| 1. |
- Aksenova, N.A., et al.
(författare)
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Structural studies of C60 polymerized at high pressure
- 1997
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Ingår i: Proceedings of the Symposium on Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials. - Pennington, NJ : Electrochemical Society, Incorporated. - 1566771927
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Konferensbidrag (refereegranskat)
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| 2. |
- Aksenova, N.A., et al.
(författare)
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Structure studies of C60 polymerized at low pressures
- 1997
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Ingår i: Fullerenes. - Pennington, NJ : The Electrochemical Society. - 1566771927 ; , s. 687-694
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Konferensbidrag (refereegranskat)abstract
- The structure and lattice properties of a polymerized C60 sample were investigated by X-ray powder diffraction over the range from liquid-nitrogen to room temperature. The aim of these studies was to establish the effect of low-pressure compression (up to 1.1 GPa) on the phase composition of the sample, to determine the structure of the phases involved, to obtain the variation of the lattice parameters with temperature, to observe eventual phase transformation in polymerized C60, and to elucidate the evolution of the orientational order with varying temperature. Analysis of the room-temperature diffraction patterns indicates that the sample contained at least two major phases, namely rhombohedral and and tetragonal with the polymerization array close to two-dimensional. Our data obtained on samples annealed at 300 C in the air allow us to conclude that polymerized C60 converts to a mixture of the fcc structure plus a new phase, presumably C60O.
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| 3. |
- Aleksandrovskii, A. N., et al.
(författare)
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Effect of argon on the thermal expansion of fullerite C60 at helium temperatures
- 2001
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Ingår i: Low temperature physics (Woodbury, N.Y., Print). - : American Institute of Physics. - 1063-777X .- 1090-6517. ; 27:3, s. 245-246
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Tidskriftsartikel (refereegranskat)abstract
- The linear thermal expansion of compacted Ar-doped fullerite C60(ArxC60) is investigated at 2–12 K using a dilatometric method. The thermal expansion of ArxC60 is also studied after partial desaturation of argon from fullerite. It is revealed that argon doping resulted in a considerable change of the temperature dependence of the thermal expansion of fullerite. An explanation of the observed effects is proposed.
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| 4. |
- Aleksandrovskii, A. N., et al.
(författare)
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Low-temperature thermal expansion of pure and inert gas-doped fullerite C60
- 2003
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Ingår i: Fizika Nizkikh Temperatur (Kharkov). - : AIP Publishing. - 0132-6414 .- 1816-0328. ; 29:4, s. 432-442
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Tidskriftsartikel (refereegranskat)abstract
- The low temperature (2–24 K) thermal expansion of pure (single-crystal and polycrystalline) C60 and polycrystalline C60 intercalated with He, Ne, Ar, and Kr has been investigated using the high-resolution capacitance dilatometer. The investigation of the time dependence of the sample length variations deltaL(t) on heating by deltaT shows that the thermal expansion is determined by the sum of positive and negative contributions, which have different relaxation times. The negative thermal expansion usually prevails at helium temperatures. The positive expansion is connected with the phonon thermalization of the system. The negative expansion is caused by reorientation of the C60 molecules. It is assumed that the reorientation is of a quantum character. The inert gas impurities affect the reorientation of the C60 molecules very strongly, especially at liquid helium temperatures. A temperature hysteresis of the thermal expansion coefficient of Kr– and He–C60 solutions has been revealed. The hysteresis is attributed to orientational polyamorphous transformation in these systems.
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| 5. |
- Aleksandrovskii, A. N., et al.
(författare)
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Negative thermal expansion of fullerite C60 at helium temperatures
- 1997
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Ingår i: Low temperature physics (Woodbury, N.Y., Print). - : AIP Publishing. - 1063-777X .- 1090-6517. ; 23:11, s. 943-946
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Tidskriftsartikel (refereegranskat)abstract
- The thermal expansion of fullerite C60 has been measured in the temperature range 2–9 K. A compacted fullerite sample with a diameter of about 6 mm and height of 2.4 mm was used. It was found that at temperatures below ~ 3.4 K the linear thermal expansion coefficient becomes negative. At temperatures above 5 K our results are in good agreement with the available literature data. A qualitative explanation of the results is proposed
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| 6. |
- Aleksandrovskii, A.N., et al.
(författare)
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On the polyamorphism of fullerite-based orientational glasses.
