article (peer-reviewed)abstract
- TiN films have been grown on SiO 2 by reactive high-power impulse magnetron sputtering (HiPIMS) at temperatures of 22°C-600°C. The film resistance is monitored in situ to determine the coalescence and continuity thicknesses that decrease with increasing growth temperature with a minimum of 0.38 ± 0.05 nm and 1.7 ± 0.2 nm, respectively, at 400°C. We find that HiPIMS-deposited films have significantly lower resistivity than dc magnetron sputtered (dcMS) films on SiO 2 at all growth temperatures due to reduced grain boundary scattering. Thus, ultrathin continuous TiN films with superior electrical characteristics can be obtained with HiPIMS at reduced temperatures compared to dcMS.
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| 19. |
- Magnus, Fridrik, et al.
(author)
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Sequential magnetic switching in Fe/MgO(001) superlattices
- 2018
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In: Physical Review B. Condensed Matter and Materials Physics. - : American Physical Society. - 1098-0121 .- 1550-235X. ; 97:17
-
Journal article (peer-reviewed)abstract
- Polarized neutron reflectometry is used to determine the sequence of magnetic switching in interlayer exchangecoupled Fe/MgO(001) superlattices in an applied magnetic field. For 19.6 Å thick MgO layers we obtain a 90◦periodic magnetic alignment between adjacent Fe layers at remanence. In an increasing applied field the toplayer switches first followed by its second-nearest neighbor. For 16.4 Å MgO layers, a 180◦periodic alignment isobtained at remanence and with increasing applied field the layer switching starts from the two outermost layersand proceeds inwards. This sequential tuneable switching opens up the possibility of designing three-dimensionalmagnetic structures with a predefined discrete switching sequence
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| 20. |
- Magnus, Fridrik, et al.
(author)
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Tunable giant magnetic anisotropy in amorphous SmCo thin films
- 2013
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In: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 102:16, s. 162402-
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Journal article (peer-reviewed)abstract
- SmCo thin films have been grown by magnetron sputtering at room temperature with a composition of 2-35 at.% Sm. Films with 5 at.% or higher Sm are amorphous and smooth. A giant tunable uniaxial in-plane magnetic anisotropy is induced in the films which peaks in the composition range 11-22 at.% Sm. This cross-over behavior is not due to changes in the atomic moments but rather the local configuration changes. The excellent layer perfection combined with highly tunable magnetic properties make these films important for spintronics applications.
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| 21. |
- Magnus, Fridrik, et al.
(author)
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Tuneable exchange-spring stiffness in amorphous magnetic trilayer structures
- 2021
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In: Journal of Physics. - : Institute of Physics Publishing (IOPP). - 0953-8984 .- 1361-648X. ; 33:44
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Journal article (peer-reviewed)abstract
- We investigate the magnetic properties of amorphous Sm10Co90/Co-60(Al70Zr30)(40)/Co-85(Al70Zr30)(15) exchange-spring magnet trilayers. The magnetically soft Co-85(Al70Zr30)(15) layer is coupled to the magnetically hard Sm10Co90 layer through the weakly magnetic low-T (c) Co-60(Al70Zr30)(40) spacer layer. The strength of the coupling can be controlled with temperature and the coupling persists above the intrinsic T (c) of the spacer layer due to a long-range magnetic proximity effect. Polarized neutron reflectivity is used to examine the magnetic profile of the trilayers during magnetization reversal. A two-step switching occurs, with the switching angle of the soft layer strongly dependent on the strength of the coupling. In the strong coupling regime a magnetic state can be achieved where the soft layer magnetization is perpendicular to the hard layer whereas in the weak coupling regime the soft layer reverses fully.
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| 22. |
- Meshkian, Rahele, et al.
