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  • Huang, Ruihua, et al. (author)
  • Star-shaped porous nitrogen-doped metal-organic framework carbon as an electrochemical platform for sensitive determination of Cd(II) in environmental and tobacco samples
  • 2022
  • In: Analytica Chimica Acta. - : Elsevier. - 0003-2670 .- 1873-4324. ; 1228
  • Journal article (peer-reviewed)abstract
    • In this study, cetyltrimethylammonium bromide and zeolitic imidazolate framework-8 (ZIF-8) were first assembled via the chemical co-precipitation, and high-quality carbon-based metal-free nanomaterials were synthesized using a heat-treatment process. The internal and morphological characteristics of hexagonal Star ZIF-8 were investigated using scanning electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The electrochemical sensor with a good response to Cd(II) was prepared via square-wave anodic stripping voltammetry (SWASV) with Star ZIF-8 nanomaterial-modified glassy carbon electrodes. The main parameters were adjusted to obtain the optimal stripping response and a wide linear range. Concurrently, under the calculation of SWASV, the sensitivity of Star ZIF-8-Nafion/GCE to Cd(II) was increased by five orders of magnitude (0.5–230 μg/L), and the determination level was even low to 0.48 μg/L. Based on the high anti-interference ability and stability of the sensor, the application potential of Star ZIF-8 carbon-based metal-free nanomaterials for the detection of trace Cd(II) in was confirmed.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Wågberg, Thomas, 197 ... (1)
Hu, Guangzhi (1)
Zhou, Shuxing (1)
Zhang, Ke (1)
Li, Wenyan (1)
Li, Yongtao (1)
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Jia, Xiuxiu (1)
Huang, Ruihua (1)
Sun, Haowei (1)
Zhang, Dafeng (1)
Zhu, Jian (1)
Wang, Chunqiong (1)
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University
Umeå University (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
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