1. |
- Kurmaev, E. Z., et al.
(author)
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Spectroscopic observation of polaron-lattice band structure in the conducting polymer polyaniline
- 2001
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In: Journal of Physics. - : IOP Publishing. - 0953-8984 .- 1361-648X. ; 13:17, s. 3907-3912
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Journal article (peer-reviewed)abstract
- We present the results of soft x-ray emission measurements for undoped and protonated polyemeraldine. We show that the polaron-lattice band structure fully accounts for the observed x-ray transitions. A finite spectral intensity of C Kα and N Kα XES is observed at the Fermi level for protonated polyemeraldine, supporting the applicability of the polaronic-metal model for highly conducting polymers.
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2. |
- Ji, Fuxiang, 1991-, et al.
(author)
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Remarkable Thermochromism in the Double Perovskite Cs2NaFeCl6
- 2023
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In: Advanced Optical Materials. - : Wiley-Blackwell. - 2162-7568 .- 2195-1071.
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Journal article (peer-reviewed)abstract
- Lead-free halide double perovskites (HDPs) have emerged as a new generation of thermochromic materials. However, further materials development and mechanistic understanding are required. Here, a highly stable HDP Cs2NaFeCl6 single crystal is synthesized, and its remarkable and fully reversible thermochromism with a wide color variation from light-yellow to black over a temperature range of 10 to 423 K is investigated. First-principles, density functional theory (DFT)-based calculations indicate that the thermochromism in Cs2NaFeCl6 is an effect of electron–phonon coupling. The temperature sensitivity of the bandgap in Cs2NaFeCl6 is up to 2.52 meVK−1 based on the Varshni equation, which is significantly higher than that of lead halide perovskites and many conventional group-IV, III–V semiconductors. Meanwhile, this material shows excellent environmental, thermal, and thermochromic cycle stability. This work provides valuable insights into HDPs' thermochromism and sheds new light on developing efficient thermochromic materials.
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3. |
- Ji, Fuxiang, 1991-, et al.
(author)
-
Remarkable Thermochromism in the Double Perovskite Cs2NaFeCl6
- 2024
-
In: Advanced Optical Materials. - : John Wiley & Sons. - 2162-7568 .- 2195-1071. ; 12:8
-
Journal article (peer-reviewed)abstract
- Lead-free halide double perovskites (HDPs) have emerged as a new generation of thermochromic materials. However, further materials development and mechanistic understanding are required. Here, a highly stable HDP Cs2NaFeCl6 single crystal is synthesized, and its remarkable and fully reversible thermochromism with a wide color variation from light-yellow to black over a temperature range of 10 to 423 K is investigated. First-principles, density functional theory (DFT)-based calculations indicate that the thermochromism in Cs2NaFeCl6 is an effect of electron-phonon coupling. The temperature sensitivity of the bandgap in Cs2NaFeCl6 is up to 2.52 meVK(-1) based on the Varshni equation, which is significantly higher than that of lead halide perovskites and many conventional group-IV, III-V semiconductors. Meanwhile, this material shows excellent environmental, thermal, and thermochromic cycle stability. This work provides valuable insights into HDPs' thermochromism and sheds new light on developing efficient thermochromic materials.
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4. |
- Magnuson, Martin, 1965-, et al.
(author)
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Interface bonding of Zr1−xAlxN nanocomposites investigated by x-ray spectroscopies and first principles calculations
- 2020
-
In: Physical Review Research. - College Park, MD, United States : American Physical Society. - 2643-1564. ; 2:1
-
Journal article (peer-reviewed)abstract
- The electronic structure, chemical bonding, and interface component in ZrN-AlN nanocomposites formed byphase separation during thin film deposition of metastable Zr1−xAlxN (x = 0.0, 0.12, 0.26, 0.40) are investigatedby resonant inelastic x-ray scattering, x-ray emission, and x-ray absorption spectroscopy and compared to firstprinciples calculations including transitions between orbital angular momentum final states. The experimentalspectra are compared with different interface-slab model systems using first principles all-electron full-potentialcalculations where the core states are treated fully relativistically. As shown in this work, the bulk sensitivity andelement selectivity of x-ray spectroscopy enables one to probe the symmetry and orbital directions at interfacesbetween cubic and hexagonal crystals. We show how the electronic structure develops from local octahedralbond symmetry of cubic ZrN that distorts for increasing Al content into more complex bonding. This results inthree different kinds of bonding originating from semicoherent interfaces with segregated ZrN and lamellar AlNnanocrystalline precipitates. An increasing chemical shift and charge transfer between the elements takes placewith increasing Al content and affects the bond strength and increases resistivity.
