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2. |
- Bouyoucef, S E, et al.
(author)
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Poster Session 2 : Monday 4 May 2015, 08
- 2015
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In: European Heart Journal Cardiovascular Imaging. - : Oxford University Press (OUP). - 2047-2404 .- 2047-2412. ; 16 Suppl 1
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Journal article (peer-reviewed)
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3. |
- Ferreira, Mjv, et al.
(author)
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Poster Session 3 : Tuesday 5 May 2015, 08
- 2015
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In: European Heart Journal Cardiovascular Imaging. - : Oxford University Press (OUP). - 2047-2404 .- 2047-2412. ; 16 Suppl 1
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Journal article (peer-reviewed)
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4. |
- Danilovich, I. L., et al.
(author)
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Co(NO3)(2) as an inverted umbrella-type chiral noncoplanar ferrimagnet
- 2020
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In: Physical Review B. - : AMER PHYSICAL SOC. - 2469-9950 .- 2469-9969. ; 102:9
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Journal article (peer-reviewed)abstract
- The low-dimensional magnetic systems tend to reveal exotic spin-liquid ground states or form peculiar types of long-range order. Among systems of vivid interest are those characterized by the triangular motif in two dimensions. The realization of either ordered or disordered ground state in triangular, honeycomb, or kagome lattices is dictated by the competition of exchange interactions, also being sensitive to anisotropy and the spin value of magnetic ions. While the low-spin Heisenberg systems may arrive to a spin-liquid long-range entangled quantum state with emergent gauge structures, the high-spin Ising systems may establish the rigid noncollinear structures. Here, we present the case of chiral noncoplanar inverted umbrella-type ferrimagnet formed in cobalt nitrate Co(NO3)(2) below T-C = 3 K with the comparable spin and orbital contributions to the total magnetic moment.
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5. |
- Chudinova, E., et al.
(author)
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Functionalization of additive-manufactured Ti6Al4V scaffolds with poly(allylamine hydrochloride)/poly(styrene sulfonate) bilayer microcapsule system containing dexamethasone
- 2021
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In: Materials Chemistry and Physics. - : Elsevier BV. - 0254-0584 .- 1879-3312. ; 273
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Journal article (peer-reviewed)abstract
- Porous titanium alloy Ti6Al4V scaffolds manufactured via electron beam melting (EBM®) reveal broad prospects for applications in bone tissue engineering. However, local inflammation and even implant failure may occur while placing an implant into the body. Thus, the application of drug carriers to the surface of a metallic implant can provide treatment at the inflammation site. In this study, we propose to use polyelectrolyte (PE) microcapsules formed by layer-by-layer (LbL) synthesis loaded with both porous calcium carbonate (CaCO3) microparticles and the anti-inflammatory drug dexamethasone (DEX) to functionalize implant surfaces and achieve controlled drug release. Scanning electron microscopy indicated that the CaCO3 microparticles coated with PE bilayers loaded with DEX had a spherical shape with a diameter of 2.3 ± 0.2 μm and that the entire scaffold surface was evenly coated with the microcapsules. UV spectroscopy showed that LbL synthesis allows the manufacturing of microcapsules with 40% DEX. According to high performance liquid chromatography (HPLC) analysis, 80% of the drug was released within 24 h from the capsules consisting of three bilayers of polystyrene sulfonate (PSS) and poly(allylamine)hydrochloride (PAH). The prepared scaffolds functionalized with CaCO3 microparticles loaded with DEX and coated with PE bilayers showed hydrophilic surface properties with a water contact angle below 5°. Mouse embryonic fibroblast cells were seeded on Ti6Al4V scaffolds with and without LbL surface modification. The surface modification with LbL PE microcapsules with CaCO3 core affected cell morphology in vitro. The results confirmed that DEX had no toxic effect and did not prevent cell adhesion and spreading, thus no cytotoxic effect was observed, which will be further studied in vivo.
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6. |
- Grechnev, G. E., et al.