- 2005
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Ingår i: Low Temperature Physics. - : AIP Publishing. - 1063-777X .- 1090-6517. ; 31:5, s. 429-444
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Tidskriftsartikel (refereegranskat)abstract
- The dilatometric investigation in the temperature range of 2–28 K shows that a first-orderpolyamorphous transition occurs in the orientational glasses based on C60 doped with H2, D2 andXe. A polyamorphous transition was also detected in C60 doped with Kr and He. It is observed thatthe hysteresis of thermal expansion caused by the polyamorphous transition (and, hence, the transitiontemperature) is essentially dependent on the type of doping gas. Both positive and negativecontributions to the thermal expansion were observed in the low-temperature phase of the glasses.The relaxation time of the negative contribution occurs to be much longer than that of the positivecontribution. The positive contribution is found to be due to phonon and libron modes, whilst thenegative contribution is attributed to tunneling states of the C60 molecules. The characteristictime of the phase transformation from the low-T phase to the high-T phase has been found for theC60–H2 system at 12 K. A theoretical model is proposed to interpret these observed phenomena.The theoretical model proposed, includes a consideration of the nature of polyamorphism inglasses, as well as the thermodynamics and kinetics of the transition. A model of noninteractingtunneling states is used to explain the negative contribution to the thermal expansion. The experimentaldata obtained is considered within the framework of the theoretical model. From the theoreticalmodel the order of magnitude of the polyamorphous transition temperature has been estimated.It is found that the late stage of the polyamorphous transformation is described well by theKolmogorov law with an exponent of n = 1. At this stage of the transformation, the two-dimensionalphase boundary moves along the normal, and the nucleation is not important.
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| 7. |
- Aleksandrovskii, A.N., et al.
(författare)
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Thermal expansion of fullerite C60 alloyed with argon and neon
- 2001
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Ingår i: Low temperature physics (Woodbury, N.Y., Print). - Woodbury : American Institute of Physics. - 1063-777X .- 1090-6517. ; 27:12, s. 1033-1036
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Tidskriftsartikel (refereegranskat)abstract
- The linear thermal expansion of compacted fullerite C60 alloyed with argon (ArxC60) and neon (NexC60) are investigated by a dilatometric method. The experimental temperature is 2–12 K. In the same temperature interval the thermal expansion of ArxC60 and NexC60 are examined after partial desaturation of the gases from fullerite. It is found that Ar and Ne alloying affects the temperature dependence of the thermal expansion coefficient of C60 quite appreciably. The libration and translation contributions to the thermal expansion of pure C60 are separated. The experimental results on the thermal expansion are used to obtain the Debye temperature of pure C60. The effects observed are tentatively interpreted.
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| 8. |
- Aleksandrovskii, A. N., et al.
(författare)
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Thermal expansion of single-crystal fullerite C60 at helium temperatures
- 2000
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Ingår i: Low temperature physics (Woodbury, N.Y., Print). - : AIP Publishing. - 1063-777X .- 1090-6517. ; 26:1, s. 75-80
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Tidskriftsartikel (refereegranskat)abstract
- The thermal expansion of single-crystal fullerite C60 has been studied in the range of liquid-helium temperatures (2–10 K). At temperatures below ~4.5 K the thermal expansion of fullerite C60 becomes negative, in agreement with the previous results on polycrystalline materials. A qualitative explanation of the results is proposed.
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| 9. |
- Andersson, Britt M., et al.
(författare)
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Defects and the thermal conductivity of YBa2Cu3O7-d and YBa2Cu4O8
- 1993
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Ingår i: Journal of Alloys and Compounds, volume 195. - : Elsevier Sequoia S.A.. - 0 444 81529 5 ; , s. 655-658
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Konferensbidrag (refereegranskat)abstract
- We present below the first measured data for the thermal diffusivity and the thermal conductivity, λ, of dense, sintered ceramic YBa2Cu4O8 (1-2-4) as a function of temperature T between 40 and 310 K. At 300 K, λ is 6.3 Wm−1K−1, increasing with decreasing T to about 9.5 Wm−1K−1 near Tc. This T dependence is much stronger than in YBa2Cu3O7−δ (1-2-3). Only a very small enhancement is observed in λ below Tc. As in 1-2-3, λ is mainly limited by phonon scattering by defects.
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| 10. |
- Andersson, Britt M., et al.
(författare)
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Electrical resistivity and critical temperature of Bi-based high-Tc superconductors to 1 GPa
- 1990
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Ingår i: High Pressure Research, volumes 3 to 5. - London : Gordon and Breach. - 2881247466 ; 3:1-6, s. 120-122
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Konferensbidrag (refereegranskat)abstract
- We have measured the electrical resistance R of a sintered, two-phase, high-TC superconductor with the nominal composition BiSrCaCu2Ox, as a function of T and p. We find d(lnR)/dp ≃ -0.06 GPa-1 at 295 K, while dTC/dp is 2.5 K/GPa for the phase with Tc ≃ 76 and 2 K/GPa for that with TC ≃ 106 K.