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5. |
- Rogström, Lina, 1983-, et al.
(author)
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Structural changes in Ti1-xAlxN coatings during turning : A XANES and EXAFS study of worn tools
- 2023
-
In: Applied Surface Science. - : Elsevier. - 0169-4332 .- 1873-5584. ; 612
-
Journal article (peer-reviewed)abstract
- Structural changes in Ti1-xAlxN coated tool inserts used for turning in 316L stainless steel were investigated by XANES, EXAFS, EDS, and STEM. For coarse-grained fcc-structured Ti1-xAlxN coatings, with 0 ≤ x ≤ 0.62, the XANES spectrum changes with Al-content. XANES Ti 1s line-scans across the rake face of the worn samples reveals that TiN-enriched domains have formed during turning in Ti0.47Al0.53N and Ti0.38Al0.62N samples as a result of spinodal decomposition. The XANES spectra reveal the locations on the tool in which the most TiN-rich domains have formed, indicating which part of the tool-chip contact area that experienced the highest temperature during turning. Changes in the pre-edge features in the XANES spectra reveal that structural changes occur also in the w-TiAlN phase in fine-grained Ti0.38Al0.62N during turning. EDS shows that Cr and Fe from the steel adhere to the tool rake face during machining. Cr 1s and Fe 1s XANES show that Cr is oxidized in the end of the contact length while the adhered Fe retains in the same fcc-structure as that of the 316L stainless steel.
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6. |
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7. |
- Butorin, S. M., et al.
(author)
-
Resonant inelastic soft X-ray scattering at the 4d edge of Ce-based heavy fermion materials
- 1999
-
In: Journal of Electron Spectroscopy and Related Phenomena. - 0368-2048 .- 1873-2526. ; 101-103, s. 783-786
-
Journal article (peer-reviewed)abstract
- Resonant X-ray scattering measurements were performed on CeB6, CeAl, γ-Ce, and α-Ce at various incident-photon energies near the Ce 4d threshold. A pronounced inelastic scattering structure which has 4f character is observed at about 4 eV below the elastic peak. The structure shows a distinct resonant behavior as well as a dependence on the degree of 4f hybridization and can therefore be attributed to charge-transfer excitations to the 4f0 state. The intensity of the elastic peak increases when going from the systems with low Kondo temperature TK to those with high TK which is consistent with a Kondo scale behavior. By analyzing the scattering data, a controversial issue on the validity of a single-impurity Anderson model in heavy-fermion materials is addressed.
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8. |
- Chowdhury, Susmita, et al.
(author)
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Thermoelectric properties and electronic structure of Cr(Mo,V)Nx thin films studied by synchrotron and lab-based x-ray spectroscopy
- 2023
-
In: Physical Review B. - : AMER PHYSICAL SOC. - 2469-9950 .- 2469-9969. ; 108:20
-
Journal article (peer-reviewed)abstract
- Chromium-based nitrides are used in hard, resilient coatings and show promise for thermoelectric applications due to their combination of structural, thermal, and electronic properties. Here, we investigate the electronic structures and chemical bonding correlated to the thermoelectric properties of epitaxially grown chromium-based multicomponent nitride Cr(Mo,V)Nx thin films. The small amount of N vacancies causes Cr 3d and N 2p states to appear at the Fermi level and reduces the band gap in Cr0.51N0.49. Incorporating holes by alloying of V in N-deficient CrN results in an enhanced thermoelectric power factor with marginal change in the charge transfer of Cr to N compared with Cr0.51N0.49. Further alloying of Mo, isoelectronic to Cr, increases the density of states at the Fermi level due to hybridization of the (Cr, V) 3d and Mo 4d-N 2p states in Cr(Mo,V)Nx. This hybridization and N off-stoichiometry result in more metal-like electrical resistivity and reduction in Seebeck coefficient. The N deficiency in Cr(Mo,V)Nx also depicts a critical role in reduction of the charge transfer from metal to N site compared with Cr0.51N0.49 and Cr0.50V0.03N0.47. In this paper, we envisage ways for enhancing thermoelectric properties through electronic band engineering by alloying and competing effects of N vacancies.