(author)
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A magnetic atomic laminate from thin film synthesis: (Mo0.5Mn0.5)2GaC
- 2015
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In: APL Materials. - : American Institute of Physics (AIP): Open Access Journals / AIP Publishing LLC. - 2166-532X. ; 3:7
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Journal article (peer-reviewed)abstract
- We present synthesis and characterization of a new magnetic atomic laminate: (Mo0.5Mn0.5)(2)GaC. High quality crystalline films were synthesized on MgO(111) substrates at a temperature of similar to 530 degrees C. The films display a magnetic response, evaluated by vibrating sample magnetometry, in a temperature range 3-300 K and in a field up to 5 T. The response ranges from ferromagnetic to paramagnetic with change in temperature, with an acquired 5T-moment and remanent moment at 3 K of 0.66 and 0.35 mu(B) per metal atom (Mo and Mn), respectively. The remanent moment and the coercive field (0.06 T) exceed all values reported to date for the family of magnetic laminates based on so called MAX phases.
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| 23. |
- Meshkian, Rahele, et al.
(author)
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Theoretical stability, thin film synthesis and transport properties of the Mon+1GaCn MAX phase
- 2015
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In: Physica Status Solidi. Rapid Research Letters. - : Wiley. - 1862-6254 .- 1862-6270. ; 9:3, s. 197-201
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Journal article (peer-reviewed)abstract
- The phase stability of Mon +1GaCn has been investigated using ab-initio calculations. The results indicate stability for the Mo2GaC phase only, with a formation enthalpy of 0.4 meV per atom. Subsequent thin film synthesis of Mo2GaC was performed through magnetron sputtering from elemental targets onto Al2O3 [0001], 6H-SiC [0001] and MgO [111] substrates within the temperature range of 500 degrees C and 750 degrees C. High structural quality films were obtained for synthesis on MgO [111] substrates at 590 degrees C. Evaluation of transport properties showed a superconducting behavior with a critical temperature of approximately 7 K, reducing upon the application of an external magnetic field. The results point towards the first superconducting MAX phase in thin film form.
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| 24. |
- Mockuté, Aurelija, et al.
(author)
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Structural and magnetic properties of (Cr1-xMnx)(5)Al-8 solid solution and structural relation to hexagonal nanolaminates
- 2014
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In: Journal of Materials Science. - : Springer Verlag (Germany). - 0022-2461 .- 1573-4803. ; 49:20, s. 7099-7104
-
Journal article (peer-reviewed)abstract
- Electron microscopy is used to reveal the competitive epitaxial growth of bcc structure (Cr1-x Mn (x) )(5)Al-8 and (Cr1-y Mn (y) )(2)AlC [M (n+1)AX (n) (MAX)] phase during both magnetron sputtering and arc deposition. X-ray diffraction theta-2 theta measurements display identical peak positions of (000n)-oriented MAX phase and (Cr1-x Mn (x) )(5)Al-8, due to the interplanar spacing of (Cr1-x Mn (x) )(5)Al-8 that matches exactly half a unit cell of (Cr1-y Mn (y) )(2)AlC. Vibrating sample magnetometry shows that a thin film exclusively consisting of (Cr1-x Mn (x) )(5)Al-8 exhibits a magnetic response, implying that the potential presence of this phase needs to be taken into consideration when evaluating the magnetic properties of (Cr, Mn)(2)AlC.
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| 25. |
- Mockuté, Aurelija, et al.
(author)
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Synthesis and characterization of arc deposited magnetic (Cr,Mn)(2)AlC MAX phase films
- 2014
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In: Physica Status Solidi. Rapid Research Letters. - : Wiley. - 1862-6254 .- 1862-6270. ; 8:5, s. 420-423
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Journal article (peer-reviewed)abstract
- (Cr1-xMnx)(2)AlC MAX phase thin films were synthesized by cathodic arc deposition. Scanning transmission electron microscopy including local energy dispersive X-ray spectroscopy analysis of the as-deposited films reveals a Mn incorporation of as much as 10 at% in the structure, corresponding to x = 0.2. Magnetic properties were characterized with vibrating sample magnetometry, revealing a magnetic response up to at least room temperature. We thus verify previous theoretical predictions of an antiferromagnetic or ferromagnetic ground state for Cr2AlC upon alloying with Mn. ((c) 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)
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