(author)
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Anisotropy of magnetic properties of Fe1+y Te
- 2014
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In: Journal of Physics. - : IOP Publishing. - 0953-8984 .- 1361-648X. ; 26:43, s. 436003-
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Journal article (peer-reviewed)abstract
- The magnetic properties of Fe1+y Te single crystals (y similar or equal to 0.1 divided by 0.18) were studied at temperatures 4.2 divided by 300 K. At an ambient pressure, with decreasing temperature a drastic drop in chi(T) was confirmed at T similar or equal to 60 divided by 65 K, which appears to be closely related to the antiferromagnetic (AFM) ordering. It is found that the magnitudes of the anisotropy of magnetic susceptibility Delta chi. in the AFM phase are close in the studied samples, whereas the sign of the anisotropy apparently depends on the small variations of the excess iron y in Fe1+y Te samples. The performed DFT calculations of the electronic structure and magnetic properties for the stoichiometric FeTe compound indicate the presence of frustrated AFM ground states. There are very close energies and magnetic moments for the double stripe configurations, with the AFM axes oriented either on the basal plane or along the [0 0 1] direction. Presumably, both these configurations can be realized in Fe1+y Te single crystals, depending on the variations of the excess iron. This can provide different signs of magnetic anisotropy in the AFM phase, presently observed in the Fe1+y Te samples. For these types of AFM configuration, the calculations for the FeTe values of Delta chi are consistent with our experimental data.
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7. |
- Korobeinikov, I., et al.
(author)
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Density of Liquid Manganese Measured Using the Maximum Bubble Pressure Method
- 2021
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In: Metallurgical and materials transactions. B, process metallurgy and materials processing science. - : Springer Nature. - 1073-5615 .- 1543-1916. ; 52:2, s. 571-575
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Journal article (peer-reviewed)abstract
- Manganese is an important metal for steelmaking. Data on the density of the metal are scarce and show considerable scatter. Present work reports the density of the liquid manganese in the range of 1535 K to 1836 K estimated for the first time with the use of the maximum bubble pressure technique. The obtained density of the manganese is marginally higher than previously reported in the literature.
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8. |
- Korobeinikov, I. I., et al.
(author)
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Density of tin, silver and copper
- 2018
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In: Archives of Materials Science and Engineering. - : International OCSCO World Press. - 1897-2764. ; 92:1, s. 28-32
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Journal article (peer-reviewed)abstract
- Purpose: Purpose of this paper is to report on the development of a new density measurement cell. Design/methodology/approach: Measurement cell based on Archimedean principle and consisting of induction furnace and a high/precision balance was applied for measurement of tin, silver and copper density. Findings: It was found that new cell is suitable for high temperature measurement of liquid metals density at temperatures from 700 to 1520°C. Measurement results are in a good agreement with the literature values. Density deviates by 0.5-1% depending on the metal. Research limitations/implications: Accuracy of the density measurement decreases at temperatures below 700°C due to oxidation of the melt surface. More accurate data on thermal expansion coefficient for sinker material is required. Practical implications: Experiments showed applicability of the new measurement cell. Archimedean principle is among the most sensitive density measurement techniques. New cell will be further used for measurement of iron-based alloys. Problems of measurements are discussed. Originality/value: Paper describes application of the known density measurement technique. The paper is of interest for the material scientists working with high-temperature thermophysical properties measurements and users of thermophysical properties data.
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9. |
- Korobeinikov, I, et al.
(author)
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Surface Tension and Density of Cr–Mn–Ni Steels with Transformation Induced Plasticity Effect
- 2020
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In: Steel Research International. - : Wiley-VCH Verlag. - 1611-3683 .- 1869-344X.