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9. |
- Duda, L.-C., et al.
(author)
-
Resonant inelastic X-ray scattering at the NiO O K-resonance: non-local charge-transfer and double singlet excitations
- 2007
-
In: MAX-lab. - Lund : MAX-lab. ; , s. 270-271
-
Book chapter (other academic/artistic)abstract
- NiO is one of the prototypical compounds that has highlighted the importance of correlation effects in transition metal oxides. Core level spectroscopies bear evidence for the highly correlated nature of low energy excitations. For instance, the asymmetry of the Ni2p-line shape has been attributed to non-local charge transfer excitations and multi-site cluster calculations show that solidstate effects generally are appreciable for correlated materials, such as cuprates and high Tc-compounds.....
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10. |
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11. |
- Furlan, Andrej, et al.
(author)
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Structure and bonding in amorphous iron carbide thin films
- 2015
-
In: Journal of Physics. - : Institute of Physics Publishing (IOPP). - 0953-8984 .- 1361-648X. ; 27:4, s. 045002-
-
Journal article (peer-reviewed)abstract
- We investigate the amorphous structure, chemical bonding, and electrical properties ofmagnetron sputtered Fe1−xCx (0.21 < x < 0.72) thin films. X-ray, electron diffraction andtransmission electron microscopy show that the Fe1−xCx films are amorphousnanocomposites, consisting of a two-phase domain structure with Fe-rich carbidic FeCy , and acarbon-rich matrix. Pair distribution function analysis indicates a close-range order similar tothose of crystalline Fe3C carbides in all films with additional graphene-like structures at highcarbon content (71.8 at% C). From x-ray photoelectron spectroscopy measurements, we findthat the amorphous carbidic phase has a composition of 15–25 at% carbon that slightlyincreases with total carbon content. X-ray absorption spectra exhibit an increasing number ofunoccupied 3d states and a decreasing number of C 2p states as a function of carbon content.These changes signify a systematic redistribution in orbital occupation due to charge-transfereffects at the domain-size-dependent carbide/matrix interfaces. The four-point proberesistivity of the Fe1−xCx films increases exponentially with carbon content from ∼200μcm(x = 0.21) to ∼1200μcm (x = 0.72), and is found to depend on the total carbon contentrather than the composition of the carbide. Our findings open new possibilities for modifyingthe resistivity of amorphous thin film coatings based on transition metal carbides through thecontrol of amorphous domain structures.
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12. |
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13. |
- Guo, J.-H., et al.
(author)
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Resonant and nonresonant x-ray scattering spectra of some poly(phenylenevinylene)s
- 1998
-
In: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 108:14, s. 5990-5996
-
Journal article (peer-reviewed)abstract
- The electronic structure of some poly(phenylenevinylene)s have been investigated by resonant and nonresonant x-ray inelastic scattering spectroscopies. The nonresonant as well as all resonant spectra for each polymer demonstrate benzene-like features, indicating a local character of the x-ray emission in which the phenyl ring acts as a building block. Theoretical simulations of x-ray energies and intensities taking the repeat unit as a model molecule of the polymer agree with the experimental spectra fairly well. The edges of the occupied bands have been identified in the nonresonant spectra of each polymer. By subtracting the emission energy of the highest occupied molecular orbital in the nonresonant spectrum from the core excitation energy in the resonant spectrum an alternative way to determine the optical band gap is obtained. As for free benzene the outer π band in the polymer spectra show a depletion of the emission going from the nonresonant to the resonant x-ray emission spectra. It is demonstrated that this transition, which is strictly symmetry forbidden for free benzene, becomes effectively forbidden in the polymer case as a result of strong interference effects, and it is argued that this is the general case for resonant x-ray emission of conjugated polymers as far as the frozen orbital approximation holds.
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14. |
- Hague, C F, et al.
(author)
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Ferrimagnetic order in thin-film Fe3O4 studied by resonant inelastic X-ray scattering
- 2000
-
Reports (other academic/artistic)abstract
- We have set out to use the ID21 microfocusing beamline to perform resonant inelastic x-ray scattering (RIXS) experiments on magnetic materials. For the first tests and experiments we start off with Fe oxide thin films of potential interest in new technical applications. Of main interest are thin films of Fe3O4 epitaxially grown on alumina. Note that RIXS is particularly well adapted to experiments involving samples on insulating substrates (no charging effects) prepared ex-situ (bulk sensitivity) which can be magnetized (all-photons experiment)....
