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  • Bidleman, Terry F., et al. (author)
  • Sea-air exchange of bromoanisoles and methoxylated bromodiphenylethers in the Northern Baltic
  • 2016
  • In: Marine Pollution Bulletin. - : Elsevier. - 0025-326X .- 1879-3363. ; 112:1-2, s. 58-64
  • Journal article (peer-reviewed)abstract
    • Halogenated natural products in biota of the Baltic Sea include bromoanisoles (BAs) and methoxylated bromodiphenyl ethers (MeO-BDEs). We identified biogenic 6-MeO-BDE47 and 2'-MeO-BDE68 in Baltic water and air for the first time using gas chromatography - high resolution mass spectrometry. Partial pressures in air were related to temperature by: log p/Pa=m/T(K)+b. We determined Henry's law constants (HLCs) of 2,4-dibromoanisole (2,4-DiBA) and 2,4,6-tribromoanisole (2,4,6-TriBA) from 5 to 30°C and revised our assessment of gas exchange in the northern Baltic. The new water/air fugacity ratios (FRs) were lower, but still indicated net volatilization in May-June for 2,4-DiBA and May - September for 2,4,6-TriBA. The net flux (negative) of BAs from Bothnian Bay (38,000km2) between May - September was revised from -1319 to -532kg. FRs of MeO-BDEs were >1, suggesting volatilization, although this is tentative due to uncertainties in their HLCs and binding to dissolved organic carbon.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Andersson, Agneta (1)
Tysklind, Mats (1)
Haglund, Peter (1)
Ripszam, Matyas (1)
Nygren, Olle (1)
Liljelind, Per (1)
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Agosta, Kathleen (1)
Bidleman, Terry F. (1)
Jantunen, Liisa M. (1)
Hegmans, Alyse (1)
Poole, Justen (1)
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University
Umeå University (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
Year
2016 (1)

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