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| 11. |
- Andersson, Britt M., et al.
(författare)
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Electrical transport in dense, bulk YBa2Cu4O8 produced by hot isostatic pressing
- 1990
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Ingår i: Physica B Volumes 165 & 166, Part 2. - : Elsevier B.V.. ; , s. 1699-1700
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Konferensbidrag (refereegranskat)abstract
- Dense (98.5%) bulk sintered specimens of YBa2Cu4O8 have been produced by hot isostatic pressing. Data for the electrical resistivity π versus temperature T and pressure p in the range 70–300 K and 0–0.7 GPa are reported and discussed. The critical current density of the material studied exceeds 100 Acm−2 below 60 K.
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| 12. |
- Andersson, Britt M., et al.
(författare)
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Electrical transport properties of dense bulk YBa2Cu4O8 produced by hot isostatic pressing
- 1990
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Ingår i: Physica. C, Superconductivity. - 0921-4534 .- 1873-2143. ; 170:5-6, s. 521-531
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Tidskriftsartikel (refereegranskat)abstract
- Highly dense sintered YBa2Cu4O8 has been produced by hot isostatic pressing (HIP). The electrical resistivity varrho of this material has been measured as a function of temperature T and pressure varrho in the range 40–650 K and 0–0.7 GPa. Both the temperature dependence and the pressure dependence of varrho are found to be well described by a model based on the standard Bloch-Grüneisen theory. It is pointed out that varrho is liner in T only under isobaric conditions, while varrho is strongly nonlinear in all high-Tc superconductors under isochoric (constant volume) conditions. The critical current density of the material is 900 A/cm2 at 4 K, while the resistivity is 630 μΩ cm at 294 K.
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| 13. |
- Andersson, Britt M., et al.
(författare)
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High-pressure properties of high-Tc superconductor samples produced by hot isostatic pressing
- 1990
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Ingår i: High Pressure Research, volumes 3 to 5. - London : Gordon and Breach. - 2881247466 ; 3:1-6, s. 123-125
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Konferensbidrag (refereegranskat)abstract
- The electrical resistance of dense YBa2Cu3Ox and YBa2Cu4Oy produced by hot isostatic pressing has been measured vs. T and p. At 295 K we find d (ln R)/dp ≃ -0.12 and -0.09 GPa-1, respectively, with no systematic dependence on initial density. For 1-2-4, dTC/dp ≃ 5.1 K/GPa, which is ten times that of 1-2-3.
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| 14. |
- Andersson, Britt M., et al.
(författare)
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Thermal conductivity and thermal diffusivity of dense, bulk YBa2Cu4O8
- 1994
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Ingår i: High Temperatures - High Pressures volume 26, issue 1. - London : Pion Press. ; , s. 53-57
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Konferensbidrag (refereegranskat)abstract
- We have measured the thermal conductivity, lambda, and the thermal diffusivity, a, of dense bulk ceramic YBa2Cu4O8 (1-2-4) between 30 and 300 K. For this material lambda is about 10 W/Km near 100 K, comparable with the in-plane thermal conductivity for single crystals of the more common high-Tc material YBa2Cu3O7 (1-2-3). Also, lambda has a much stronger T dependence in 1-2-4 than in 1-2-3. We find that, for 1-2-4, lambda can be very well described by a semiclassical phonon theory, which includes phonon, electron, and boundary scattering. The difference between the present results and those for 1-2-3 can be explained mainly in terms of a smaller amount of point-defect scattering in 1-2-4 because of the stable oxygen stoichiometry of this material.
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| 15. |
- Andersson, Britt M., et al.
(författare)
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Thermal conductivity of polycrystalline YBa2Cu4O8
- 1994
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Ingår i: Physical Review B. Condensed Matter and Materials Physics. - 1098-0121 .- 1550-235X. ; 49:6, s. 4189-4198
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Tidskriftsartikel (refereegranskat)abstract
- We have measured the thermal conductivity κ and the thermal diffusivity a of a dense bulk ceramic polycrystalline sample of YBa2Cu4O8 (1:2:4) in the temperature range 30–300 K. We find κ≊10 W m-1 K-1 at 100 K, significantly higher than in ceramic YBa2Cu3O7-δ (1:2:3) and approaching the in-plane value for single-crystal 1:2:3, and decreasing to 7.6 W m-1 K-1 at 300 K. The data for this sample can be described by standard theories for phonon thermal conductivity of crystalline materials with boundary, phonon, and electron scattering. The higher κ in 1:2:4 as compared to 1:2:3 is, in this model, due to the smaller point defect scattering in the former. The fitted parameters for the three scattering mechanisms all agree with independent estimates based on simple models; inserting data for electric resistivity, grain size, carrier density, and lattice properties we can predict κ and its T dependence to within about 20%. We also discuss models for the phonon and electron thermal conductivities in some detail, including some second-order effects such as inelastic electron scattering and a T-dependent carrier density.