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15. |
- Hahlin, Maria, et al.
(author)
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Mapping the frontier electronic structures of triphenylamine based organic dyes at TiO2 interfaces
- 2011
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In: Physical Chemistry, Chemical Physics - PCCP. - : Royal Society of Chemistry (RSC). - 1463-9076 .- 1463-9084. ; 13:8, s. 3534-3546
-
Journal article (peer-reviewed)abstract
- The frontier electronic structures of a series of organic dye molecules containing a triphenylamine moiety, a thiophene moiety and a cyanoacrylic acid moiety have been investigated by photoelectron spectroscopy (PES), X-ray absorption spectroscopy (XAS), X-ray emission spectroscopy (XES) and resonant photoelectron spectroscopy (RPES). The experimental results were compared to electronic structure calculations on the molecules, which are used to confirm and enrich the assignment of the spectra. The approach allows us to experimentally measure and interpret the basic valence energy level structure in the dye, including the highest occupied energy level and how it depends on the interaction between the different units. Based on N 1s X-ray absorption and emission spectra we also obtain insight into the structure of the excited states, the molecular orbital composition and dynamics. Together the results provide an experimentally determined energy level map useful in the design of these types of materials. Included are also results indicating femtosecond charge redistribution at the dye/TiO2 interface.
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16. |
- Halim, Joseph, 1985-
(author)
-
Synthesis and transport properties of 2D transition metal carbides (MXenes)
- 2018
-
Doctoral thesis (other academic/artistic)abstract
- Since the isolation and characterization of graphene, there has been a growing interest in 2D materials owing to their unique properties compared to their 3D counterparts. Recently, a family of 2D materials of early transition metal carbides and nitrides, labelled MXenes, has been discovered (Ti2CTz, Ti3C2Tz, Mo2TiC2Tz, Ti3CNTz, Ta4C3Tz, Ti4N3Tz among many others), where T stands for surface-terminating groups (O, OH, and F). MXenes are mostly produced by selectively etching A layers (where A stands for group A elements, mostly groups 13 and 14) from the MAX phases. The latter are a family of layered ternary carbides and/or nitrides and have a general formula of Mn+1AXn (n = 1-3), where M is a transition metal and X is carbon and/or nitrogen. The produced MXenes have a conductive carbide core and a non-conductive O-, OH- and/or F-terminated surface, which allows them to work as electrodes for energy storage applications, such as Li-ion batteries and supercapacitors.Prior to this work, MXenes were produced in the form of flakes of lateral dimension of about 1 to 2 microns; such dimensions and form are not suitable for electronic characterization and applications. I have synthesized various MXenes (Ti3C2Tz, Ti2CTz and Nb2CTz) as epitaxial thin films, a more suitable form for electronic and photonic applications. These films were produced by HF, NH4HF2 or LiF + HCl etching of magnetron sputtered epitaxial Ti3AlC2, Ti2AlC, and Nb2AlC thin films. For transport properties of the Ti-based MXenes, Ti2CTz and Ti3C2Tz, changing n from 1 to 2 resulted in an increase in conductivity but had no effect on the transport mechanism (i.e. both Ti3C2Tx and Ti2CTx were metallic). In order to examine whether the electronic properties of MXenes differ when going from a few layers to a single flake, similar to graphene, the electrical characterization of a single Ti3C2Tz flake with a lateral size of about 10 μm was performed. These measurements, the first for MXene, demonstrated its metallic nature, along with determining the nature of the charge carriers and their mobility. This indicates that Ti3C2Tz is inherently of 2D nature independent of the number of stacked layers, unlike graphene, where the electronic properties change based on the number of stacked layers.Changing the transition metal from Ti to Nb, viz. comparing Ti2CTz and Nb2CTz thin films, the electronic properties and electronic conduction mechanism differ. Ti2CTz showed metallic-like behavior (resistivity increases with increasing temperature) unlike Nb2CTz where the conduction occurs via variable range hopping mechanism (VRH) - where resistivity decreases with increasing temperature.Furthermore, these studies show the synthesis of pure Mo2CTz in the form of single flakes and freestanding films made by filtering Mo2CTz colloidal suspensions. Electronic characterization of free-standing films made from delaminated Mo2CTz flakes was investigated, showing that a VRH mechanism prevails at low temperatures (7 to ≈ 60 K). Upon vacuum annealing, the room temperature, RT, conductivity