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Journal article (peer-reviewed)abstract
- Thermophysical properties of liquid metal alloys play a crucial role in the variety of processes. Present work reports experimental investigations of two new transformation induced plasticity (TRIP) steels. A classical maximum bubble pressure technique is successfully used to measure surface tension and density of the liquid TRIP-steel samples in the temperatures range of 1500–1800 °C. Experiments are performed in two different measurement cells from TU Freiberg and Commissariat a l'Energie Atomique (CEA), Cadarache. Capillaries are made of zirconia partially stabilized with yttrium oxide, and the samples are molten in Al2O3 crucibles. Measurements are conducted under the argon atmosphere. Surface tension of the investigated samples rises up to 1700 °C and further remains the same. Density of the new steels obtained in this study is in good agreement with the previously reported values for Fe–Cr alloys with similar Cr content. Density of the alloy is estimated as 875 488–11 885 × T (±218.85 kg m−3) for a 15%Cr alloy and 796 042–06 897 × T (±199 kg m−3) for a 19%Cr alloy.
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10. |
- Shyrokykh, T., et al.
(author)
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Vaporization of Vanadium Pentoxide from CaO-SiO2-VOx Slags During Alumina Dissolution
- 2021
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In: Metallurgical and materials transactions. B, process metallurgy and materials processing science. - : Springer Nature. - 1073-5615 .- 1543-1916. ; 52:3, s. 1472-1483
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Journal article (peer-reviewed)abstract
- The vaporization of vanadium pentoxide from CaO-SiO2-VOx ternary slags using different gas treatment regimens and parallel vacuum gas extirpation to treat V-bearing slags at 1873 K has been developed in the present study. The novelty of the present study is to monitor the effect of parallel alumina dissolution on the vaporization phenomenon. Vanadium pentoxide has high vapor pressure at the temperatures over 1500 K. When CaO-SiO2-VOx ternary slags, kept in dense alumina crucibles, are injected with oxygen, V2O5 gas bubbles are formed which are forced out by using vacuum extirpation. The vanadium pentoxide could be then collected in the exhaust gases. The mechanism of the process phenomenon is described as the formation of V2O5 gas phase resulting from the oxidation of the lower-valent oxides present in the slag. This gas phase would form microbubbles in the molten slag bulk phase due to low surface tension between the gas phase and the slag, thereby increasing the contact surface. At the same time, the crucible material would dissolve in the slag causing an increase in the slag viscosity. Due to the high slag viscosity of the bulk slag, these microbubbles formed would have difficulty in coalescing and reaching the slag surface. The escaping of the bubbles into the gas phase is enabled by the vacuum extirpation.
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11. |
- Svensson, Gunnar, 1960-, et al.
(author)
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Synthesis and characterisation of the novel double perovskites La2CrB2/3Nb1/3O6, B = Mg, Ni, Cu
- 2012
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In: Materials Research Bulletin. - : Elsevier BV. - 0025-5408 .- 1873-4227. ; 47:9, s. 2449-2454
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Journal article (peer-reviewed)abstract
- The novel perovskites La2CrB2/3Nb1/3O6, B = Mg, Ni, and Cu have been synthesised at 1350 degrees C in air via the citrate route. Rietveld refinements using neutron powder diffraction (NPD) data showed that the compounds adopt the GdFeO3 type structure with space group Pbnm, and unit cell parameters a approximate to b approximate to root 2 x a(p) and c approximate to 2 x a(p), where a(p) approximate to 3.8 angstrom. Selected area electron diffraction (SAED) of B = Ni and Cu samples confirmed space group Pbnm. However, distinct reflections forbidden in Pbnm symmetry, but allowed in the monoclinic sub-group P2(1)/n and unit cell parameters a approximate to b approximate to root 2 x a(p) and c approximate to 2 x a(p), beta approximate to 90 degrees were present in SAED patterns of B = Mg sample. This indicates an ordering of the B-cations within the crystal structure of La2CrMg2/3Nb1/3O6. High-resolution electron microscopy (HREM) study indicating uniform, without formation of clusters, ordering of B-cations in the crystallites of La2CrMg2/3Nb1/3O6. Magnetic susceptibility measurements show that the compounds are antiferromagnetic (with some glass or spin clustering effects due to additional ferromagnetic interactions between the B-cations) with T-N for La2CrB2/3Nb1/3O6, B = Mg, Ni, Cu being 90, 125 and 140K, respectively.
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