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| 16. |
- Andersson, Britt M., et al.
(författare)
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Thermal conductivity of YBa2Cu4O8 dominated by phonon-phonon interactions
- 1993
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Ingår i: Physical Review B. Condensed Matter and Materials Physics. - 1098-0121 .- 1550-235X. ; 48:5, s. 3575-3578
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Tidskriftsartikel (refereegranskat)abstract
- The thermal conductivity κ of dense sintered ceramic YBa2Cu4O8 in the range 30–310 K has been measured. At 100 K, κ is 10 W m-1 K-1, approaching the in-plane κ of single crystals of other high-Tc materials. κ decreases rapidly with increasing T to 7.4 W m-1 K-1 at 300 K. Fitting standard models for κ(T) to the data we find that κ is limited mainly by phonon-phonon interactions. Depending on the model used, the best fit is found for effective values of FTHETADebye between 155 and 185 K, characteristic for the acoustic phonon branches, indicating that such phonons carry most of the heat. Finally, we suggest a possible way to test the electron-phonon model for the electrical and thermal conductivities in high-Tc materials.
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| 17. |
- Andersson, Britt M., et al.
(författare)
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Thermal conductivity of YBa2Cu4O8 under high pressure
- 1993
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Ingår i: Physica. C, Superconductivity. - : Elsevier B.V.. - 0921-4534 .- 1873-2143. ; 216:1-2, s. 187-194
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Tidskriftsartikel (refereegranskat)abstract
- The thermal diffusivity a of YBa2Cu4O8 (1-2-4) has been measured as a function of pressure p and temperature T over the range 85
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| 18. |
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| 19. |
- Andersson, Göran, et al.
(författare)
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A high-pressure cell for electrical resistance measurements at hydrostatic pressures up to 8 GPa : Results for Bi, Ba, Ni, and Si
- 1989
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Ingår i: Journal of Applied Physics. - : AIP Publishing. - 0021-8979 .- 1089-7550. ; 65:10, s. 3943-3950
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Tidskriftsartikel (refereegranskat)abstract
- A modified Bridgman anvil high-pressure device, capable of producing hydrostatic pressures up to 8 GPa (80 kbar), was designed and built. The size of the pressure chamber (10 mm in diameter) allows the use of large specimens and simple experimental procedures. Experimental results show that hydrostatic conditions are necessary if accurate quantitative information is desired about the electrical properties of materials under pressure. Accurate data on resistance (and resistivity) versus pressure at 294 K are given for Bi, Ba, Ni, and Si. The initial pressure coefficients of R were d(ln R)dP=0.13, −7.6×10−2, −2.0×10−2, and −0.26 GPa−1, respectively. Barium has a resistance minimum near 0.9 GPa. For Bi we observe sharp transitions at 2.55, 2.7, and 7.7 GPa, and for Ba at 5.55 GPa, but we cannot verify the existence of a transition in Ba near 7 GPa. Neither do we confirm the phase transformation in Ni recently reported to occur above 2.5 GPa. For Si, R(P) agrees very well with a theoretical function calculated from the change in band gap and electron mobility with pressure.
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| 20. |
- Andersson, Göran, et al.
(författare)
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Electrical resistivity measurements under hydrostatic conditions up to 10 GPa
- 1984
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Ingår i: Journal de Physique Colloques vol. 45. - : EDP Sciences. - 0449-1947. ; , s. 379-382
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Konferensbidrag (refereegranskat)abstract
- A large scale Bridgman anvil system has been designed. Steel gaskets permit compression of a methanol-ethanol medium over a volume of 500-250 mm3. Up to 12 wires have been used to contact specimens. The system has so far served up to 7.5 GPa, with anvils made of ASP tool steel. The transition Bi III-V was found to occur at a lower pressure than the recommended average. The electrical resistance of copper was measured up to 6 GPa under hydrostatic conditions.
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| 21. |
- Andersson, Göran, et al.