of Mo2CTx increased by two orders of magnitude. The conduction mechanism was concluded to be VRH most likely dominated by hopping within each flake.Other Mo-based MXenes, Mo2TiC2Tz and Mo2Ti2C3Tz, showed VRH mechanism at low temperature. However, at higher temperatures up to RT, the transport mechanism was not clearly understood. Therefore, a part of this thesis was dedicated to further investigating the transport properties of Mo-based MXenes. This includes Mo2CTz, out-of-plane ordered Mo2TiC2Tz and Mo2Ti2C3Tz, and vacancy ordered Mo1.33CTz. Magneto-transport of free-standing thin films of the Mo-based MXenes were studied, showing that all Mo-based MXenes have two transport regimes: a VRH mechanism at lower temperatures and a thermally activated process at higher temperatures. All Mo-based MXenes except Mo1.33CTz show that the electrical transport is dominated by inter-flake transfer. As for Mo1.33CTz, the primary electrical transport mechanism is more likely to be intra-flake.The synthesis of vacancy ordered MXenes (Mo1.33CTz and W1.33CTz) raised the question of possible introduction of vacancies in all MXenes. Vacancy ordered MXenes are produced by selective etching of Al and (Sc or Y) atoms from the parent 3D MAX phases, such as (Mo2/3Sc1/3)2AlC, with in-plane chemical ordering of Mo and Sc. However, not all quaternary parent MAX phases form the in-plane chemical ordering of the two M metals; thus the synthesis of the vacancy-ordered MXenes is restricted to a very limited number of MAX phases. I present a new method to obtain MXene flakes with disordered vacancies that may be generalized to all quaternary MAX phases. As proof of concept, I chose Nb-C MXene, as this 2D material has shown promise in several applications, including energy storage, photothermal cell ablation and photocatalysts for hydrogen evolution. Starting from synthetizing (Nb2/3Sc1/3)2AlC quaternary solid solution and etching both the Sc and Al atoms resulted in Nb1.33C material with a large number of vacancies and vacancy clusters. This method may be applicable to other quaternary or higher MAX phases wherein one of the transition metals is more reactive than the other, and it could be of vital importance in applications such as catalysis and energy storage.
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17. |
- Karis, O., et al.
(author)
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Observation of short- and long-range hybridization of a buried Cu monolayer in Ni
- 2000
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In: Physical Review B Condensed Matter. - 0163-1829 .- 1095-3795. ; 62:24, s. R16239-R16242
-
Journal article (peer-reviewed)abstract
- The electronic structure of a Cu monolayer buried in Ni fcc(100) is studied by means of x-ray emission and absorption spectroscopies in combination with first principles calculations. The local character of the x-ray probes allows us to investigate changes in the chemical interaction for these ultrathin film systems. In comparison to bulk Cu, the occupied d states of a buried Cu monolayer, as mapped in the x-ray emission spectrum, remain mostly unaltered. The absorption spectrum on the other hand shows that the empty states of the buried Cu monolayer are modified, and instead resemble the unoccupied electronic density of bulk Ni. These findings agree well with our first principle electronic structure calculations and the results are interpreted in terms of short- and long-range hybridization.
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18. |
- Kashiwaya, Shun, et al.
(author)
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Synthesis of goldene comprising single-atom layer gold
- 2024
-
In: Nature Synthesis. - : Nature Publishing Group. - 2731-0582.
-
Journal article (peer-reviewed)abstract
- The synthesis of monolayer gold has so far been limited to free-standingseveral-atoms-thick layers, or monolayers confned on or inside templates.Here we report the exfoliation of single-atom-thick gold achieved throughwet-chemically etching away Ti3C2 from nanolaminated Ti3AuC2, initiallyformed by substituting Si in Ti3SiC2 with Au. Ti3SiC2 is a renown MAX phase,where M is a transition metal, A is a group A element, and X is C or N. Ourdeveloped synthetic route is by a facile, scalable and hydrofuoric acid-freemethod. The two-dimensional layers are termed goldene. Goldene layerswith roughly 9% lattice contraction compared to bulk gold are observedby electron microscopy. While ab initio molecular dynamics simulationsshow that two-dimensional goldene is inherently stable, experiments showsome curling and agglomeration, which can be mitigated by surfactants.X-ray photoelectron spectroscopy reveals an Au 4f binding energy increaseof 0.88 eV. Prospects for preparing goldene from other non-van der WaalsAu-intercalated phases, including developing etching schemes,are presented.
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19. |
- Magnuson, Martin, 1965-
(author)
-
An Electron Beam Heated Evaporation Source
- 1994
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Reports (other academic/artistic)abstract
- An electron beam evaporator has been assembled, tested and used for deposition of thin nickel films. Flux and deposition rates has been measured with an oscillating quartz crystal monitor (QCM), an ion sensor wire, and visible deposition on a mirror on front of the evaporator. A thin nickel rod of 2 mm diameter was found to improve the pressure in comparison to a 6-mm nickel rod. The flux was typically 3-4 Angstroms per minute during the test, but other flux rates can easily be achieved by changing the filament current and the acceleration voltage.
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20. |
- Magnuson, Martin, et al.
(author)
-
Anisotropy in the electronic structure of V2GeC investigated by soft x-ray emission spectroscopy and first-principles theory
- 2008
-
In: Physical Review B. Condensed Matter and Materials Physics. - 1098-0121 .- 1550-235X. ; 78:035117
-
Journal article (peer-reviewed)abstract
- Theanisotropy of the electronic structure of ternary nanolaminate V2GeC isinvestigated by bulk-sensitive soft x-ray emission spectroscopy. The measured polarization-dependentemission spectra of V L2,3, C K, Ge M1, and Ge M2,3 in V2GeCare compared with those from monocarbide VC and pure Ge.The experimental emission spectra are interpreted with calculated spectra usingab initio density-functional theory including dipole transition matrix elements. Differenttypes of covalent chemical bond regions are revealed: V 3d-C 2p bondingat −3.8 eV, Ge 4p-C 2p bonding at −6 eV, and Ge 4p-C 2s interaction mediatedvia the V 3d orbitals at −11 eV below the Fermi level.We find that the anisotropic effects are high for the4p valence states and the shallow 3d core levels ofGe, while relatively small anisotropy is detected for the V 3dstates. The macroscopic properties of the V2GeC nanolaminate result fromthe chemical bonds with the anisotropic pattern as shown inthis work.
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21. |
- Magnuson, Martin, 1965-, et al.
(author)
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Bonding Structures of ZrHx Thin Films by X-ray Spectroscopy
- 2017
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In: The Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 121, s. 25750-25758
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Journal article (peer-reviewed)abstract
- The variation in local atomic structure and chemical bonding of ZrHx (x=0.15, 0.30, 1.16) magnetron sputtered thin films are investigated by Zr K-edge (1s) X-ray absorption near-edge structure and extended X-ray absorption fine structure spectroscopies. A chemical shift of the Zr K-edge towards higher energy with increasing hydrogen content is observed due to charge-transfer and an ionic or polar covalent bonding component between the Zr 4d and the H 1s states with increasing valency for Zr. We find an increase in the Zr-Zr bond distance with increasing hydrogen content from 3.160 Å in the hexagonal closest-packed metal (a-phase) to 3.395 Å in the understoichiometric d-ZrHx film (CaF2-type structure) with x=1.16 that largely resembles that of bulk d-ZrH2. For yet lower hydrogen contents, the structures are mixed a- and d-phases, while sufficient hydrogen loading (x>1) yields a pure δ-phase that is understoichiometric, but thermodynamically stable. The change in the hydrogen content and strain is discussed in relation to the corresponding change of bond lengths, hybridizations, and trends in electrical resistivity.
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22. |
- Magnuson, Martin, 1965-, et al.
(author)
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Chemical bonding and electronic-structure in MAX phases as viewed by X-ray spectroscopy and density functional theory
- 2017
-
In: Thin Solid Films. - : Elsevier. - 0040-6090 .- 1879-2731. ; 621, s. 108-130
-
Research review (peer-reviewed)abstract
- This is a critical review of MAX-phase carbides and nitrides from an electronic-structure and chemical bonding perspective. This large group of nanolaminated materials is of great scientific and technological interest and exhibit a combination of metallic and ceramic features. These properties are related to the special crystal structure and bonding characteristics with alternating strong M-C bonds in high-density MC slabs, and relatively weak M-A bonds between the slabs. Here, we review the trend and relationship between the chemical bonding, conductivity, elastic and magnetic properties of the MAX phases in comparison to the parent binary MX compounds with the underlying electronic structure probed by polarized X-ray spectroscopy. Spectroscopic studies constitute important tests of the results of state-of-the-art electronic structure density functional theory that is extensively discussed and are generally consistent. By replacing the elements on the M, A, or X-sites in the crystal structure, the corresponding changes in the conductivity, elasticity, magnetism and other materials properties makes it possible to tailor the characteristics of this class of materials by controlling the strengths of their chemical bonds.