(författare)
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Pressure dependence of the c-axis resistance of stage 2 SbCl5 intercalated graphite to 4 GPa
- 1988
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Ingår i: Solid State Communications. - : Elsevier BV. - 0038-1098 .- 1879-2766. ; 65:7, s. 735-738
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Tidskriftsartikel (refereegranskat)abstract
- The c-axis electrical resistance R has been measured under pressure up to 4 GPa (40 kbar) at room temperature for stage 2, HOPG-based SbCl5 intercalated graphite. In addition to the well known ordering transition at 0.3–0.5 GPa a second anomaly in R is observed above 1 GPa, corresponding to a further phase transition which is not completed until above 2.4 GPa. In all phases R depends more strongly on p for the intercalated material than for HOPG, and the total decrease in R is over 80% to 4 GPa.
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| 22. |
- Andersson, Ove, et al.
(författare)
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A low-temperature high-pressure apparatus with a temperature control system
- 1992
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Ingår i: High Pressure Research. - : Informa UK Limited. - 0895-7959 .- 1477-2299. ; 10:4, s. 599-606
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Tidskriftsartikel (refereegranskat)abstract
- A low-temperature high-pressure apparatus was designed using commercial cryogenic equipment. Pressures up to 1 GPa and temperatures down to 40 K can be obtained in a volume of up to 30 cm3. The apparatus is of the piston-cylinder type with a piston diameter of 45 mm, and the pressure can be varied at all temperatures, An adaptive temperature control system keeps the temperature inside the pressure cylinder constant to within ±0.1 K.
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| 23. |
- Andersson, Odd E., et al.
(författare)
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A study of temperature and pressure induced structural and electronic changes in SbCl5 intercalated graphite : Part II. Experimental data for c-axis resistivity
- 1992
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Ingår i: Journal of Materials Research. - 0884-2914 .- 2044-5326. ; 7:11, s. 2989-3000
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Tidskriftsartikel (refereegranskat)abstract
- We present experimental data for the c-axis resistivity ?c of stage s = 2, 3, 4, 5, and 8, SbCl5 intercalated graphite, over the temperature range 40 to 300 K and the pressure range 0 to 0.8 GPa (0–8 kbar). For most specimens studied, resistance anomalies are observed below 230 K at atmospheric pressure and at pressures up to 0.5 GPa at 293 K. These anomalies are explained in terms of structural changes from a disordered or partly crystallized in-plane intercalate structure at atmospheric pressure and T > 230 K to an almost completely crystallized structure below this temperature, or at elevated pressures, as discussed in a companion paper. In the crystallized phases ?c is approximately linear in T except for stage 8, for which a nonlinear behavior, with a negative temperature coefficient of resistivity below 200 K, is observed. The results are compared with previously available literature data, and the p-T phase diagram is briefly discussed.
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| 24. |
- Andersson, Odd E., et al.
(författare)
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A study of temperature and pressure induced structural and electronic changes in SbCl5 intercalated graphite : Part IV: Basal plane resistivity
- 1995
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Ingår i: Journal of Materials Research. - 0884-2914 .- 2044-5326. ; 10:7, s. 1653-1660
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Tidskriftsartikel (refereegranskat)abstract
- Using an inductive technique, we have measured the in-plane resistivity rhoa of stages 2, 4, 5, and 8 SbCl5-GIC's versus temperature T and pressure p in the ranges 130–300 K and 0–0.85 GPa. The room temperature values of rhoa range from 4.0 µOcm for the stages 5 sample to 7.7 µOcm for the stage 8 sample. At all pressures, rhoa shows a metallic temperature dependence rhoa ~ Ta, with 1 < a < 2, but in contrast to the c-axis resistivity rhoc, it depends only very weakly on pressure and/or intercalate structural order. We show that the behavior observed is consistent with a band conduction model.
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| 25. |
- Andersson, Odd E., et al.
(författare)
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C-axis resistance of HgCl2 intercalated graphite as a function of temperature and pressure
- 1989
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Ingår i: Synthetic Metals volume 34. - Lausanne : Elsevier Sequoia SA. ; , s. 485-490
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Konferensbidrag (refereegranskat)abstract
- The c-axis resistance of stage 3 HgCl2 intercalated graphite has been measured as a function of temperature T and pressure p in the range 40 to 300 K and up to 1 GPa (10 kbar). The absolute resistivity and its T- and p- dependence are all in good agreement with data for other acceptor compounds. The measurements show that a previosly unknown phase transformation occurs above 0.4 GPa. Below 250 K the high pressure phase is metastable down to zero pressure, and an x-ray diffraction analysis of metastable material shows that no stage change occurs. The transition thus probably leads to a different in-plane structure characterized by a more densely packed intercalate layer.
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