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23. |
- Magnuson, Martin, 1965-, et al.
(author)
-
Chemical bonding in carbide MXene nanosheets
- 2018
-
In: Journal of Electron Spectroscopy and Related Phenomena. - : Elsevier. - 0368-2048 .- 1873-2526. ; 224, s. 27-32
-
Journal article (peer-reviewed)abstract
- tThe chemical bonding in the carbide core and the surface chemistry in a new group of transition-metalcarbides Tin+1Cn-Tx(n = 1,2) called MXenes have been investigated by surface-sensitive valence bandX-ray photoelectron spectroscopy. Changes in band structures of stacked nano sheets of different thick-nesses are analyzed in connection to known hybridization regions of TiC and TiO2that affect elastic andtransport properties. By employing high excitation energy, the photoelectron cross-section for the C 2s– Ti 3d hybridization region at the bottom of the valence band is enhanced. As shown in this work, theO 2p and F 2p bands strongly depend both on the bond lengths to the surface groups and the adsorptionsites. The effect of surface oxidation and Ar+sputtering on the electronic structure is also discussed.
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24. |
- Magnuson, Martin, 1965-, et al.
(author)
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Chemical Bonding in Epitaxial ZrB2 Studied by X-ray Spectroscopy
- 2018
-
In: Thin Solid Films. - : Elsevier. - 0040-6090 .- 1879-2731. ; 649, s. 89-96
-
Journal article (peer-reviewed)abstract
- The chemical bonding in an epitaxial ZrB2 film is investigated by Zr K-edge (1s) X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) spectroscopies and compared to the ZrB2 compound target from which the film was synthesized as well as a bulk α-Zr reference. Quantitative analysis of X-ray Photoelectron Spectroscopy spectra reveals at the surface: ~5% O in the epitaxial ZrB2 film, ~19% O in the ZrB2 compound target and ~22% O in the bulk α-Zr reference after completed sputter cleaning. For the ZrB2 compound target, X-ray diffraction (XRD) shows weak but visible 11, 111, and 220 peaks from monoclinic ZrO2 together with peaks from ZrB2 and where the intensity distribution for the ZrB2 peaks show a randomly oriented target material. For the bulk α-Zr reference no peaks from any crystalline oxide were visible in the diffractogram recorded from the 0001-oriented metal. The Zr K-edge absorption from the two ZrB2 samples demonstrate more pronounced oscillations for the epitaxial ZrB2 film than in the bulk ZrB2 attributed to the high atomic ordering within the columns of the film. The XANES exhibits no pre-peak due to lack of p-d hybridization in ZrB2, but with a chemical shift towards higher energy of 4 eV in the film and 6 eV for the bulk compared to α-Zr (17.993 keV) from the charge-transfer from Zr to B. The 2 eV larger shift in bulk ZrB2 material suggests higher oxygen content than in the epitaxial film, which is supported by XPS. In EXAFS, the modelled cell-edge in ZrB2 is slightly smaller in the thin film (a=3.165 Å, c=3.520 Å) in comparison to the bulk target material (a=3.175 Å, c=3.540 Å) while in hexagonal closest-packed metal (α-phase, a=3.254 Å, c=5.147 Å). The modelled coordination numbers show that the EXAFS spectra of the epitaxial ZrB2 film is highly anisotropic with strong in-plane contribution, while the bulk target material is more isotropic. The Zr-B distance in the film of 2.539 Å is in agreement with the calculated value from XRD data of 2.542 Å. This is slightly shorter compared to that in the ZrB2 compound target 2.599 Å, supporting the XANES results of a higher atomic order within the columns of the film compared to bulk ZrB2.
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25. |
- Magnuson, Martin, 1965-, et al.
(author)
-
Coherent and Incoherent Processes in resonant Photoemission
- 1997
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In: Advanced Light Source. - California, USA : Ernest Orlando Lawrence Berkeley National Laboratory, University of California Berkeley. ; 65:2, s. 159-167
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Book chapter (pop. science, debate, etc.)
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